Polypyrrole Nanopipes as a Promising Cathode Material for Li-ion Batteries and Li-ion Capacitors : Two-in-One Approach

Lithium ion capacitor (LIC) is a promising energy storage system that can simultaneously provide high energy with high rate (high power). Generally, LIC is fabricated using capacitive cathode (activated carbon, AC) and insertion-type anode (graphite) with Li-ion based organic electrolyte. However, the limited specific capacities of both anode and cathode materials limit the performance of LIC, in particular energy density. In this context, we have developed "two in one" synthetic approach to engineer both cathode and anode from single precursor for high performance LIC. Firstly, we have engineered a low cost 1D polypyrrole nanopipes (PPy-NPipes), which was utilized as cathode material and delivered a maximum specific capacity of 126 mAh/g, far higher than that of conventional AC cathodes (35 mAh/g). Later, N doped carbon nanopipes (N-CNPipes) was derived from direct carbonization of PPy-NPipes and successfully applied as anode material in LIC. Thus, a full LIC was fabricated using both pseudo-capacitive cathode (PPy-NPipes) and anode (N-CNPipes) materials, respectively. The cell delivered a remarkable specific energy of 107 Wh/kg with maximum specific power of 10 kW/kg and good capacity retention of 93 % over 2000 cycles. Thus, this work provide a new approach of utilization of nanostructured conducting polymers as a promising pseudocapacitive cathode for high performance energy storage systems

Design principles and architecture of a second language learning chatbot

The purpose of this article is to set out the design principles and architecture of a second language (L2) learning voice chatbot. Building on L2 acquisition theories and chatbot research, in this article, we report on a South Korean government-funded longitudinal project in which we designed and developed a chatbot called “Ellie”. Chatbot Ellie has three chat modes, “General Chat,” “Task Chat,” and “Skills”. In the General Chat mode, L2 users can have short talks about personal information, whereas in the Task Chat mode, they can engage in a wide range of problem-solving L2 tasks to achieve task goals by exchanging meanings with Ellie. The Skills mode offers form-focused language practice. Ellie was piloted among 137 Korean high school students, who used Ellie individually or in a group, for seven weeks in their English classes. The quality of the chatbot was investigated in terms of the appropriateness of language level, continuity of conversation, and success in task performance. Based on the results of the pilot, Ellie appears to have considerable potential to become an effective language learning companion for L2 learners, and has implications for the design and developments of future L2 chatbots

An inclusive measurement of the photon energy spectrum in b->s gamma decays

We report a fully inclusive measurement of the flavour changing neutral current decay b->s gamma in the energy range 1.8 GeV < E* < 2.8 GeV, covering 95% of the total spectrum. Using 140 fb^-1 we obtain BF(b->s gamma)= 3.55 +/- 0.32 +0.30-0.31 +0.11-0.07, where the errors are statistical, systematic and from theory corrections. We also measure the first and second moments of the photon energy spectrum above 1.8 GeV and obtain = 2.292 +/- 0.026 +/- 0.034 GeV and -^2 = 0.0305 +/- 0.0074 +/- 0.0063 GeV^2, where the errors are statistical and systematic.Comment: RevTex4, 6 pages, Submitted to Phys.Rev.Lett. Replaced: added table of systematic errors. New results take into account radiative J/Psi decay

Search for tau -> e gamma decay at Belle

We have searched for the lepton-flavor-violating decay tau -> e gamma using a data sample of 86.7/fb collected with the Belle detector at the KEKB asymmetric e^+ e^- collider. No evidence for a signal is obtained, and we set an upper limit for the branching fraction Br(tau -> e gamma) < 3.9 x 10^-7 at the 90% C.L.Comment: 11 pages, 10 figures, ReVTeX4, eps

Measurements of Branching Fractions and CP Asymmetries in B-> etah Decays

We report measurements of B to pseudoscalar-pseudoscalar decays with at least one eta meson in the final state using 140 fb^{-1} of data collected by the Belle detector at KEKB e^+ e^- collider. We observe the decay B^+-> eta pi^+ and find evidence of B^+-> eta K+; the measured branching fractions are B(B^+-> eta pi^+)=(4.8^{+0.8}_{-0.7}(stat) +- 0.3(sys))*10^{-6} and B(B^+-> eta K^+)=(2.1 +- 0.6(stat)+- 0.2(sys))*10^{-6}. Their corresponding CP violating asymmetries are measured to be 0.07+- 0.15 (stat) +- 0.03(sys) for eta pi^+- and -0.49+- 0.31 (stat) +- 0.07(sys) for eta K^+-. No significant signals are found for neutral B->eta h decays. We report the following upper limits on branching fractions at the 90% confidence level: B(B-> eta K^0 < 2.0* 10^{-6}, B(B-> eta pi0) eta eta) <2.0*10^{-6}.Comment: 7 pages, 2 figure

Measurement of Time-Dependent CP-Violating Asymmetries in B0→KsKsKsB_0 \to K_sK_sK_s Decay

We present a measurement of CP-violation parameters in the B0 -> KsKsKs decay based on a sample of 275 x 10^6 BBbar pairs collected at the Upsilon(4S) resonance with the Belle detector at the KEKB energy-asymmetric e+e- collider. One neutral B meson is fully reconstructed in the decay B0 -> KsKsKs, and the flavor of the accompanying B meson is identified from its decay products. CP-violation parameters are obtained from the asymmetry in the distributions of the proper-time interval between the two B decays: S = +1.26 +/- 0.68(stat) +/- 0.20(syst) and A = +0.54 +/- 0.34(stat) +/- 0.09(syst).Comment: 10 pages, 2 figures 10 pages, 2 figure

Measurements of Branching Fractions and Polarization in B > K^* rho Decays

We present results of a study of the charmless vector-vector decays B^0 -> K^{*0} rho^0 and B^+ ->K^{*0} rho^+. The results are based on a 140 fb^{-1} data sample collected by the Belle detector at the KEKB asymmetric e^+e^- collider. We obtain the branching fraction B(B^+ -> K^{*0} rho^+)=(6.6 +- 2.2(stat.) +- 0.8 (syst.)) x 10^{-6}, and set upper limits on the branching fractions B(B^0 -> K^{*0} rho^0) f_0(980) K^{*0})<5.2 x 10^{-6}. We also perform a helicity analysis of the rho and K^* vector mesons in the decay B^+ -> K^{*0} rho^+, and obtain the longitudinal polarization fraction R_0(B^+ -> K^{*0} rho^+)=0.50 +- 0.19(stat.)+0.05-0.07}(syst.).Comment: 11 pages, 4 figures, submitted to ICHEP04, Beijing, Chin

Observation of a narrow charmonium-like state in exclusive B+ -> K+ pi+pi- J/psi decays

We report the observation of a narrow charmonium-like state produced in the exclusive decay process B+ -> K+ pi+pi- J/psi. This state, which decays into pi+pi- J/psi, has a mass of 3872.0+-0.6(stat)+-0.5(syst) MeV, a value that is very near the M_D + M_D* mass threshold. The results are based on an analysis of 152M B-Bbar events collected at the Upsilon(4S) resonance in the Belle detector at the KEKB collider. The statistical significance of the signal is in excess of 10 sigma.Comment: 10 pages 4 figures, submitted to Physical Review Letter

Spectra of prompt electrons from decays of B+ and B0 mesons and ratio of inclusive semielectronic branching fractions

We present spectra of prompt electrons from decays of neutral and charged B mesons. The results are based on 140 /fb of data collected by the Belle detector on the Upsilon(4S) resonance at the KEKB e+e- asymmetric collider. We tag Upsilon(4S) -> B \bar{B} events by reconstructing a B meson in one of several hadronic decay modes; the semileptonic decay of the other B meson is inferred from the presence of an identified electron. We obtain for charged and neutral B mesons the partial rates of semileptonic decay, to electrons with momentum greater than 0.6 GeV/c in the B rest frame, and their ratio b_+/b_0 = 1.08 +- 0.05 +- 0.02, where the first and second errors are statistical and systematic, respectively.Comment: 16 pages, 2 figure files, submitted to Phys. Lett.

Measurement of branching fraction ratios and CP asymmetries in B±→DCPK±B^{\pm} \to D_{CP}K^{\pm}

We report results on the decay $B^{-} \to D_{CP}K^{-}$ and its charge conjugate using a data sample of 85.4 million $B\bar{B}$ pairs recorded at the $\Upsilon(4S)$ resonance with the Belle detector at the KEKB asymmetric $e^{+}e^{-}$ storage ring. Ratios of branching fractions of Cabibbo-suppressed to Cabibbo-favored processes are determined to be ${\cal B}(B^- \to D^0 K^-)/{\cal B}(B^- \to D^0 \pi^-)= 0.077 \pm 0.005(stat) \pm 0.006(sys)$, ${\cal B}(B^- \to D_1 K^-)/{\cal B}(B^- \to D_1 \pi^-) = 0.093 \pm 0.018(stat) \pm 0.008(sys)$ and ${\cal B}(B^- \to D_2 K^-)/{\cal B}(B^- \to D_2 \pi^-) = 0.108 \pm 0.019(stat) \pm 0.007(sys)$ where the indices 1 and 2 represent the CP=+1 and CP=$-$1 eigenstates of the $D^{0}-\bar{D^{0}}$ system, respectively. We find the partial-rate charge asymmetries for $B^{-} \to D_{CP}K^{-}$ to be ${\cal{A}}_1 = 0.06 \pm 0.19(stat) \pm 0.04(sys)$ and ${\cal{A}}_2 = -0.19 \pm 0.17(stat) \pm 0.05(sys)$.Comment: 10 pages, 3 figures, submitted to Physical Review