1,217 research outputs found

    An \u3cem\u3em\u3c/em\u3e-Carboranedicarboxylic Acid Dianilide

    Get PDF
    The crystal structure of the \u27non hydrogen-bonded\u27 (according to IR data) polymorph of 1,7-bis(phenylcarbamoyl)-1,7-dicarba-closo-dodecaborane(12), C16-H22B10N2O2, has been determined. The two phenylamide groups have a Z configuration [the torsion angles 0-C-N-C are -2.3 (5) and -3.0 (5)°]. As a result both \u27active\u27 protons of these groups are almost completely shielded by other H atoms of the neighbouring carborane nucleus and phenyl substituents, and, therefore, no hydrogen-bonding contacts are found

    Casimir forces in modulated systems

    Full text link
    For the first time we present analytical results for the contribution of electromagnetic fluctuations into thermodynamic properties of modulated systems, like cholesteric or smectic liquid crystalline films. In the case of small dielectric anisotropy we have derived explicit analytical expressions for the chemical potential of such systems. Two limiting cases were specifically considered: (i) the Van der Waals (VdW) limit, i.e., in the case when the retardation of the electromagnetic interactions can be neglected; and (ii) the Casimir limit, i.e. when the effects of retardation becomes considerable. It was shown that in the Casimir limit, the film chemical potential oscillates with the thickness of the film. This non-monotonic dependence of the chemical potential on the film thickness can lead to step-wise wetting phenomena, surface anchoring reorientation and other important effects. Applications of the results may concern the various systems in soft matter or condensed matter physics with multilayer or modulated structures.Comment: 13 page

    Tectonics and volcanisms of Mars

    Get PDF
    Televised images of Mars transmitted from interplanetary stations are used to develop a theory of the structure and development of the planet. Crater chronology, the structure of planetary bodies in the Earth group, and a comparison of the Earth planetary bodies are among the factors included

    Polarized iridescence of the tropical carpenter bee, <i>Xylocopa latipes</i>

    Get PDF
    The tropical carpenter bee, Xylocopa latipes, has metallic-reflecting, iridescent wings. The wing reflectance spectra for TE- and TM-polarized light depend on the angle of light incidence in a way characteristic for dielectric multilayers. Anatomy indicates the presence of melanin multilayers in the wing’s chitinous matrix. A simple optical model of melanin multilayers explains the angle dependence of the wing reflectance spectra. The wing reflections that occur upon oblique illumination exhibit colourful and strongly polarized light patterns, which may mediate intraspecific signaling and mutual recognition by conspecifics.</p

    Dynamic Fluctuation Phenomena in Double Membrane Films

    Full text link
    Dynamics of double membrane films is investigated in the long-wavelength limit including the overdamped squeezing mode. We demonstrate that thermal fluctuations essentially modify the character of the mode due to its nonlinear coupling to the transversal shear hydrodynamic mode. The corresponding Green function acquires as a function of the frequency a cut along the imaginary semi-axis. Fluctuations lead to increasing the attenuation of the squeezing mode it becomes larger than the `bare' value.Comment: 7 pages, Revte

    Title Stabilization of Membrane Pores by Packing

    Full text link
    We present a model for pore stabilization in membranes without surface tension. Whereas an isolated pore is always unstable (since it either shrinks tending to re-seal or grows without bound til to membrane disintegration), it is shown that excluded volume interactions in a system of many pores can stabilize individual pores of a given size in a certain range of model parameters. For such a multipore membrane system, the distribution of pore size and associated pore lifetime are calculated within the mean field approximation. We predict that, above certain temperature when the effective line tension becomes negative, the membrane exhibits a dynamic sieve-like porous structure.Comment: 4 pages, 4 figure

    Comment on "Effects of spatial dispersion on electromagnetic surface modes and on modes associated with a gap between two half spaces"

    Full text link
    Recently Bo E. Sernelius [Phys. Rev. B {\bf 71}, 235114 (2005)] investigated the effects of spatial dispersion on the thermal Casimir force between two metal half spaces. He claims that incorporating spatial dispersion results in a negligible contribution from the transverse electric mode at zero frequency as compared to the transverse magnetic mode. We demonstrate that this conclusion is not reliable because, when applied to the Casimir effect, the approximate description of spatial dispersion used is unjustified.Comment: 9 pages, minor corrections in accordance with the journal publication have been mad

    Weak gravity conjecture constraints on inflation

    Get PDF
    We consider the gravitational correction to the coupling of the scalar fields. Weak gravity conjecture says that the gravitational correction to the running of scalar coupling should be less than the contribution from scalar fields. For instance, a new scale Λ=λ41/2Mp\Lambda=\lambda_4^{1/2}M_p sets a UV cutoff on the validity of the effective λ4ϕ4\lambda_4 \phi^4 theory. Furthermore, this conjecture implies a possible constraint on the inflation model, e.g. the chaotic inflation model might be in the swampland.Comment: 11 pages, 3 figs; monor corrections; some clarifying remarks added and the final version for publication in JHE

    Surface Screening in the Casimir Force

    Full text link
    We calculate the corrections to the Casimir force between two metals due to the spatial dispersion of their response functions. We employ model-independent expressions for the force in terms of the optical coefficients. We express the non-local corrections to the Fresnel coefficients employing the surface d⊥d_\perp parameter, which accounts for the distribution of the surface screening charge. Within a self-consistent jellium calculation, spatial dispersion increases the Casimir force significatively for small separations. The nonlocal correction has the opposite sign than previously predicted employing hydrodynamic models and assuming abruptly terminated surfaces.Comment: 5 pages, 2 figure
    • …
    corecore