420 research outputs found
Surfactant-based critical phenomena in microgravity
The objective of this research project is to characterize by experiment and theoretically both the kinetics of phase separation and the metastable structures produced during phase separation in a microgravity environment. The particular systems we are currently studying are mixtures of water, nonionic surfactants, and compressible supercritical fluids at temperatures and pressures where the coexisting liquid phases have equal densities (isopycnic phases). In this report, we describe experiments to locate equilibrium isopycnic phases and to determine the 'local' phase behavior and critical phenomena at nearby conditions of temperature, pressure, and composition. In addition, we report the results of preliminary small angle neutron scattering (SANS) experiments to characterize microstructures that exist in these mixtures at different fluid densities
Isopycnic Phases and Structures in H2O/CO2/Ethoxylated Alcohol Surfactant Mixtures
Ternary mixtures of H2O and CO2 with ethoxylated alcohol (C(i)E(j)) surfactants can form three coexisting liquid phases at conditions where two of the phases have the same density (isopycnic phases). Isopycnic phase behavior has been observed for mixtures containing the surfactants C8E5, C10E6, and C12E6, but not for those mixtures containing either C4E1 or CgE3. Pressure-temperature (PT) projections for this isopycnic three-phase equilibrium were determined for H2O/CO2/C8E5 and H2O/CO2/C10E6 mixtures at temperatures from approximately 25 to 33 C and pressures between 90 and 350 bar. As a preliminary to measuring the microstructure in isopycnic three component mixtures, phase behavior and small angle neutron scattering (SANS) experiments were performed on mixtures of D2O/CO2/ n-hexaethyleneglycol monododecyl ether (C12E6) as a function of temperature (25-31 C), pressure (63.1-90.7 bar), and CO2 composition (0-3.9 wt%). Parameters extracted from model fits of the SANS spectra indicate that, while micellar structure remains essentially unchanged, critical concentration fluctuations increase as the phase boundary and plait point are approached
Equilibrium onions?
We demonstrate the possibility of a stable equilibrium multi-lamellar ("onion") phase in pure lamellar systems (no excess solvent) due to a sufficiently negative Gaussian curvature modulus. The onion phase is stabilized by non-linear elastic moduli coupled to a polydisperse size distribution (Apollonian packing) to allow space-filling without appreciable elastic distortion. This model is compared to experiments on copolymer-decorated lamellar surfactant systems, with reasonable qualitative agreement
Charge-Fluctuation-Induced Non-analytic Bending Rigidity
In this Letter, we consider a neutral system of mobile positive and negative
charges confined on the surface of curved films. This may be an appropriate
model for: i) a highly charged membrane whose counterions are confined to a
sheath near its surface; ii) a membrane composed of an equimolar mixture of
anionic and cationic surfactants in aqueous solution. We find that the charge
fluctuations contribute a non-analytic term to the bending rigidity that varies
logarithmically with the radius of curvature. This may lead to spontaneous
vesicle formation, which is indeed observed in similar systems.Comment: Revtex, 9 pages, no figures, submitted to PR
Surfactant Diffusion into Lysozyme Crystal Matrices Investigated by Quantitative Fluorescence Microscopy
Forces between a single atom and its distant mirror image
An excited-state atom whose emitted light is back-reflected by a distant
mirror can experience trapping forces, because the presence of the mirror
modifies both the electromagnetic vacuum field and the atom's own radiation
reaction field. We demonstrate this mechanical action using a single trapped
barium ion. We observe the trapping conditions to be notably altered when the
distant mirror is shifted by an optical wavelength. The well-localised barium
ion enables the spatial dependence of the forces to be measured explicitly. The
experiment has implications for quantum information processing and may be
regarded as the most elementary optical tweezers.Comment: 4 pages, 5 figures, published versio
Vacuum-field level shifts in a single trapped ion mediated by a single distant mirror
A distant mirror leads to a vacuum-induced level shift in a laser-excited
atom. This effect has been measured with a single mirror 25 cm away from a
single, trapped barium ion. This dispersive action is the counterpart to the
mirror's dissipative effect, which has been shown earlier to effect a change in
the ion's spontaneous decay [J. Eschner et al., Nature 413, 495-498 (2001)].
The experimental data are well described by 8-level optical Bloch equations
which are amended to take into account the presence of the mirror according to
the model in [U. Dorner and P. Zoller, Phys. Rev. A 66, 023816 (2002)].
Observed deviations from simple dispersive behavior are attributed to
multi-level effects.Comment: version accepted by PR
Ovine pedomics : the first study of the ovine foot 16S rRNA-based microbiome
We report the first study of the bacterial microbiome of ovine interdigital skin based on 16S rRNA by pyrosequencing and conventional cloning with Sanger-sequencing. Three flocks were selected, one a flock with no signs of footrot or interdigital dermatitis, a second flock with interdigital dermatitis alone and a third flock with both interdigital dermatitis and footrot. The sheep were classified as having either healthy interdigital skin (H), interdigital dermatitis (ID) or virulent footrot (VFR). The ovine interdigital skin bacterial community varied significantly by flock and clinical condition. The diversity and richness of operational taxonomic units was greater in tissue from sheep with ID than H or VFR affected sheep. Actinobacteria, Bacteriodetes, Firmicutes and Proteobacteria were the most abundant phyla comprising 25 genera. Peptostreptococcus, Corynebacterium and Staphylococcus were associated with H, ID and VFR respectively. Sequences of Dichelobacter nodosus, the causal agent of ovine footrot, were not amplified due to mismatches in the 16S rRNA universal forward primer (27F). A specific real time PCR assay was used to demonstrate the presence of D. nodosus which was detected in all samples including the flock with no signs of ID or VFR. Sheep with ID had significantly higher numbers of D. nodosus (104-109 cells/g tissue) than those with H or VFR feet
Quantum state engineering on an optical transition and decoherence in a Paul trap
A single Ca+ ion in a Paul trap has been cooled to the ground state of
vibration with up to 99.9% probability. Starting from this Fock state |n=0> we
have demonstrated coherent quantum state manipulation on an optical transition.
Up to 30 Rabi oscillations within 1.4 ms have been observed. We find a similar
number of Rabi oscillations after preparation of the ion in the |n=1> Fock
state. The coherence of optical state manipulation is only limited by laser and
ambient magnetic field fluctuations. Motional heating has been measured to be
as low as one vibrational quantum in 190 ms.Comment: 4 pages, 5 figure
Orbital parameters, masses and distance to Beta Centauri determined with the Sydney University Stellar Interferometer and high resolution spectroscopy
The bright southern binary star beta Centauri (HR 5267) has been observed
with the Sydney University Stellar Interferometer (SUSI) and spectroscopically
with the ESO CAT and Swiss Euler telescopes at La Silla. The interferometric
observations have confirmed the binary nature of the primary component and have
enabled the determination of the orbital parameters of the system. At the
observing wavelength of 442 nm the two components of the binary system have a
magnitude difference of 0.15. The combination of interferometric and
spectroscopic data gives the following results: orbital period 357 days,
semi-major axis 25.30 mas, inclination 67.4 degrees, eccentricity 0.821,
distance 102.3 pc, primary and secondary masses M1 = M2 = 9.1 solar masses and
absolute visual magnitudes of the primary and secondary M1V = -3.85 and M2V =
-3.70. The high accuracy of the results offers a fruitful starting point for
future asteroseismic modelling of the pulsating binary components.Comment: 10 pages, 4 figures. Accepted for publication in MNRA
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