1,217 research outputs found
An \u3cem\u3em\u3c/em\u3e-Carboranedicarboxylic Acid Dianilide
The crystal structure of the \u27non hydrogen-bonded\u27 (according to IR data) polymorph of 1,7-bis(phenylcarbamoyl)-1,7-dicarba-closo-dodecaborane(12), C16-H22B10N2O2, has been determined. The two phenylamide groups have a Z configuration [the torsion angles 0-C-N-C are -2.3 (5) and -3.0 (5)°]. As a result both \u27active\u27 protons of these groups are almost completely shielded by other H atoms of the neighbouring carborane nucleus and phenyl substituents, and, therefore, no hydrogen-bonding contacts are found
Casimir forces in modulated systems
For the first time we present analytical results for the contribution of
electromagnetic fluctuations into thermodynamic properties of modulated
systems, like cholesteric or smectic liquid crystalline films. In the case of
small dielectric anisotropy we have derived explicit analytical expressions for
the chemical potential of such systems. Two limiting cases were specifically
considered: (i) the Van der Waals (VdW) limit, i.e., in the case when the
retardation of the electromagnetic interactions can be neglected; and (ii) the
Casimir limit, i.e. when the effects of retardation becomes considerable. It
was shown that in the Casimir limit, the film chemical potential oscillates
with the thickness of the film. This non-monotonic dependence of the chemical
potential on the film thickness can lead to step-wise wetting phenomena,
surface anchoring reorientation and other important effects. Applications of
the results may concern the various systems in soft matter or condensed matter
physics with multilayer or modulated structures.Comment: 13 page
Tectonics and volcanisms of Mars
Televised images of Mars transmitted from interplanetary stations are used to develop a theory of the structure and development of the planet. Crater chronology, the structure of planetary bodies in the Earth group, and a comparison of the Earth planetary bodies are among the factors included
Polarized iridescence of the tropical carpenter bee, <i>Xylocopa latipes</i>
The tropical carpenter bee, Xylocopa latipes, has metallic-reflecting, iridescent wings. The wing reflectance spectra for TE- and TM-polarized light depend on the angle of light incidence in a way characteristic for dielectric multilayers. Anatomy indicates the presence of melanin multilayers in the wing’s chitinous matrix. A simple optical model of melanin multilayers explains the angle dependence of the wing reflectance spectra. The wing reflections that occur upon oblique illumination exhibit colourful and strongly polarized light patterns, which may mediate intraspecific signaling and mutual recognition by conspecifics.</p
Dynamic Fluctuation Phenomena in Double Membrane Films
Dynamics of double membrane films is investigated in the long-wavelength
limit including the overdamped squeezing mode. We demonstrate that thermal
fluctuations essentially modify the character of the mode due to its nonlinear
coupling to the transversal shear hydrodynamic mode. The corresponding Green
function acquires as a function of the frequency a cut along the imaginary
semi-axis. Fluctuations lead to increasing the attenuation of the squeezing
mode it becomes larger than the `bare' value.Comment: 7 pages, Revte
Title Stabilization of Membrane Pores by Packing
We present a model for pore stabilization in membranes without surface
tension. Whereas an isolated pore is always unstable (since it either shrinks
tending to re-seal or grows without bound til to membrane disintegration), it
is shown that excluded volume interactions in a system of many pores can
stabilize individual pores of a given size in a certain range of model
parameters. For such a multipore membrane system, the distribution of pore size
and associated pore lifetime are calculated within the mean field
approximation. We predict that, above certain temperature when the effective
line tension becomes negative, the membrane exhibits a dynamic sieve-like
porous structure.Comment: 4 pages, 4 figure
Comment on "Effects of spatial dispersion on electromagnetic surface modes and on modes associated with a gap between two half spaces"
Recently Bo E. Sernelius [Phys. Rev. B {\bf 71}, 235114 (2005)] investigated
the effects of spatial dispersion on the thermal Casimir force between two
metal half spaces. He claims that incorporating spatial dispersion results in a
negligible contribution from the transverse electric mode at zero frequency as
compared to the transverse magnetic mode. We demonstrate that this conclusion
is not reliable because, when applied to the Casimir effect, the approximate
description of spatial dispersion used is unjustified.Comment: 9 pages, minor corrections in accordance with the journal publication
have been mad
Weak gravity conjecture constraints on inflation
We consider the gravitational correction to the coupling of the scalar
fields. Weak gravity conjecture says that the gravitational correction to the
running of scalar coupling should be less than the contribution from scalar
fields. For instance, a new scale sets a UV cutoff
on the validity of the effective theory. Furthermore, this
conjecture implies a possible constraint on the inflation model, e.g. the
chaotic inflation model might be in the swampland.Comment: 11 pages, 3 figs; monor corrections; some clarifying remarks added
and the final version for publication in JHE
Surface Screening in the Casimir Force
We calculate the corrections to the Casimir force between two metals due to
the spatial dispersion of their response functions. We employ model-independent
expressions for the force in terms of the optical coefficients. We express the
non-local corrections to the Fresnel coefficients employing the surface
parameter, which accounts for the distribution of the surface
screening charge. Within a self-consistent jellium calculation, spatial
dispersion increases the Casimir force significatively for small separations.
The nonlocal correction has the opposite sign than previously predicted
employing hydrodynamic models and assuming abruptly terminated surfaces.Comment: 5 pages, 2 figure
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