Efficient room temperature aqueous Sb2S3 synthesis for inorganic-organic sensitized solar cells with 5.1% efficiencies.

Sb2S3 sensitized solar cells are a promising alternative to devices employing organic dyes. The manufacture of Sb2S3 absorber layers is however slow and cumbersome. Here, we report the modified aqueous chemical bath synthesis of Sb2S3 absorber layers for sensitized solar cells. Our method is based on the hydrolysis of SbCl3 to complex antimony ions decelerating the reaction at ambient conditions, in contrast to the usual low temperature deposition protocol. This simplified deposition route allows the manufacture of sensitized mesoporous-TiO2 solar cells with power conversion efficiencies up to η = 5.1%. Photothermal deflection spectroscopy shows that the sub-bandgap trap-state density is lower in Sb2S3 films deposited with this method, compared to standard deposition protocols.Cambridge Trust, the Mott Fund for Physics of the Environment and Corpus Christi College Cambridge for funding. A.S. acknowledges funding from the Engineering and Physical Sciences Research Council (EPSRC).This is the final version. It first appeared at http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/c5cc01966d#!divAbstract

Blue-Green Color Tunable Solution Processable Organolead Chloride-Bromide Mixed Halide Perovskites for Optoelectronic Applications.

Solution-processed organo-lead halide perovskites are produced with sharp, color-pure electroluminescence that can be tuned from blue to green region of visible spectrum (425-570 nm). This was accomplished by controlling the halide composition of CH3NH3Pb(BrxCl1-x)3 [0 ≤ x ≤ 1] perovskites. The bandgap and lattice parameters change monotonically with composition. The films possess remarkably sharp band edges and a clean bandgap, with a single optically active phase. These chloride-bromide perovskites can potentially be used in optoelectronic devices like solar cells and light emitting diodes (LEDs). Here we demonstrate high color-purity, tunable LEDs with narrow emission full width at half maxima (FWHM) and low turn on voltages using thin-films of these perovskite materials, including a blue CH3NH3PbCl3 perovskite LED with a narrow emission FWHM of 5 nm.We acknowledge funding from the Engineering and Physical Sciences Research Council (EPSRC) and the Winton Programme (Cambridge) for the Physics of Sustainability. Support from the Deutsche Forschungsgemeinschaft (NIM Excellence Cluster) is gratefully acknowledged. A.S. acknowledges the funding and support from the Indo-UK APEX project. F.D. acknowledges funding and support from a Herchel Smith fellowship. M.D.V. acknowledges funding and support from the ERC-StG 337739-HIENA. A.S. thanks Dr. D. Di for the insightful discussions. P. D. gratefully acknowledges support from the European Union in the form of a Marie Curie Intra-European fellowship.This is the final version of the article. It first appeared from the American Chemical Society via http://dx.doi.org/10.1021/acs.nanolett.5b0236

Simulation framework for coherent and incoherent X-ray imaging and its application in Talbot-Lau dark-field imaging

A simulation framework for coherent X-ray imaging, based on scalar diffraction theory, is presented. It contains a core C++ library and an additional Python interface. A workflow is presented to include contributions of inelastic scattering obtained with Monte-Carlo methods. X-ray Talbot-Lau interferometry is the primary focus of the framework. Simulations are in agreement with measurements obtained with such an interferometer. Especially, the dark-field signal of densely packed PMMA microspheres is predicted. A realistic modeling of the microsphere distribution, which is necessary for correct results, is presented. The framework can be used for both setup design and optimization but also to test and improve reconstruction methods

Research data supporting “High open circuit voltages in tin-rich low-bandgap perovskites based planar heterojunction photovoltaics”

PL, EQE, absorption, XRD, THz and PV dataEPSRC [EP/M005143/1], India-UK APEX project, Winton Programme (Cambridge) for the Physics of Sustainability, Cambridge Trust, China Scholarship Council, Nvak Technology Ltd., LDRD program, LAN

High Open-Circuit Voltages in Tin-Rich Low-Bandgap Perovskite-Based Planar Heterojunction Photovoltaics

Low-bandgap CH3NH3(PbxSn1–x)I3 (0 ≤ x ≤ 1) hybrid perovskites (e.g., ≈1.5–1.1 eV) demonstrating high surface coverage and superior optoelectronic properties are fabricated. State-of-the-art photovoltaic (PV) performance is reported with power conversion efficiencies approaching 10% in planar heterojunction architecture with small (<450 meV) energy loss compared to the bandgap and high (>100 cm2 V−1s−1) intrinsic carrier mobilities

Codification, Abstraction, and Firm Differences: A Cognitive Information-based Perspective

knowledge, codification, theory of the firm, firm heterogeneity, resource-based view, information asymmetry, B52, D01, D82, D83, L25,