Supercritical Carbon Dioxide Extraction

The objective of this thesis is to explore the properties of supercritical carbon dioxide (CO2). In addition, the feasibility of building a small-scale low cost system will be explained. A supercritical fluid is a fluid which exhibits properties between liquid and gas with liquid like densities and viscosities similar to a gas. Since the discovery of supercritical fluids in 1822, the use of supercritical fluids, specifically supercritical CO2, has grown in popularity. The application of supercritical CO2 has continued to grow in industrial applications since the 1970’s. Supercritical CO2’s has many beneficial properties as a “green” solvent. Supercritical CO2 as a solvent is able to be implemented in a wide range of applications from aerospace, microchip manufacturing, food production, biomedical, pharmaceutical, dry-cleaning, and many more. This thesis project included designing, building and testing a supercritical CO2 extraction apparatus that examines the use of supercritical CO2 as a solvent in the extraction process of decaffeinating coffee. Due to the fact that supercritical CO2 requires high pressure operating conditions, the apparatus design is important not only for function but also for safety. In the description portion of this paper, design considerations related to each component’s function and their specific roles in the overall system are clearly stated. Furthermore, the build process is outlined along with the overall step-by-step operation of the apparatus. Different methods of data measurements are taken while the system is running, in order to interpret the apparatus’ overall functionality. Through the exploration of this experimental data, the results were compared between different operating parameters. In order to determine the feasibility of the supercritical apparatus, the devise was tested by applying the supercritical CO2 as a solvent for the extraction of caffeine from coffee beans. Analysis of the analytical data recorded from experimental testing confirms that the apparatus produced supercritical CO2. After testing specific operating conditions, it is proven that the supercritical CO2 is able to function as a “green” solvent in this small-scale system. The experimental results from these analytical runs are compared with theoretical maximums in order to determine the efficiency of the devise. Lastly, the paper presents an overview including lessons learned from the design process and from the information gathered. Data from experimental testing is interpreted and the system design is reevaluated with suggestions for future improvements

Investigation of in-situ parameter control in novel semiconductor optical amplifiers

Fibre optic networks form the backbone of modern communications systems. As demand for ever increasing bandwidth continues to grow, technologies that enable the expansion of optical networks will be the key to future development. The semiconductor optical amplifier (SOA) is a technology that may be crucial in future optical networks, as a low cost in-line amplifier or as a functional element. As fibre networks extend closer to the end user, economical ways of improving the reach of these networks are important. SOAs are small, relatively inexpensive and can be readily integrated in photonic circuits. Problems persist with the development of SOAs, however, in the form of a relatively high noise figure and low saturation output power, which limits their use in many circumstances. The aim of this thesis is to outline a concept for control of these parameters such that the SOA can achieve the performance required. The concept relies on the control of the carrier density distribution in the SOA. The basic characteristics of the SOA and how they are affected by changes in the carrier density are studied. The performance of the SOA in linear and high power transmission of CW and pulsed signals is determined. Finally, the wavelength conversion characteristics of the SOA are outlined. The role of the carrier density control in shaping all of these characteristics will be explained

Novel design for noise controlled semiconductor optical amplifier

The use of semiconductor optical amplifiers (SOA) in optical communications networks has so far been limited due to their inherent large noise figure (NF) compared to Erbium Doped Fibre Amplifiers. Therefore improvement of the noise performance of SOAs is critical to their widespread adoption in future networks. We propose to reduce the NF of the SOA by introducing a lasing cavity lateral to the axis of amplification of the device. The carrier density within the cavity is clamped at the lasing threshold. It is thus possible to engineer the carrier density distribution along the active waveguide by controlling the cavity design. According to our simulations, some of the cavity designs lead to a reduction of the noise figure in this novel SOA

Semiconductor optical amplifier-based heterodyning detection for resolving optical terahertz beat-tone signals from passively mode-locked semiconductor lasers

An all-optical heterodyne approach based on a room-temperature controlled semiconductor optical amplifier (SOA) for measuring the frequency and linewidth of the terahertz beat-tone signal from a passively mode-locked laser is proposed. Under the injection of two external cavity lasers, the SOA acts as a local oscillator at their detuning frequency and also as an optical frequency mixer whose inputs are the self-modulated spectrum of the device under test and the two laser beams. Frequency and linewidth of the intermediate frequency signal and therefore, the beat-tone signal are resolved by using a photodiode and an electrical spectrum analyze

Titan Talks: The State of Fraternity and Sorority Life at Illinois Wesleyan

Illinois Wesleyan University\u27s Fraternity and Sorority Life purpose is to cultivate a sense of community and belonging, while building successful, thriving students! Come join university staff and student leaders as they share the successes and opportunities within our fraternity and sorority community. Information will be shared regarding academic experiences, health and safety prevention, membership development, recruitment and retention, and relationship and community building. You will also hear about the success of our chapters and councils, as they describe goals and met and achievements made through our Chapter Thrive Program. We look forward to engaging and updating our alumni community on the continued importance fraternity and sorority can have on individual students at Illinois Wesleyan University

Chronic brain stimulation using Micro-ECoG devices

Recording and stimulating brain activity has had great success both as a research tool and as a clinical technique. Neural prosthetics can replace limbs, restore hearing, and treat disorders like Parkinson’s and epilepsy, but are relatively crude. Current neural prosthetic systems use penetrating electrodes to achieve high precision, but the invasive nature of these devices provoke a strong immune response that limits chronic use. (Polikov et al) In our study we evaluate micro-electrocortiographic (micro-ECoG) devices which sit under the skull and on the surface of the brain for stimulation over chronic timescales. We anticipate these devices with their less invasive placement will evoke less extreme immune responses compared to penetrating electrodes and allow for stable stimulation over long periods of time (months to years). These devices were developed by the NITRO Lab of University of Wisconsin. (Thongpang et al) In short, Sprague Dawley rats were implanted with micro-ECoG devices over either somatosensory or auditor cortex. They were stimulated electrically through these devices on a daily basis to evaluate their chronic performance in vivo. Sensitivity to stimulation was determined via an operant behavioral task and the implants’ electrical properties were measured daily to monitor functionality and approximate of the immune response. After at least two months of implantation, animals were perfused and a histological analysis was performed to evaluate the chronic immune response. From preliminary results we expect to see that the micro-ECoG devices are capable of long term stimulation and evoke a smaller immune response from the brain than penetrating neural implants. In addition, we have found that removing the dura in rats for device implantation causes significant brain swelling, which indicates a strong immune response preventing effective stimulation. This research shows that micro-ECoG devices can chronically stimulate brain tissue and show great promise as a less invasive method of neural interfacing compared to traditional penetrating electrodes

Ballistics Analysis of Orion Crew Module Separation Bolt Cover

NASA is currently developing a new crew module to replace capabilities of the retired Space Shuttles and to provide a crewed vehicle for exploring beyond low earth orbit. The crew module is a capsule-type design, which is designed to separate from the launch vehicle during launch ascent once the launch vehicle fuel is expended. The separation is achieved using pyrotechnic separation bolts, wherein a section of the bolt is propelled clear of the joint at high velocity by an explosive charge. The resulting projectile must be contained within the fairing structure by a containment plate. This paper describes an analytical effort completed to augment testing of various containment plate materials and thicknesses. The results help guide the design and have potential benefit for future similar applications

Micro-and macro-plastics in marine species from Nordic waters

This report summarises the knowledge on plastics in Nordic marine species. Nordic biota interacts with plastic pollution, through entanglement and ingestion. Ingestion has been found in many seabirds and also in stranded mammals. Ingestion of plastics has been documented in 14 fish species, which many of them are of ecology and commercially importance. Microplastics have also been found in blue mussels and preliminary studies found synthetic fibres in marine worms. Comparability between and within studies of plastic ingestion by biota from the Nordic environment and other regions are difficult as there are: few studies and different methods are used. It is important that research is directed towards the knowledge gaps highlighted in this report, to get a better understanding on plastic ingestion and impact on biota from the Nordic marine environment

Kinetic and structural mechanism for DNA unwinding by a non-hexameric helicase

UvrD, a model for non-hexameric Superfamily 1 helicases, utilizes ATP hydrolysis to translocate stepwise along single-stranded DNA and unwind the duplex. Previous estimates of its step size have been indirect, and a consensus on its stepping mechanism is lacking. To dissect the mechanism underlying DNA unwinding, we use optical tweezers to measure directly the stepping behavior of UvrD as it processes a DNA hairpin and show that UvrD exhibits a variable step size averaging ~3 base pairs. Analyzing stepping kinetics across ATP reveals the type and number of catalytic events that occur with different step sizes. These single-molecule data reveal a mechanism in which UvrD moves one base pair at a time but sequesters the nascent single strands, releasing them non-uniformly after a variable number of catalytic cycles. Molecular dynamics simulations point to a structural basis for this behavior, identifying the protein-DNA interactions responsible for strand sequestration. Based on structural and sequence alignment data, we propose that this stepping mechanism may be conserved among other non-hexameric helicases

Mid-Infrared InP-Based Discrete Mode Laser Diodes

Low cost, compact and robust single mode semiconductor laser diodes emitting at λ ∼ 1.6–2.1 μm are highly desirable as light sources for trace gas spectroscopy and an increasing number of other applications, such as, high data-rate communications over hollow core photonic crystal fibre, noninvasive optical blood glucose monitoring. Indium phosphide based light sources provide a solid and flexible base for mid-infrared semiconductor diode lasers. This chapter provides an overview of the current state of the art in discrete mode InGaAs/InP long-wavelength quantum-well lasers emitting in the 1.6–2.1 μm wavelength range. The discrete mode laser is essentially a regrowth free modified ridge waveguide Fabry-Pérot laser whose optical spectrum has a single wavelength mode. High-performance and cost-effective mid-infrared DM laser diode sources are well suited to a wide range of sensor applications. The current state of the art will also be outlined in this chapter