45 research outputs found
Electric double layer effect on observable characteristics of the tunnel current through a bridged electrochemical contact
Continuous dielectric permittivity II: An Iterative Method for Calculating the Polar Component of the Molecular Solvation Gibbs Energy Under a Smooth Change in the Dielectric Permittivity of a Solution
An iterative method for calculating the polar component of the solvation
Gibbs energy under a smooth change in dielectric permittivity, both between a
substrate and a solvent and in a solvent is formulated on the basis of a
previously developed model. The method is developed in the approximation of the
local relationship D = \eps (r) E between the displacement vectors D and the
electric field intensity E.Comment: 36 pages,3 Figures, in English and in Russia
Long-range intramolecular electron transfer in aromatic radical anions and binuclear transition metal complexes
Photoinduced Excited State Electron Transfer at Liquid/Liquid Interfaces
Several aspects of the photoinduced electron transfer (ET) reaction betweencoumarin 314 (C314) and N,N-dimethylaniline (DMA) at the water/DMA interface areinvestigated by molecular dynamics simulations. New DMA and water/DMA potentialenergy surfaces are developed and used to characterize the neat water/DMA interface.The adsorption free energy, the rotational dynamics and the solvation dynamics of C314at the liquid/liquid interface are investigated and are generally in reasonable agreementwith available experimental data. The solvent free energy curves for the ET reactionbetween excited C314 and DMA molecules are calculated and compared with thosecalculated for a simple point charge model of the solute. It is found that thereorganization free energy is very small when the full molecular description of the soluteis taken into account. An estimate of the ET rate constant is in reasonable agreement withexperiment. Our calculations suggest that the polarity of the surface “reported” by thesolute, as reflected by solvation dynamics and the reorganization free energy, is strongly solute-dependent
Use of the dielectric sphere model for the calculation of the effect of a solvent on the kinetics of chemical reactions with charge transer. Communication 1. Energy of reorganization of a polar medium
An approach to long-range electron transfer mechanisms in metalloproteins: In situ scanning tunneling microscopy with submolecular resolution
In situ scanning tunneling microscopy (STM) of redox molecules, in aqueous solution, shows interesting analogies and differences compared with interfacial electrochemical electron transfer (ET) and ET in homogeneous solution. This is because the redox level represents a deep indentation in the tunnel barrier, with possible temporary electronic population. Particular perspectives are that both the bias voltage and the overvoltage relative to a reference electrode can be controlled, reflected in spectroscopic features when the potential variation brings the redox level to cross the Fermi levels of the substrate and tip. The blue copper protein azurin adsorbs on gold(111) via a surface disulfide group. Well resolved in situ STM images show arrays of molecules on the triangular gold(111) terraces. This points to the feasibility of in situ STM of redox metalloproteins directly in their natural aqueous medium. Each structure also shows a central brighter contrast in the constant current mode, indicative of 2- to 4-fold current enhancement compared with the peripheral parts. This supports the notion of tunneling via the redox level of the copper atom and of in situ STM as a new approach to long-range electron tunneling in metalloproteins