13 research outputs found

    A review of career devoted to biophotonics-in memoriam to Ekaterina Borisova (1978-2021)

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    Regretfully, because of her sudden demise, Assoc. Prof. Ekaterina Borisova is no longer amongst us. COVID-19 pulled away a brilliant scientist during the peak of her scientific career (see Fig. 1). All authors would like to express deepest condolences and sincere support to her family, friends, relatives and colleagues! We, therefore, rightfully commemorate her dedicated and devoted contribution to biophotonics, her readiness to always support, help, motivate and inspire all her colleagues and collaborators

    Mesoporous Ce-Fe-Ni nanocomposites encapsulated in carbon-nanofibers: Synthesis, characterization and catalytic behavior in oxygen evolution reaction

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    16 figures, 6 tables.-- Supplementary material available.Ceria-iron oxide mesoporous materials with Fe:Ce molar ratio of 5:5 and 9:1 were synthesized by hydrothermal method using CTAB as a template and subsequently modified with NiO (molar ratio Ni:Fe = 1:2) by incipient wetness impregnation technique. In order to increase the electro-capacitive properties and reduce the intrinsic impedance of the metal oxides, the samples were consecutively modified by reduction in hydrogen to obtain highly dispersed Ni–Fe alloys into ceria matrix. By exploiting the high permeability of carbon inside ferrous alloys, the metal phase has been further modified into ferrous carbides and metal alloys encapsulated within carbon nanofibers. For this purpose, a reaction, already widely studied for the production of hydrogen, was used, that is the decomposition of methanol vapors. In fact, this decomposition, in addition to producing syn-gas and methane, changes the catalysts in use through a chemical vapor deposition-carbon coating process. This fact, has been used by us to demonstrate how the newly obtained metal-carbon nanocomposites can be used for electro-catalytic purposes. The modified phases of the two molar ratios of the Fe–Ni–Ce catalysts were tested in the Oxygen Evolution Reaction (OER) in an alkaline environment (1 M KOH), showing a satisfactory and progressive increase in activity and a surprising decrease in the overpotential at 10 mA/cm2 of current density. The morphological, textural and physicochemical properties of the samples were characterized in details by XRD, N2-physisorption, TG-TPO, TEM, EDX, FTIR, XPS, Raman and Moessbauer spectroscopies.This research was funded by the BIKE project, which received funding from the European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement no. 813748.Peer reviewe

    Proposal for hadron production measurements using the NA49 detector for use in long-baseline and atmospheric neutrino flux calculations

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    O CIES Football Observatory é um site especializado na análise estatística do futebol. Foi fundado em 2005, por Raffaele Poli e Loïc Ravenel, aos quais se juntou Roger Besson, e é apoiado e enquadrado pelo Centre International d’Étude du Sport (Suíça). O prestígio deste Observatório reflete­-se nas inúmeras solicitações feitas por entidades como a Fédération Internationale de Football Association (FIFA), a Union of European Football Associations (UEFA), ou o Comité Olímpico Internacional. O t..
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