A synopsis of the Joint Environment and Human Health Programme in the UK

The Joint Environment and Human Health (E&HH) Programme has explored how both man-made and natural changes to the environment can influence human health. Scientists have tackled the complicated mix of environmental, social and economic factors that influence health, particularly focusing on naturally occurring toxins, man-made pollutants, nanoparticles and pathogens to see

Sr-Nd-Pb-Hf isotope results from ODP Leg 187: Evidence for mantle dynamics of the Australian-Antarctic Discordance and origin of the Indian MORB source

New high precision PIMMS Hf and Pb isotope data for 14–28 Ma basalts recovered during ODP Leg 187 are compared with zero-age dredge samples from the Australian-Antarctic Discordance (AAD). These new data show that combined Nd-Hf isotope systematics can be used as an effective discriminant between Indian and Pacific MORB source mantle domains. In particular, Indian mantle is displaced to lower εNd and higher εHf ratios compared to Pacific mantle. As with Pb isotope plots, there is almost no overlap between the two mantle types in Nd-Hf isotope space. On the basis of our new Nd-Hf isotope data, we demonstrate that Pacific MORB-source mantle was present near the eastern margin of the AAD from as early as 28 Ma, its boundary with Indian MORB-source mantle coinciding with the eastern edge of a basin-wide arcuate depth anomaly that is centered on the AAD. This observation rules out models requiring rapid migration of Pacific MORB mantle into the Indian Ocean basin since separation of Australia from Antarctica. Although temporal variations in isotopic composition can be discerned relative to the fracture zone boundary of the modern AAD at 127°E, the distribution of different compositional groups appears to have remained much the same relative to the position of the residual depth anomaly for the past 30 m.y. Thus significant lateral flow of mantle along the ridge axis toward the interface appears unlikely. Instead, the dynamics that maintain both the residual depth anomaly and the isotopic boundary between Indian and Pacific mantle are due to eastward migration of the Australian and Antarctic plates over a stagnated, but slowly upwelling, slab oriented roughly orthogonal to the ridge axis. Temporal and spatial variations in the compositions of Indian MORB basalts within the AAD can be explained by progressive displacement of shallower Indian MORB-source mantle by deeper mantle having a higher εHf composition ascending ahead of the upwelling slab. Models for the origin of the distinctive composition of the Indian MORB-source based on recycling of a heterogeneous enriched component that consist of ancient altered ocean crust plus<10% pelagic sediment are inconsistent with Nd-Hf isotope systematics. Instead, the data can be explained by a model in which Indian mantle includes a significant proportion of material that was processed in the mantle wedge above a subduction zone and was subsequently mixed back into unprocessed upper mantle

Pervasive mantle plume head heterogeneity: Evidence from the late Cretaceous Caribbean-Colombian oceanic plateau

In SW Colombia picritic pillow lavas and tuffs, as well as breccias composed of picritic clasts, occur interspersed with basalts of the Central Cordillera and represent accreted portions of the ∼90 Ma Colombian/Caribbean oceanic plateau (CCOP). We present new geochemical data for these picrites and high-MgO basalts from SW Colombia, along with new data from Deep Sea Drilling Project Leg 15 drill sites. The 40Ar/39Ar ages for the CCOP in the Central Colombian Cordillera range from 87 to 93 Ma. Both SW Colombia picrites and Leg 15 basalts are compositionally diverse and range from reasonably enriched ((La/Nd)n > 1 and (εNd)i +8.0). Nb/Y and Zr/Y systematics suggest that the depleted component is not depleted MORB mantle, but is an intrinsic part of the plume. The bulk of the CCOP compositions can be explained by mixing between this depleted mantle and a HIMU component. However, radiogenic isotope systematics indicate the presence of an EM2 (or possibly EM1) component within the plume. Mantle melt modeling suggests that the enriched magma types are the product of deeper, small degree melting of a pervasively heterogeneous plume comprising a refractory matrix with enriched streaks/blobs, whereas shallower, more extensive melting, results in the formation of relatively depleted magmas

Large Scale Biodiversity, Environmental Gradients and Ecosystem Sustainability. Report on workshop outputs from Marine and Terrestrial & Freshwater community perspectives (15th and 16th December 2008)

This document outlines the objectives, background and outcomes of two workshops held at the Defra Innovation Centre, Reading on 15-16 December 2008. These workshops were held to help develop the ‘ecosystem sustainability’ priority action of the 2008 Biodiversity Theme Action Plan, to inform our understanding of biodiversity functions and processes across scales and systems. Introductory and background material are given in Section 1 and Annexes 1-4, with reports from the marine workshop in Section 2 and from the terrestrial and freshwater workshop in Section 3. Both workshops identified priority questions; assessed different approaches for addressing these questions; and commented on issues, concerns and opportunities that a large-scale study of ecosystem sustainability could offer. The main outcomes of the two workshops were as follows. i) All research communities (marine, terrestrial and freshwater) recognised that a large-scale, long term and collaborative biodiversity initiative would provide unique and exciting opportunities to advance scientific knowledge of ecosystem services and sustainability. ii) No single priority research question was identified. However, both workshops emphasised the need to increase fundamental understanding of ecosystem sensitivity to change (tipping points, non-linearities and resilience) and ecosystem functioning across different scales, in order to improve management advice in a broader socio-economic context. These issues are closely linked. iii) Focussing research effort on a single site was not favoured. Instead, both workshops preferred a nested, multi-site study that could cover a relatively wide geographic range and would include process-based experimental studies. iv) Resource constraints, gaps in the national skills base and community cohesion were identified as issues requiring further consideration if viability and success of the programme is to be assured. v) All research communities recognised the need for a clear, well-defined and appropriately funded work plan with defined aims and the establishment of a strong governance structure to ensure community cohesion and delivery of interdisciplinary science of societal value

Evaluation of the effects of alteration and leaching on Sm-Nd and Lu-Hf systematics in submarine mafic rocks

Nd and Hf isotope systematics of oceanic basaltic rocks are often assumed to be largely immune to the effects of hydrothermal alteration. We have tested this assumption by comparing Nd and Hf isotope data for acid-leached Cretaceous oceanic basalts from Gorgona and DSDP Leg 15 with unleached data on the same rocks. Hf isotope values and Lu/Hf ratios are relatively unaffected by leaching, but 143Nd/144Nd values of leached samples are significantly higher than those of unleached fractions of the same sample in most cases. Furthermore, the Sm/Nd ratios of the majority of leached samples are 10–40% greater than those of unleached samples. X-ray diffraction studies indicate that selective removal of secondary minerals, such as smectite, during the acid leaching process is responsible for the fractionation of Sm/Nd ratios. These results have implications for interpretation of the Hf–Nd isotope systematics of ancient submarine rocks (older than ~ 50 Ma), as (1) the age-corrected 143Nd/144Nd ratio may not be representative of the primary magmatic signature and (2) the uncertainty of the age-corrected εNd value may exceed the assumed analytical precision

Geochemistry and isotopic composition of gabbros from ODP Hole 118-375B

Gabbros drilled from the shallow (720 m) east wall of the Atlantis II transform on the Southwest Indian Ridge (SWIR; 32°43.40', 57°16.00') provide the most complete record of the stratigraphy and composition of the oceanic lower crust recovered from the ocean basins to date. Lithologies recovered include gabbro, olivine gabbro, troctolite, trondhjemite, and unusual iron-titanium (FeTi) oxide-rich gabbro containing up to 30% FeTi oxides. The plutonic rock sequence represents a tholeiitic fractionation trend ranging from primitive magmas having Mg numbers of 67 to 69 that fractionated troctolites, to highly evolved liquids that crystallized two-pyroxene, FeTi oxide-rich gabbros and, ultimately, trondhjemite. Isotopic compositions of unaltered Leg 118 gabbros are distinct from Indian Ocean mid-ocean ridge basalts (MORB) in having higher 143Nd/144Nd (0.51301-0.51319) and lower 206Pb/204Pb values (17.35-17.67); 87Sr/86Sr values (0.7025-0.7030) overlap those of SWIR basalts, but are generally lower than MORBs from the Southeast Indian Ridge or the Rodrigues Triple Junction. More than one magma composition may have been introduced into the magma chamber during its crystallization history, as suggested by the higher 87Sr/86Sr, 206Pb/204Pb, and lower 143Nd/144Nd values of chromium-rich olivine gabbros from the bottom of Hole 735B. Whole-rock gabbro and plagioclase mineral separate 87Sr/86Sr values are uniformly low (0.7027-0.7030), irrespective of alteration and deformation. By contrast, 87Sr/86Sr values for clinopyroxene (0.7025-0.7039) in the upper half of Hole 735B are higher than coexisting plagioclase and reflect extensive replacement of clinopyroxene by amphibole. Hydrothermal veins and breccias have elevated 87Sr/86Sr values (0.7029-0.7035) and indicate enhanced local introduction of seawater strontium. Oxygen- and hydrogen-isotope results show that secondary amphiboles have uniform dD values of -49 to -54 per mil and felsic hydrothermal veins range from -46 to - 77 per mil. Oxygen-isotope data for secondary amphibole and visibly altered gabbros range to low values (+1.0-+5.5 per mil), and O-isotope disequilibrium between coexisting pyroxene and plagioclase pairs from throughout the stratigraphic column indicates that seawater interacted with much of the gabbro section, but at relatively low water/rock ratios. This is consistent with the persistence of low 87Sr/86Sr values, even in gabbros that were extensively deformed and altered