91,179 research outputs found
Abstract Tensor Systems as Monoidal Categories
The primary contribution of this paper is to give a formal, categorical
treatment to Penrose's abstract tensor notation, in the context of traced
symmetric monoidal categories. To do so, we introduce a typed, sum-free version
of an abstract tensor system and demonstrate the construction of its associated
category. We then show that the associated category of the free abstract tensor
system is in fact the free traced symmetric monoidal category on a monoidal
signature. A notable consequence of this result is a simple proof for the
soundness and completeness of the diagrammatic language for traced symmetric
monoidal categories.Comment: Dedicated to Joachim Lambek on the occasion of his 90th birthda
A Critical Review of the Magnetoplasmadynamic /MPD/ Thrustor for Space Applications
Magnetoplasmadynamic thrustor for space application
Historical Internal Migration in Ireland
Copyright & reuse City University London has developed City Research Online so that its users may access the research outputs of City University London's staff. Copyright © and Moral Rights for this paper are retained by the individual author(s) and / or other copyright holders. All material in City Research Online is checked for eligibility for copyright before being made available in the live archive. URLs from City Research Online may be freely distributed and linked to from other web pages. Versions of research The version in City Research Online may differ from the final published version. Users are advised to check the Permanent City Research Online URL above for the status of the paper. Enquiries If you have any enquiries about any aspect of City Research Online, or if you wish to make contact with the author(s) of this paper, please email the team at [email protected]
Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles
© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k
Some Aspects of Measurement Error in Linear Regression of Astronomical Data
I describe a Bayesian method to account for measurement errors in linear
regression of astronomical data. The method allows for heteroscedastic and
possibly correlated measurement errors, and intrinsic scatter in the regression
relationship. The method is based on deriving a likelihood function for the
measured data, and I focus on the case when the intrinsic distribution of the
independent variables can be approximated using a mixture of Gaussians. I
generalize the method to incorporate multiple independent variables,
non-detections, and selection effects (e.g., Malmquist bias). A Gibbs sampler
is described for simulating random draws from the probability distribution of
the parameters, given the observed data. I use simulation to compare the method
with other common estimators. The simulations illustrate that the Gaussian
mixture model outperforms other common estimators and can effectively give
constraints on the regression parameters, even when the measurement errors
dominate the observed scatter, source detection fraction is low, or the
intrinsic distribution of the independent variables is not a mixture of
Gaussians. I conclude by using this method to fit the X-ray spectral slope as a
function of Eddington ratio using a sample of 39 z < 0.8 radio-quiet quasars. I
confirm the correlation seen by other authors between the radio-quiet quasar
X-ray spectral slope and the Eddington ratio, where the X-ray spectral slope
softens as the Eddington ratio increases.Comment: 39 pages, 11 figures, 1 table, accepted by ApJ. IDL routines
(linmix_err.pro) for performing the Markov Chain Monte Carlo are available at
the IDL astronomy user's library, http://idlastro.gsfc.nasa.gov/homepage.htm
Electron density and temperature measurements in the exhaust of a mpd source
Electron density and temperature profiles measured in exhaust of magnetoplasma-dynamic sourc
Quantitative analysis of ruminal methanogenic microbial populations in beef cattle divergent in phenotypic residual feed intake (RFI) offered contrasting diets
peer-reviewedBackground
Methane (CH4) emissions in cattle are an undesirable end product of rumen methanogenic fermentative activity as they are associated not only with negative environmental impacts but also with reduced host feed efficiency. The aim of this study was to quantify total and specific rumen microbial methanogenic populations in beef cattle divergently selected for residual feed intake (RFI) while offered (i) a low energy high forage (HF) diet followed by (ii) a high energy low forage (LF) diet. Ruminal fluid was collected from 14 high (H) and 14 low (L) RFI animals across both dietary periods. Quantitative real time PCR (qRT-PCR) analysis was conducted to quantify the abundance of total and specific rumen methanogenic microbes. Spearman correlation analysis was used to investigate the association between the relative abundance of methanogens and animal performance, rumen fermentation variables and diet digestibility.
Results
Abundance of methanogens, did not differ between RFI phenotypes. However, relative abundance of total and specific methanogen species was affected (P < 0.05) by diet type, with greater abundance observed while animals were offered the LF compared to the HF diet.
Conclusions
These findings suggest that differences in abundance of specific rumen methanogen species may not contribute to variation in CH4 emissions between efficient and inefficient animals, however dietary manipulation can influence the abundance of total and specific methanogen species.Funding for the development and main work of this research was provided
under the National Development Plan, through the Research Stimulus Fund, administered by the Department of Agriculture, Fisheries & Food, Ireland RSF 05 224
Calibration of shielded microwave probes using bulk dielectrics
A stripline-type near-field microwave probe is microfabricated for microwave
impedance microscopy. Unlike the poorly shielded coplanar probe that senses the
sample tens of microns away, the stripline structure removes the stray fields
from the cantilever body and localizes the interaction only around the
focused-ion beam deposited Pt tip. The approaching curve of an oscillating tip
toward bulk dielectrics can be quantitatively simulated and fitted to the
finite-element analysis result. The peak signal of the approaching curve is a
measure of the sample dielectric constant and can be used to study unknown bulk
materials.Comment: 10 pages, 3 figure
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