van der Waals materials for overcoming fundamental limitations in photonic integrated circuitry

With the advance of on-chip nanophotonics, there is a high demand for high-refractive-index and low-loss materials. Currently, this technology is dominated by silicon, but van der Waals (vdW) materials with a high refractive index can offer a very advanced alternative. Still, up to now, it was not clear if the optical anisotropy perpendicular to the layers might be a hindering factor for the development of vdW nanophotonics. Here, we studied WS2-based waveguides in terms of their optical properties and, particularly, in terms of possible crosstalk distance. Surprisingly, we discovered that the low refractive index in the direction perpendicular to the atomic layers improves the characteristics of such devices, mainly due to expanding the range of parameters at which single-mode propagation can be achieved. Thus, using anisotropic materials offers new opportunities and novel control knobs when designing nanophotonic devices.L.M.M. acknowledges Project PID2020-115221GB-C41, financed by MCIN/AEI/10.13039/501100011033, and the Aragon Government through Project Q-MAD. A.A.V., I.K., and D.I.Y. gratefully acknowledge the financial support from the Ministry of Science and Higher Education (Agreement No. 075-15-2021-606). I.A.K. gratefully acknowledges the financial support from the RSF (No. 22-19-00738) for first-principle calculations. K.S.N. is grateful to the Ministry of Education, Singapore (Research Centre of Excellence award to the Institute for Functional Intelligent Materials, I-FIM, project No. EDUNC-33-18-279-V12) and to the Royal Society (UK, grant number RSRP\R\190000) for support.Peer reviewe

Supplementary information for "Dual-band coupling of phonon and surface plasmon polaritons with vibrational and electronic excitations in molecules"

The dielectric functions of materials. SEM images of the Al ribbons. Analysis of the polaritonic modes in the nanoresonator heterostructure. Data processing of nanoimaging experiments. Comparison between the experimental and simulated extinction spectra. Details of the coupled classical harmonic oscillator fits.Peer reviewe

Graphene-Supported Thin Metal Films for Nanophotonics and Optoelectronics

Graphene-metal hybrid nanostructures have attracted considerable attention due to their potential applications in nanophotonics and optoelectronics. The output characteristics of devices based on such nanostructures largely depend on the properties of the metals. Here, we study the optical, electrical and structural properties of continuous thin gold and copper films grown by electron beam evaporation on monolayer graphene transferred onto silicon dioxide substrates. We find that the presence of graphene has a significant effect on optical losses and electrical resistance, both for thin gold and copper films. Furthermore, the growth kinetics of gold and copper films vary greatly; in particular, we found here a significant dependence of the properties of thin copper films on the deposition rate, unlike gold films. Our work provides new data on the optical properties of gold and copper, which should be considered in modeling and designing devices with graphene-metal nanolayers

Double-resonant second-harmonic generation in MoS2 nanoantennas

Molybdenum disulfide (MoS2) is a layered material of transition metal dichalcogenides (TMDCs) with a high refractive index in the visible and infrared spectral range. Therefore, by constructing MoS2 into dielectric nanoresonators, one can generate highly confined electromagnetic Mie-type modes. In this work, we applied lithography and etching techniques to single crystal MoS2 flakes to fabricate nanodisks that support magnetic dipole Mie resonances in near infrared spectral range. The nanodisks were studied by second-harmonic generation (SHG) rotational anisotropy revealing the retention of crystallinity and the orientation of the crystallographic axes of the single disk structure after fabrication. Magnetic dipole resonances manifest as resonant intensity enhancement in SHG spectra. Tuning Mie resonances by selecting the geometrical size of MoS2 nanodisks, we demonstrated strongly enhanced SHG due to the overlap of the optical resonance at the fundamental wavelength with the C-exciton resonance at the second-harmonic wavelength

Wandering principal optical axes in van der Waals triclinic materials

Abstract Nature is abundant in material platforms with anisotropic permittivities arising from symmetry reduction that feature a variety of extraordinary optical effects. Principal optical axes are essential characteristics for these effects that define light-matter interaction. Their orientation – an orthogonal Cartesian basis that diagonalizes the permittivity tensor, is often assumed stationary. Here, we show that the low-symmetry triclinic crystalline structure of van der Waals rhenium disulfide and rhenium diselenide is characterized by wandering principal optical axes in the space-wavelength domain with above π/2 degree of rotation for in-plane components. In turn, this leads to wavelength-switchable propagation directions of their waveguide modes. The physical origin of wandering principal optical axes is explained using a multi-exciton phenomenological model and ab initio calculations. We envision that the wandering principal optical axes of the investigated low-symmetry triclinic van der Waals crystals offer a platform for unexplored anisotropic phenomena and nanophotonic applications

Dual-Band Coupling of Phonon and Surface Plasmon Polaritons with Vibrational and Electronic Excitations in Molecules

Strong coupling (SC) between light and matter excitations bears intriguing potential for manipulating material properties. Typically, SC has been achieved between mid-infrared (mid-IR) light and molecular vibrations or between visible light and excitons. However, simultaneously achieving SC in both frequency bands remains unexplored. Here, we introduce polaritonic nanoresonators (formed by h-BN layers on Al ribbons) hosting surface plasmon polaritons (SPPs) at visible frequencies and phonon polaritons (PhPs) at mid-IR frequencies, which simultaneously couple to excitons and molecular vibrations in an adjacent layer of CoPc molecules, respectively. Employing near-field optical nanoscopy, we demonstrate the colocalization of near fields at both visible and mid-IR frequencies. Far-field transmission spectroscopy of the nanoresonator structure covered with a layer of CoPc molecules shows clear mode splittings in both frequency ranges, revealing simultaneous SPP–exciton and PhP–vibron coupling. Dual-band SC may offer potential for manipulating coupling between exciton and molecular vibration in future optoelectronics, nanophotonics, and quantum information applications