Performance enhancement of inverted type organic solar cells by using Eu doped TiO2 thin film

WOS: 000418617000010In the present work, europium (Eu) has been used as a dopant element in titanium dioxide (TiO2) crystal structure to enhance the photovoltaic performance of the inverted type organic solar cells fabricated with TiO2 thin film as an electron transport layer. Poly(3-hexylthiophene): phenylC61-butyric acid methyl ester (P3HT: PCBM) blend has been used as an active layer and Eu: TiO2 thin films have been fabricated with different Eu concentrations as 0, 1, 5, 7 and 10% (w/w) by sol-gel method. Effect of Eu doping concentration on the photovoltaic performance of the inverted type solar cells has been investigated. Inverted type organic solar cells using Eu doped TiO2 thin films as electron transport layer has been fabricated as a structure of ITO/Eu:TiO2/P3HT: PCBM/Ag. Power conversion efficiency of the fabricated solar cells increased from 1.16% to 2.47% at 5% Eu doping concentration. Electron transport and hole blocking properties of the TiO2 inter layer has been improved by Eu doping.Ahi Evran UniversityAhi Evran University [MMF.A3.16.009]This research is supported by Ahi Evran University Grant no.: MMF.A3.16.009

Fe doped TiO2 thin film as electron selective layer for inverted solar cells

WOS: 000377311400044Inverted P3HT:PCBM based organic solar cells were fabricated by using Fe2+ doped TiO2 films as electron selective layer. Pure and Fe2+ doped TiO2 films were prepared by sol gel method and the optical as well as the structural properties of the thin films were characterized by UV-Vis spectrophotometer and SEM. The concentration of Fe2+ was varied as 0.5%, 1%, 2% and 3% (w/w) in TiO2 layer and the influence of Fe2+ doping on the solar cell parameters were systemically investigated. Photocurrent density of the solar cells as increased from 8.75 to 13.8 mA/cm(2), whereas the solar cell efficiency changed from 1.7% to 2.79% by using Fe2+ doped TiO2 electron selective layer. It was experimentally found and demonstrated that charge injection and selection in the TiO2 interlayer was improved by doping of Fe2+ atoms in the TiO2. (C) 2016 Elsevier Ltd. All rights reserved.TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [113M935]This research is supported by TUBITAK Grant No.: 113M935

Electrochemical Growth of Pd Doped ZnO Nanorods

WOS: 000349827200059In this work, dense arrays of pure and Pd doped zinc oxide (ZnO) nanorods (NRs) were fabricated by an electrochemical growth. Pure and Pd doped ZnO NRs were characterized via scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and optic spectroscopy. Structural studies confirmed that pure and doped ZnO NRs present the hexagonal wurtzite crystal structures. The optical properties of pure and doped ZnO NRs were found to present redshift by increasing doping concentration. The diameters of the NRs increase with increasing Pd doping concentration under same condition. Compared with pure ZnO NRs, the Pd doped ZnO NRs presents improved optical properties in terms of bandgap energy from 3.24 eV to 1.97 eV. These bandgap values were obtained by optical absorption using a UV-Visible spectrophotometer. In addition, Pd doping concentration in ZnO affects the active species on the surface such as oxygen deficiencies and hydroxyls. The electrochemically growing mechanism is also discussed in detail in the scope of this work. (C) 2015 The Electrochemical Society. All rights reserved.TUBITAK [113F403, 113M935]The authors thank KUYTAM at Koc University and Dr. Baris Yagci for SEM measurements. This research is supported by TUBITAK grant no.: 113F403 and grant no.: 113M935

An efficient organic inverted solar cell with AnE-PVstat:PCBM active layer and V2O5/Al anode layer

WOS: 000330489900009An inverted organic solar cell, which is based on anthcene-containing poly (p-phenylene-ethynylene)-alt-poly(p-phenylene-vinylene) (PPE-PPV) polymer (AnE-PVstat) and phenyl C-61 butyric acid methyl ester (PCBM), was fabricated with Titanium dioxide (TiO2) electron transport layer and V2O5/Al anode layer. In this study, we have investigated the effect of V2O5 thickness on solar cell efficiency. Power conversion efficiency of 3.26% has been achieved for 15 nm V2O5 layer. The lifetime of the cell was investigated using ISOS-L-1. The test indicated that the durability of the solar cell, which is designed in ITO/TiO2/AnE-PVstat:PCBM/V2O5 (15 nm)/Al configuration, is 99% under standard solar irradiation of 100 mW/cm(2) (AM 1.5 G) at ambient conditions for 24 h. (C) 2013 Elsevier Ltd. All rights reserved