Textural evolution and phase transformation in titania membranes: Part 1. -unsupported membranes

Textural evolution in sol–gel derived nanostructured unsupported titania membranes has been studied using differential scanning calorimetry (DSC), differential thermal analysis (DTA), thermal gravimetry (TG), X-ray diffraction (XRD) and N2 adsorption. The anatase-to-rutile phase transformation kinetics were studied using the Avrami model. The precursor gel had a surface area of ca. 165 m2 g–1, which after heat treatment at 600 °C for 8 h reduced to zero. Undoped titania-gel layers transformed to more than 95% rutile after calcination at 600 °C for 8 h. The causes of surface-area reduction and pore growth were anatase crystallite growth and the enhanced sintering of rutile during transformation. Lanthanum oxide was identified as a suitable dopant for shifting the transformation temperature to ca. 850 °C. Lanthanum oxide doped titania showed an improved stability of porous texture compared to that of the undoped titania membranes

Muon localization site in U(Pt,Pd)3

The angular and temperature (10-250 K) variation of the Knight shift of single-crystalline U(Pt0.95Pd0.05)3 has been measured in transverse field (B=0.6 T) mSR experiments. By analysing the temperature variation of the Knight shift with a modified Curie-Weiss expression the muon localization site in this hexagonal material is determined at (0,0,0).Comment: 12 pages (including 4 figures); postscript file; Proc. 8th Int. Conf. on Muon Spin Rotation, Relaxation and Resonance (Aug.30-Sept.3, Les Diablerets); 2nd version with minor correction

Synthesis and textural properties of unsupported and supported rutile (TiO2) membranes

Two approaches were postulated for improving the stability of porous texture of titania membranes: (1) retarding the phase transformation and grain growth; (2) avoiding the phase transformation. Based on the second approach, rutile membranes were made directly from a rutile sol, prepared by the precipitation of titania on SnO2 nuclei. The rutile membranes were stable up to 800 °C, with a porosity of ca. 40%, whereas normal titania membranes (starting with anatase) show very little porosity above 600 °C. Alumina substitution retards grain growth and pore growth at 850 °C for unsupported as well as supported membranes. \u

Textural evolution and phase transformation in titania membranes: Part 2. - Supported membranes

Nanostructural evolution and phase transformation in supported and unsupported titania membranes have been studied using Raman spectroscopy, X-ray diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM). Densification of unsupported membranes started at ca. 450 °C and reached more than 97% density at 600 °C, whereas the supported membranes had a density of only ca. 70–75% even at 700 °C when calcined for 8 h. At 700 °C the average crystallite size of supported and unsupported membranes was ca. 20 and 70 nm, respectively. This behaviour is primarily attributed to the decrease in the driving force for sintering due to the stress developed during the constrained sintering of a film attached to a rigid support and to the inhibition of the reorganization process within the film, resulting in lower coordination numbers in supported membranes. Supported membranes showed a higher transformation temperature (slower rate of transformation) than did the unsupported. Supported and unsupported membranes, calcined for 8 h, transformed to ca. 90% rutile (calculated from Raman spectrum) after calcination at 850 and 650 °C, respectively. This difference in phase transformation behaviour is attributed primarily to the large stress which is developed in a constrained environment owing to the negative volume change during the anatase–rutile transformation

Critical voltage of a mesoscopic superconductor

We study the role of the quasiparticle distribution function f on the properties of a superconducting nanowire. We employ a numerical calculation based upon the Usadel equation. Going beyond linear response, we find a non-thermal distribution for f caused by an applied bias voltage. We demonstrate that the even part of f (the energy mode f_L) drives a first order transition from the superconducting state to the normal state irrespective of the current

Highly Non-linear Excitonic Zeeman Spin-Splitting in Composition-Engineered Artificial Atoms

Non-linear Zeeman splitting of neutral excitons is observed in composition engineered In(x)Ga(1-x)As self-assembled quantum dots and its microscopic origin is explained. Eight-band k.p simulations, performed using realistic dot parameters extracted from cross-sectional scanning tunneling microscopy, reveal that a quadratic contribution to the Zeeman energy originates from a spin dependent mixing of heavy and light hole orbital states in the dot. The dilute In-composition (x<0.35) and large lateral size (40-50 nm) of the quantum dots investigated is shown to strongly enhance the non-linear excitonic Zeeman gap, providing a blueprint to enhance such magnetic non-linearities via growth engineering

Last Frontier of Agricultural Big Data in Rotation?

Over the years new and promising varieties are bred not only for resistance to diseases but also for direct yield by stress tolerance, architectural or other properties. However, these potential yield improvements under optimal circumstances are not met by the growers in their practice, and is even widening. ..

Trajectory Deflection of Spinning Magnetic Microparticles, the Magnus Effect at the Microscale

The deflection due to the Magnus force of magnetic particles with a diameter of 80 micrometer dropping through fluids and rotating in a magnetic field was measured. With Reynolds number for this experiment around 1, we found trajectory deflections of the order of 1 degree, in agreement within measurement error with theory. This method holds promise for the sorting and analysis of the distribution in magnetic moment and particle diameter of suspensions of microparticles, such as applied in catalysis, or objects loaded with magnetic particles.Comment: 12 pages, 3 figures. Appendix with 6 figure