Synthesis and application of hemin copolymer as polymer reagents

Thesis--University of Tsukuba, D.Sc.(A), no. 648, 1989. 3. 2

Characteristics of two-phase flow heat transfer of R-22 and R-290 in horizontal circular small tube

Hydrocarbon refrigerants have been widely used to replace HFCs. As hydrocarbon, R- 290 has no ODP (Ozone Depletion Potential) and negligible GWP (Global Warming Potential). This paper presents flow boiling heat transfer in small tube with R-290 and R-22. The test tube has inner diameter of 7.6 mm and length of 1.07 m. In order to determine the heat transfer coefficient, experiments were carried out for heat fluxes ranging from 10 to 25 kW/m2K, mass fluxes ranging from 204 to 628 kg/m2s, and saturation temperatures ranging from 1.87 to 11.9o C. The study analyzed the heat transfer through the local heat transfer coefficient along the flow under the variation of these different parameters. In comparison with R-22, R-290 provides higher heat transfer coefficients. In the prediction of the heat transfer coefficients of R-22 and R-290, the correlation of Shah (1982) and Choi et.al. (2009) best fitted the present experimental result, respectively

Solution-processed n-type organic thin-film transistors with high field-effect mobility

We report the performance of solution-processed n-type organic thin-film transistors (OTFTs) based on C60 derivatives. Long-chain alkyl-substituted C60, C60-fused N-methylpyrrolidine-meta-C12 phenyl (C60MC12), was used as a semiconducting layer. The C60MC12-thin-film transistor shows high electron mobility of 0.067 cm2/V s in saturation regime. From the result of x-ray diffraction analysis, the C60MC12 active layer forms highly ordered crystalline film. We found that self-assemble ability of long alkyl chains plays an important role for fabrication of highly ordered crystalline film, leading to achievement of high electron mobility in solution-processed n-type OTFTs

Solution-processed n-type organic thin-film transistors with high field-effect mobility

We report the performance of solution-processed n-type organic thin-film transistors (OTFTs) based on C60 derivatives. Long-chain alkyl-substituted C60, C60-fused N-methylpyrrolidine-meta-C12 phenyl (C60MC12), was used as a semiconducting layer. The C60MC12-thin-film transistor shows high electron mobility of 0.067 cm2/V s in saturation regime. From the result of x-ray diffraction analysis, the C60MC12 active layer forms highly ordered crystalline film. We found that self-assemble ability of long alkyl chains plays an important role for fabrication of highly ordered crystalline film, leading to achievement of high electron mobility in solution-processed n-type OTFTs

Three-body Coulomb breakup of 11Li in the complex scaling method

Coulomb breakup strengths of 11Li into a three-body 9Li+n+n system are studied in the complex scaling method. We decompose the transition strengths into the contributions from three-body resonances, two-body ``10Li+n'' and three-body ``9Li+n+n'' continuum states. In the calculated results, we cannot find the dipole resonances with a sharp decay width in 11Li. There is a low energy enhancement in the breakup strength, which is produced by both the two- and three-body continuum states. The enhancement given by the three-body continuum states is found to have a strong connection to the halo structure of 11Li. The calculated breakup strength distribution is compared with the experimental data from MSU, RIKEN and GSI.Comment: RevTeX4, 6 pages, 4 figures, Accepted to Phys. Lett. B DOI

Specific Removal of Monocytes from Peripheral Blood of Septic Patients by Polymyxin B-immobilized Filter Column

Lipopolysaccharide (LPS) is one of the major causes of septic shock. The polymyxin B-immobilized filter column (PMX) was developed for the adsorption of endotoxin by direct hemoperfusion and has been used for the treatment of LPS-induced septic shock. In this study, we demonstrated that PMX also specifically bound monocytes from the peripheral blood leukocytes of septic patients by mean of an analysis of bound cells using immunocytochemical and electron microscopic techniques. The specific removal of monocytes from septic patients may produce beneficial effects by reducing the interaction between monocytes and functionally associated cells including vascular endothelial cells

Film Rupture And Partial Wetting Over Flat Surfaces

Various technical applications require conditions which prevent thin liquid films from breaking into a series of rivulets, leaving the solid surface partly uncovered and lowering the extension of the liquid free interface. What is needed is both a criterion for the stability of the film to identify the minimum flow rate able to ensure the complete wetting of the surface and, after the film rupture, a method to estimate the wet (active) part of the same surface. At low Reynolds and high Weber numbers, the assumptions of a film with uniform thickness and complete wetting of the transfer surface cannot be considered, even approximately, rigorous, hence, leading to unacceptable inaccuracy of simulation results of the transfer performance in that operative region. Accordingly, the inadequacy of previous theoretical models of devices that use falling films as transfer mediums can be ascribed to a major issue, namely the assumption of complete wetting. As they provide a simple variational method to solve complex, multi-variable problems and directly reach a rational explanation of physical phenomena, extremum principles have led to critical results in the theoretical and technical fields. Hamilton’s principle (or principle of least action), Gauss’ principle of least constraint, as well as Oasager’s extremum principle or Prigogine’s principle of minimum entropy production remain central in modern physics and engineering. In this context and with regard to the previously stated technical aim, the principle of minimising the energy of a given stream-wise section of the film is applied in order to model and investigate the film stability. Specifically, a criterion for defining the film stability is established for a rivulet cross-section shape suitable for predicting the transient evolution of the wetting ability under an imposed fluid distribution width. The evolution from uniform film to the stable rivulet configuration is estimated considering the energy of the system under a Lagrangian approach. The Lagrange equation is written with reference to a single generalized wetting coordinate and its time derivative, under the effect of Rayleigh\u27s dissipation function and a generalized force associated to a scalar potential defined as the energy excess with respect to the local energy minimum. This methodology is extended to include the hysteresis behaviour of the contact angle (considering advancing and receding contact angles) and wettability hysteresis when increasing or decreasing mass flow rates are delivered. Finally, a first qualitative and quantitative validation of the results is presented with reference to the visual data captured on a dedicated experimental test section