59 research outputs found

    Effect of Rayleigh Wave on Ultrasonic Underground Imaging

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    AbstractIn order to acquire image with higher resolution and less error for detecting underground objects, a three dimensional ultrasonic underground imaging technique using an electromagnetic-induction type sound source and an amplitude correlation synthesis processing (ACSP) method has been proposed in our previous work. Depending on the conditions of the ground surface, Rayleigh waves propagating along the surface directly may be received with significant amplitude by the receiver array. That will cause interference with the reflect signal of the underground objects and will bring forth error images to the imaging result. In this paper, the Rayleigh wave with comparatively high amplitude is measured experimentally in a model field filled with mountain sands, and its waveform is estimated and simulated approximately by an exponentially decaying sinusoidal wave. The effect on the image of underground object is discussed by synthesizing the received signal with the modeled Rayleigh wave with various relative amplitudes. The result images calculated by ACSP method show that the effect of Rayleigh wave is not marked when its peak amplitude is not greater than that of the signal reflected from the underground object

    Characterization of commercial natural rubber purified with transesterification

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    Highly purified commercial natural rubbers were prepared and characterized to elucidate the effect of processing condition on structure characteristic of the rubbers. In the present study, various commercial rubbers, i.e. Pale Crepe (PC), Ribbed Smoked Sheet (RSS3), Technically Specified Sheet (TSS8®), Standard Thailand Rubber (STR5L) and Standard Malaysian Rubber (SMR20) were purified by acetone extraction and transesterification (TE) to prepare highly purified commercial rubbers (TE-NR). The resulting TE-NRs were characterized by nuclear magnetic resonance (NMR) spectroscopy, Fourier transform infrared (FT-IR) spectroscopy and size exclusion chromatography (SEC). Epoxy group was found for PC, STR5L, RSS3, TSS8® and SMR20 and trans-1,4-isoprene unit from trans-1,4-isoprene units from cis-trans isomerization was found for TSS8® and SMR20 from the assignments of 1H-NMR signals. This result implies that the degradation, that is epoxidation and isomerization, took place during the processing of commercial rubbers. The damage of commercial natural rubbers was investigated with respect to its molecular weight. Keywords. Commercial rubber, transesterification, NMR, epoxidation, isomerization

    Glyburide inhibits the bone resorption induced by traumatic occlusion in rats.

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    To examine whether glyburide inhibits bone destruction caused by traumatic occlusion in a rat occlusal trauma model.Excessive mechanical stress, such as traumatic occlusion, induces expression of IL-1β and may be involved in bone resorption. NLRP3 inflammasomes have been linked to IL-1β expression, but it is currently unclear whether glyburide, the inhibiter of NLRP3 inflammasome, suppresses occlusal trauma in rats.Male SD rats aged 7 weeks were used. In the trauma group, the occlusal surface of the maxillary first right molar was raised by attaching a metal wire to apply occlusal trauma to the mandibular first right molar. In the trauma + glyburide group, the NLRP3 inhibitor glyburide was administered orally every 24 hours from 1 day before induction of occlusal trauma. Rats were euthanized after 5 or 10 days, and the maxillary first molars were harvested with the adjacent tissues for histopathological investigation. Immunohistochemical expression of IL-1β, NLRP3, and RANKL was also assessed.On day 5, bone resorption was significantly greater in the trauma group compared with the control group or the trauma + glyburide group, and there were significantly higher numbers of osteoclasts and cells positive for IL-1β, NLRP3, and RANKL in the trauma group.In this study, glyburide inhibits bone resorption by traumatic occlusion in rats. It suggests that the NLRP3/IL-1β pathway might be associated with bone resorption induced by traumatic occlusion.福岡歯科大学2019年

    Effect of water on the accelerated sulfur vulcanization of natural rubber

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    Water present in natural rubber was found to play a role in forming carbon-carbon crosslinking junctions before forming carbon-sulfur crosslinking junctions when its effect on the accelerated sulfur vulcanization was investigated by analyzing low–molecular weight products through various instrumental analytical techniques. Samples were prepared by mixing deproteinized natural rubber (DPNR) with various moisture contents with stearic acid, ZnO, sulfur, and N-tert-butylbenzothiazole-2-sulfenamide, and they were vulcanized at 150 °C for various cure times. Low–molecular weight products such as 2,2′-dibenzothiazole disulfide (MBTS), 2-mercaptobenzothiazole (MBT), ZnMBT, Zn2+ and sulfur linked to the rubber were extracted from the vulcanized natural rubbers using benzene and dioxane, and subsequently measured by high-performance liquid chromatography, UV–visible spectroscopy, inductively coupled plasma atomic emission spectroscopy, and combustion analysis. The water present in natural rubber was found to strongly affect the production and formation rate of the low–molecular weight products in the accelerated sulfur vulcanization of natural rubber. As the result it suggests that the water promotes the formation of the C-C linkages, and then it sequentially promotes the formation of the C-S linkages

    The Conformation Search and Structural Analysis of Natural Rubber

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    Distribution of Nanodiamond Inside the Nanomatrix in Natural Rubber

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    The distribution of nanodiamond inside a nanomatrix, which is related to the mechanical and viscoelastic properties, is investigated for a natural rubber–nanodiamond composite. The composite is prepared by reacting nanodiamond with deproteinized natural rubber (NR–ND) in the presence of a <i>tert</i>-butylhydroperoxide (TBHPO)/tetraethylenepentamine (TEPA) radical initiator at 30 °C in the latex stage and subsequent drying. The morphology of the composite is observed by three-dimensional transmission electron microscopy. NR–ND prepared with an initiator exhibits a nanomatrix structure, whereas NR–ND prepared without an initiator displays an island matrix structure. The nanomatrix is densely loaded with 15 nm or smaller-sized nanodiamond. Both the mechanical and viscoelastic properties of NR–ND depend upon the morphology. The stress at break and the plateau modulus are 12 MPa and 1.19 × 10<sup>6</sup> Pa, respectively, when NR–ND is prepared with a TBHPO/TEPA initiator and contains 25 w/w % nanodiamond, which are 4 and 8 times higher than those of deproteinized natural rubber, respectively

    The effects of visual impediment on the approaching behavior of harbor porpoise, Phocoena phocoena

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    Studies on odontocetes (e.g., porpoises) have revealed that these animals may adaptively use vision. The present study examined the contributions of vision to the approaching behavior of the harbor porpoise (Phocoena phocoena). When a porpoise approached a target, the time-to-contact perceived by the animal and its trajectory with a visual impediment condition were compared with those in the control (no impediment) condition. The results suggested that approaching behavior to a stationary target was guided by the animal's evaluation of time-to-contact (tau), maintaining the time derivative of tau ((tau) Over dot) at a constant value. A porpoise with visual deprivation exhibited grater (tau) Over dot) value and a longer evaluation time before contact than a porpoise that was not blindfolded in the task of reaching for the target. Furthermore, the porpoise with a visual impediment changed its swimming trajectory toward a target less than the control, which appeared to adaptively adjust its approaching trajectory. These findings imply that the use of vision aided echolocation and enables precise control and alteration of the trajectory during the approach. The present study has implications for adaptive use of vision during approaching behavior in the harbor porpoise

    天然ゴムの生合成過程解析

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