384 research outputs found
Transformation of ethylbenzene-m-xylene feed over MCM-22 zeolites with different acidities
Transformation of ethylbenzene (EB, 22 wt%)-m-xylene (78 wt%) mixture was carried out over zeolite MCM-22 catalysts with different acidities. The modification of the number and strength of the acid sites was attained by: (i) dealumination by steaming and successive acid treatment and (ii) isomorphous substitution of framework Al for boron ([Al,B]MCM-22). The effect of platinum introduction was also investigated. The strong decrease in the Brønsted acidity, concomitant to the dealumination procedure, appears unfavorable since it leads to a drastic diminish of the degree of EB conversion, not compensated by satisfactory level of m-xylene isomerization. [Al,B]MCM-22 is a modification with much better performance, most probably because it contains both strong, Al-connected acid sites but in lower amount than in the parent sample, and weaker boron-generated sites and practically no any Lewis sites.
Parent zeolite [Al]MCM-22 as well as B-substitution possess promising properties for ethylbenzene–m-xylene mixture transformation catalyst with adequate degree of EB conversion and extent of p-xylene approach to equilibrium as well as low xylene loss
A high fibered power of a family of varieties of general type dominates a variety of general type
We prove the following theorem:
Fibered Power Theorem: Let X\rar B be a smooth family of positive
dimensional varieties of general type, with irreducible. Then there exists
an integer , a positive dimensional variety of general type , and a
dominant rational map X^n_B \das W_n.Comment: Latex2e (in latex 2.09 compatibility mode). To get a fun-free version
change the `FUN' variable to `n' on the second line (option dedicated to my
friend Yuri Tschinkel). Postscript file with color illustration available on
http://math.bu.edu/INDIVIDUAL/abrmovic/fibered.p
Fibrations on four-folds with trivial canonical bundles
Four-folds with trivial canonical bundles are divided into six classes
according to their holonomy group. We consider examples that are fibred by
abelian surfaces over the projective plane. We construct such fibrations in
five of the six classes, and prove that there is no such fibration in the sixth
class. We classify all such fibrations whose generic fibre is the Jacobian of a
genus two curve.Comment: 28 page
Mono- and double carbonylation of aryl iodides with amine nucleophiles in the presence of recyclable palladium catalysts immobilised on a supported dicationic ionic liquid phase
Silica modified with organic dicationic moieties proved to be an excellent support for palladium catalysts used in the aminocarbonylation of aryl iodides. By an appropriate choice of the reaction conditions, the same catalyst could be used for selective mono- or double carbonylations leading to amide and [small alpha]-ketoamide products, respectively. The best catalyst could be recycled for at least 10 consecutive runs with a loss of palladium below the detection limit. By the application of the new support, efficient catalyst recycling could be achieved under mild reaction conditions (under low pressure and in a short reaction time). Palladium-leaching data support a mechanism with dissolution-re-precipitation of the active palladium species
A simply connected surface of general type with p_g=0 and K^2=2
In this paper we construct a simply connected, minimal, complex surface of
general type with p_g=0 and K^2=2 using a rational blow-down surgery and
Q-Gorenstein smoothing theory.Comment: 19 pages, 6 figures. To appear in Inventiones Mathematica
Differential Forms on Log Canonical Spaces
The present paper is concerned with differential forms on log canonical
varieties. It is shown that any p-form defined on the smooth locus of a variety
with canonical or klt singularities extends regularly to any resolution of
singularities. In fact, a much more general theorem for log canonical pairs is
established. The proof relies on vanishing theorems for log canonical varieties
and on methods of the minimal model program. In addition, a theory of
differential forms on dlt pairs is developed. It is shown that many of the
fundamental theorems and techniques known for sheaves of logarithmic
differentials on smooth varieties also hold in the dlt setting.
Immediate applications include the existence of a pull-back map for reflexive
differentials, generalisations of Bogomolov-Sommese type vanishing results, and
a positive answer to the Lipman-Zariski conjecture for klt spaces.Comment: 72 pages, 6 figures. A shortened version of this paper has appeared
in Publications math\'ematiques de l'IH\'ES. The final publication is
available at http://www.springerlink.co
2-elementary subgroups of the space Cremona group
We give a sharp bound for orders of elementary abelian 2-groups of birational
automorphisms of rationally connected threefolds
The Neron-Severi group of a proper seminormal complex variety
We prove a Lefschetz (1,1)-Theorem for proper seminormal varieties over the
complex numbers. The proof is a non-trivial geometric argument applied to the
isogeny class of the Lefschetz 1-motive associated to the mixed Hodge structure
on H^2.Comment: 16 pages; Mathematische Zeitschrift (2008
Multiple Mirror Manifolds and Topology Change in String Theory
We use mirror symmetry to establish the first concrete arena of spacetime
topology change in string theory. In particular, we establish that the {\it
quantum theories} based on certain nonlinear sigma models with topologically
distinct target spaces can be smoothly connected even though classically a
physical singularity would be encountered. We accomplish this by rephrasing the
description of these nonlinear sigma models in terms of their mirror manifold
partners--a description in which the full quantum theory can be described
exactly using lowest order geometrical methods.
We establish that, for the known class of mirror manifolds, the moduli space
of the corresponding conformal field theory requires not just two but {\it
numerous} topologically distinct Calabi-Yau manifolds for its geometric
interpretation. A {\it single} family of continuously connected conformal
theories thereby probes a host of topologically distinct geometrical spaces
giving rise to {\it multiple mirror manifolds}.Comment: 18 pp., (uses harvmac and epsf) (Missing reference added.
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