Magnetic Properties and Magnetocaloric Effect in Layered NdMn1.9Ti0.1Si2

The structural and magnetic properties of the NdMn1.9Ti0.1Si2 compund have been studied by high-intensity x-ray and high-resolution neutron powder diffraction, specific heat, dc magnetization, and differential scanning calorimetry measurements over the temperature range of 3-450 K. The Curie temperature and Néel temperature of layered NdMn1.9Ti0.1Si2 are indicated as TC ~ 22 K and TN ~ 374 K respectively. The first order magnetic transition from antiferromagnetic [AFil-type] to ferromagnetic [F(Nd)+Fmc] around TC is found in layered NdMn1.9Ti0.1Si2and is associated with large magnetocaloric effect. This behavior has been confirmed as a contribution of the magnetostructural coupling by using neutron and x-ray powder diffraction. The magnetic entropy change –ΔSM ~ 15.3 J kg-1 K-1 and adiabatic temperature change ΔTad ~ 4.7 K have been determined using magnetization and specific heat measurement under 0-5 T applied fields. This compound exhibits almost no thermal and magnetic hysteresis, thus potentially applicable in low temperature region for magnetic refrigerator material.Received: 31 December 2013; Revised:10 February 2014; Accepted: 24 February 201

The Papal Encyclical Laudato Si’

This article seeks to reflect upon Laudato Si’, the papal encyclical on ecology and sustainable development, and uncover its apparent philosophical and practical approach to the environment. It begins with a discussion of paradigms of thought that outline the new ecological paradigm (NEP) suggested in the ecological literature, thereby helping to situate the ecosophy of Laudato Si’ within current thought. As we will show, Laudato Si’ differs from the NEP by linking the poor to our approach to sustainability and in its consideration of integral ecology. Specific principles for sustainability in business are then identified and strategic approaches are recommended, as are guidelines for an eco-justice approach to business and business education

Corporate Social Responsibility and the New Governance: In Search of Epstein\u27s Good Company in the Employment Context

The purpose of this Article is to apply Epstein’s Good Company framework to corporate behavior that falls under three distinct employment law issues31 that continually challenge TNCs as they conduct business. Part I summarizes Epstein’s Good Company framework and his insights about the Good Company. Part II integrates Epstein’s Good Company framework with TNCs’ ability to curb the use of abusive forms of child labor (enact responsible child labor policies), foster open, democratic, and collaborative workplaces (improved employer-employee bargaining), and to create an ethic of care for employees (ethic of care). Part III briefly analyzes our findings, suggests modifications to Epstein’s Good Company framework, and positions the modifications in the context of New Governance scholarship. The article concludes by affirming Epstein’s approach to the Good Company and offers final reflections about fostering Good Companies in the employment context

The cost of moderate and severe COPD exacerbations to the Canadian healthcare system

SummaryBackgroundThe cost of exacerbations in chronic obstructive pulmonary disease (COPD) has not been well studied. The aim of this study was to identify and quantify the (average) cost of moderate and severe exacerbations (ME and SE, respectively) from a Canadian perspective.MethodsResources used during ME and SE were identified in a year long prospective, observational study (Resource Utilization Study In COPD (RUSIC)). The units of analysis were ME and SE. Unit costs (2006$CAN), based on provincial, hospital and published sources, were applied to resources. The overall cost per ME and SE were calculated. The population burden of exacerbations was also calculated.ResultsAmong study participants (N=609, aged 68.6±9.4 years, 58.3$126 (N=574) and $515 (N=105), respectively. The average overall cost of a ME was$641. For SEs, the average hospital stay was 10.0 days. The overall mean costs of outpatient, ED and hospitalization services for SE were $114 (N=44),$774 (N=140) and $8669 (N=151), respectively. The average overall cost of a SE was$9557.ConclusionThe economic burden associated with MEs and especially SEs, in Canada, is considerable and likely has a substantial impact on healthcare costs. The overall burden of exacerbations has been estimated in the range of $646 million to$736 million per annum

Magnetocaloric effect and magnetostructural coupling in Mn0.92Fe0.08CoGe compound

The structural properties of Mn0.92Fe0.08CoGe have been investigated in detail using synchrotron x-ray diffraction in zero and applied pressure (p = 0-10 GPa). A ferromagnetic transition occurs around TC = 300 K and a large magnetic-entropy change -ΔSM = 17.3 J/kg K detected at TC for a field change of ΔB = 5 T. The field dependence of -ΔSM max can be expressed as -ΔSM max ∞ B. At ambient temperature and pressure, Mn0.92Fe0.08CoGe exhibits a co-existence of the orthorhombic TiNiSi-type structure (space group Pnma) and hexagonal Ni2In-type structure (space group P63/mmc). Application of external pressure drives a structure change from the orthorhombic TiNiSi-type structure to the hexagonal Ni2In-type structure. A large anomaly in heat capacity around TC is detected and the Debye temperature θD (=319(±10) K) has been derived from analyses of the low temperature heat capacity, T ≲ 10 K

Do insect outbreaks reduce the severity of subsequent forest fires?

Understanding the causes and consequences of rapid environmental change is an essential scientific frontier, particularly given the threat of climate- and land use-induced changes in disturbance regimes. In western North America, recent widespread insect outbreaks and wildfires have sparked acute concerns about potential insect-fire interactions. Although previous research shows that insect activity typically does not increase wildfire likelihood, key uncertainties remain regarding insect effects on wildfire severity (i.e., ecological impact). Recent assessments indicate that outbreak severity and burn severity are not strongly associated, but these studies have been limited to specific insect or fire events. Here, we present a regional census of large wildfire severity following outbreaks of two prevalent bark beetle and defoliator species, mountain pine beetle (Dendroctonus ponderosae) and western spruce budworm (Choristoneura freemani), across the US Pacific Northwest. We first quantify insect effects on burn severity with spatial modeling at the fire event scale and then evaluate how these effects vary across the full population of insect-fire events (n = 81 spanning 1987-2011). In contrast to common assumptions of positive feedbacks, we find that insects generally reduce the severity of subsequent wildfires. Specific effects vary with insect type and timing, but both insects decrease the abundance of live vegetation susceptible to wildfire at multiple time lags. By dampening subsequent burn severity, native insects could buffer rather than exacerbate fire regime changes expected due to land use and climate change. In light of these findings, we recommend a precautionary approach when designing and implementing forest management policies intended to reduce wildfire hazard and increase resilience to global change

Neural Networks, Heart Attack and Bayesian Decisions: An Application of the Boltzmann Perceptron Network

A decision aid is proposed for the diagnosis of the most commonly occurring cause of emergency admission to hospital in the developed world-acute myocardial infarction, or heart attack. The motivation for the proposal lies in the Bayesian ( minimum risk)decision theory which is briefly reviewed. The fact that many feedforward artificial neural networks are known to estimate the conditional class probabilities required for Bayesian decision theory is explored and one candidate-the Boltzmann Perceptron Network-is selected as possessing the most desirable properties. A brief account of the theory (based upon the so-called Boltzmann machine) underlying this little known network is presented. The Boltzmann Perceptron Network is trained to diagnose the presence or absence of myocardial infarction on data gathered from a large UK teaching hospital and is found to perform as well as senior registras with specific cardiological training (diagnostic accuracy in excess of 80%). In addition, the Boltzmann Perceptron Network is found to provide greater user confidence than the multi-layer Perceptron