890 research outputs found
H-1 NMR study of internal motions and quantum rotational tunneling in (CH3)(4)NGeCl3
(CH3)(4)NGeCl3 is prepared, characterized and studied using H-1 NMR spin lattice relaxation time and second moment to understand the internal motions and quantum rotational tunneling. Proton second moment is measured at 7 MHz as function of temperature in the range 300-77 K and spin lattice relaxation time (T-1) is measured at two Larmor frequencies, as a function of temperature in the range 270-17 K employing a homemade wide-line/pulsed NMR spectrometers. T-1 data are analyzed in two temperature regions using relevant theoretical models. The relaxation in the higher temperatures (270-115 K) is attributed to the hindered reorientations of symmetric groups (CH3 and (CH3)(4)N). Broad asymmetric T-1 minima observed below 115 K down to 17 K are attributed to quantum rotational tunneling of the inequivalent methyl groups. Copyright (c) 2007 John Wiley & Sons, Ltd
Design optimization of deflection caused after release of multilayer structural membrane of Symmetric Toggle Switch
This paper presents the optimization in deflection caused by the inbuilt stress generated in mechanical or movable membrane of Symmetric Toggle RF MEMS Switch (STS). The movable membrane of STS was initially fabricated with two different materials, i.e. Chrome and Gold. The simulated deflection at 70°C was 11.9
μm, and experimental deflection was 11-12 μm. We present a study of inbuilt deflection reduction in multimetal movable layers without change in actuation voltage of the switch. The design study was initially carried out on cantilevers and then on
structural membrane of STS. STS with proposed multilayer of Cr-Au-Au-Ti-Au has a simulated deflection of 0.56 μm at 70°C.
When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2212
Anisotropic two-dimensional Heisenberg model by Schwinger-boson Gutzwiller projected method
Two-dimensional Heisenberg model with anisotropic couplings in the and
directions () is considered. The model is first solved in the
Schwinger-boson mean-field approximation. Then the solution is Gutzwiller
projected to satisfy the local constraint that there is only one boson at each
site. The energy and spin-spin correlation of the obtained wavefunction are
calculated for systems with up to sites by means of the
variational Monte Carlo simulation. It is shown that the antiferromagnetic
long-range order remains down to the one-dimensional limit.Comment: 15 pages RevTex3.0, 4 figures, available upon request, GWRVB8-9
Electronic Structure of the Complex Hydride NaAlH4
Density functional calculations of the electronic structure of the complex
hydride NaAlH4 and the reference systems NaH and AlH3 are reported. We find a
substantially ionic electronic structure for NaAlH4, which emphasizes the
importance of solid state effects in this material. The relaxed hydrogen
positions in NaAlH4 are in good agreement with recent experiment. The
electronic structure of AlH3 is also ionic. Implications for the binding of
complex hydrides are discussed.Comment: 4 pages, 5 figure
Counter-intuitive influence of Himalayan river morphodynamics on Indus Civilisation urban settlements
Urbanism in the Bronze-age Indus Civilisation (~4.6–3.9 thousand years before the present, ka) has been linked to water resources provided by large Himalayan river systems, although the largest concentrations of urban-scale Indus settlements are located far from extant Himalayan rivers. Here we analyse the sedimentary architecture, chronology and provenance of a major palaeochannel associated with many of these settlements. We show that the palaeochannel is a former course of the Sutlej River, the third largest of the present-day Himalayan rivers. Using optically stimulated luminescence dating of sand grains, we demonstrate that flow of the Sutlej in this course terminated considerably earlier than Indus occupation, with diversion to its present course complete shortly after ~8 ka. Indus urban settlements thus developed along an abandoned river valley rather than an active Himalayan river. Confinement of the Sutlej to its present incised course after ~8 ka likely reduced its propensity to re-route frequently thus enabling long-term stability for Indus settlements sited along the relict palaeochannel
Thermomagnetic history effects in SmMnGe
The intermetallic compound SmMnGe, displaying multiple magnetic phase
transitions, is being investigated in detail for its magnetization behavior
near the 145 K first order ferromagnetic to antiferromagnetic transition
occuring on cooling, in particular for thermomagnetic history effects in the
magnetization data. The most unusual finding is that the thermomagnetic
irreversibility, [= M(T)-M(T)] at 135 K is higher in
intermediate magnetic field strengths. By studying the response of the sample
(i.e., thermomagnetic irreversibility and thermal hysteresis) to different
histories of application of magnetic field and temperature, we demonstrate how
the supercooling and superheating of the metastable magnetic phases across the
first order transition at 145 K contribute to overall thermomagnetic
irreversibility.Comment: 15 pages, 5 figures, to appear in Physical Review
Neurophysiologically-informed markers of individual variability and pharmacological manipulation of human cortical gamma
The ability to quantify synaptic function at the level of cortical microcircuits from non-invasive data would be enormously useful in the study of neuronal processing in humans and the pathophysiology that attends many neuropsychiatric disorders. Here, we provide proof of principle that one can estimate inter-and intra-laminar interactions among specific neuronal populations using induced gamma responses in the visual cortex of human subjects – using dynamic causal modelling based upon the canonical microcircuit (CMC; a simplistic model of a cortical column). Using variability in induced (spectral) responses over a large cohort of normal subjects, we find that the predominant determinants of gamma responses rest on recurrent and intrinsic connections between superficial pyramidal cells and inhibitory interneurons. Furthermore, variations in beta responses were mediated by inter-subject differences in the intrinsic connections between deep pyramidal cells and inhibitory interneurons. Interestingly, we also show that increasing the self-inhibition of superficial pyramidal cells suppresses the amplitude of gamma activity, while increasing its peak frequency. This systematic and nonlinear relationship was only disclosed by modelling the causes of induced responses. Crucially, we were able to validate this form of neurophysiological phenotyping by showing a selective effect of the GABA re-uptake inhibitor tiagabine on the rate constants of inhibitory interneurons. Remarkably, we were able to recover the pharmacodynamics of this effect over the course of several hours on a per subject basis. These findings speak to the possibility of measuring population specific synaptic function – and its response to pharmacological intervention – to provide subject-specific biomarkers of mesoscopic neuronal processes using non-invasive data. Finally, our results demonstrate that, using the CMC as a proxy, the synaptic mechanisms that underlie the gain control of neuronal message passing within and between different levels of cortical hierarchies may now be amenable to quantitative study using non-invasive (MEG) procedures
An Exact Diagonalization Demonstration of Incommensurability and Rigid Band Filling for N Holes in the t-J Model
We have calculated S(q) and the single particle distribution function
for N holes in the t - J model on a non--square sqrt{8} X sqrt{32} 16--site
lattice with periodic boundary conditions; we justify the use of this lattice
in compariosn to those of having the full square symmetry of the bulk. This new
cluster has a high density of vec k points along the diagonal of reciprocal
space, viz. along k = (k,k). The results clearly demonstrate that when the
single hole problem has a ground state with a system momentum of vec k =
(pi/2,pi/2), the resulting ground state for N holes involves a shift of the
peak of the system's structure factor away from the antiferromagnetic state.
This shift effectively increases continuously with N. When the single hole
problem has a ground state with a momentum that is not equal to k =
(pi/2,pi/2), then the above--mentioned incommensurability for N holes is not
found. The results for the incommensurate ground states can be understood in
terms of rigid--band filling: the effective occupation of the single hole k =
(pi/2,pi/2) states is demonstrated by the evaluation of the single particle
momentum distribution function . Unlike many previous studies, we show
that for the many hole ground state the occupied momentum states are indeed k =
(+/- pi/2,+/- pi/2) states.Comment: Revtex 3.0; 23 pages, 1 table, and 13 figures, all include
Genome‐Wide Association Mapping for Leaf Tip Necrosis and Pseudo‐black Chaff in Relation to Durable Rust Resistance in Wheat
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