High-performance light-weight electrodes for hydrogen-oxygen fuel cells

High performance light weight electrodes for hydrogen oxygen fuel cell

Reconstruction of Defect Geometries in Ultrasonic NDT

The international activities in developing new flaw characterization methods with special emphasis on acoustic imaging have been increased. To reduce the dependency upon amplitude information and due to the fact that flaw information is buried in the shape and fine structure of wave fronts, considerable attention has been given to the development of methods using time-of-flight information from different probe positions. For this reason, with mechanical scanners and specially build data acquisition and evaluation systems, a vareity of ways to produce images has been developed. These include echotomography, linear or two dimensional mono- or multi-frequency holography, tip echo interference methods, ALOK (amplitude-,time-of-flight-locus curves), Phased Array, SAFT or Rayleigh-Sommerfeld Holography. These methods use mathematical algorithms which seem to be independent or which have been derived heuristically. Based upon the concept of elastodynamic diffraction theory together with that of tomography a concept can be derived which reveals the inner connection of these algorithms. Differences in the reconstructions arise due to limitations like limited aperture, limited bandwidth, use of mode converted signals or due to complex surface shapes. An attempt is made to cover the theoretical background, to give an overview on existing data acquisition systems and to describe the strength, weaknesses, and difficulties in producing acoustic images

Design and Fabrication of Three-Dimensional Scaffolds for Tissue Engineering of Human Heart Valves

We developed a new fabrication technique for 3-dimensional scaffolds for tissue engineering of human heart valve tissue. A human aortic homograft was scanned with an X-ray computer tomograph. The data derived from the X-ray computed tomogram were processed by a computer-aided design program to reconstruct a human heart valve 3-dimensionally. Based on this stereolithographic model, a silicone valve model resembling a human aortic valve was generated. By taking advantage of the thermoplastic properties of polyglycolic acid as scaffold material, we molded a 3-dimensional scaffold for tissue engineering of human heart valves. The valve scaffold showed a deviation of only +/- 3-4% in height, length and inner diameter compared with the homograft. The newly developed technique allows fabricating custom-made, patient-specific polymeric cardiovascular scaffolds for tissue engineering without requiring any suture materials. Copyright (c) 2008 S. Karger AG, Base

Effects of image charges, interfacial charge discreteness, and surface roughness on the zeta potential of spherical electric double layers

We investigate the effects of image charges, interfacial charge discreteness, and surface roughness on spherical electric double layers in electrolyte solutions with divalent counter-ions in the setting of the primitive model. By using Monte Carlo simulations and the image charge method, the zeta potential profile and the integrated charge distribution function are computed for varying surface charge strengths and salt concentrations. Systematic comparisons were carried out between three distinct models for interfacial charges: 1) SURF1 with uniform surface charges, 2) SURF2 with discrete point charges on the interface, and 3) SURF3 with discrete interfacial charges and finite excluded volume. By comparing the integrated charge distribution function (ICDF) and potential profile, we argue that the potential at the distance of one ion diameter from the macroion surface is a suitable location to define the zeta potential. In SURF2 model, we find that image charge effects strongly enhance charge inversion for monovalent interfacial charges, and strongly suppress charge inversion for multivalent interfacial charges. For SURF3, the image charge effect becomes much smaller. Finally, with image charges in action, we find that excluded volumes (in SURF3) suppress charge inversion for monovalent interfacial charges and enhance charge inversion for multivalent interfacial charges. Overall, our results demonstrate that all these aspects, i.e., image charges, interfacial charge discreteness, their excluding volumes have significant impacts on the zeta potential, and thus the structure of electric double layers.Comment: 11 pages, 10 figures, some errors are change

The collapsed tetragonal phase as a strongly covalent and fully nonmagnetic state: persistent magnetism with interlayer As-As bond formation in Rh-doped Ca0.8_{0.8}Sr0.2_{0.2}Fe2_2As2_2

A well-known feature of CaFe$_{2}$As$_{2}$-based superconductors is the pressure-induced collapsed tetragonal phase that is commonly ascribed to the formation of an interlayer As-As bond. Using detailed X-ray scattering and spectroscopy, we find that Rh-doped Ca$_{0.8}$Sr$_{0.2}$Fe$_{2}$As$_{2}$ does not undergo a first-order phase transition and that local Fe moments persist despite the formation of interlayer As-As bonds. Our density functional theory calculations reveal that the Fe-As bond geometry is critical for stabilizing magnetism and that the pressure-induced drop in the $c$ lattice parameter observed in pure CaFe$_{2}$As$_{2}$ is mostly due to a constriction within the FeAs planes. These phenomena are best understood using an often overlooked explanation for the equilibrium Fe-As bond geometry, which is set by a competition between covalent bonding and exchange splitting between strongly hybridized Fe $3d$ and As $4p$ states. In this framework, the collapsed tetragonal phase emerges when covalent bonding completely wins out over exchange splitting. Thus the collapsed tetragonal phase is properly understood as a strong, covalent phase that is fully nonmagnetic with the As-As bond forming as a byproduct.Comment: 6 pages, 2 figures, and 1 table. Supplemental materials are available by reques

Particle Ratios, Equilibration, and the QCD Phase Boundary

We discuss the status of thermal model descriptions of particle ratios in central nucleus-nucleus collisions at ultra-relativistic energy. An alternative to the ``Cleymans-Redlich'' interpretation of the freeze-out trajectory is given in terms of the total baryon density. Emphasis is placed on the relation between the chemical equilibration parameters and the QCD phase boundary. Furthermore, we trace the essential difference between thermal model analyses of data from collisions between elementary particles and from heavy ion collisions as due to a transition from local strangeness conservation to percolation of strangeness over large volumes, as occurs naturally in a deconfined medium. We also discuss predictions of the thermal model for composite particle production.Comment: Contribution to SQM2001 Conference, submitted to J. Phys.

Phase Separation in Charge-Stabilized Colloidal Suspensions: Influence of Nonlinear Screening

The phase behavior of charge-stabilized colloidal suspensions is modeled by a combination of response theory for electrostatic interparticle interactions and variational theory for free energies. Integrating out degrees of freedom of the microions (counterions, salt ions), the macroion-microion mixture is mapped onto a one-component system governed by effective macroion interactions. Linear response of microions to the electrostatic potential of the macroions results in a screened-Coulomb (Yukawa) effective pair potential and a one-body volume energy, while nonlinear response modifies the effective interactions [A. R. Denton, \PR E {\bf 70}, 031404 (2004)]. The volume energy and effective pair potential are taken as input to a variational free energy, based on thermodynamic perturbation theory. For both linear and first-order nonlinear effective interactions, a coexistence analysis applied to aqueous suspensions of highly charged macroions and monovalent microions yields bulk separation of macroion-rich and macroion-poor phases below a critical salt concentration, in qualitative agreement with predictions of related linearized theories [R. van Roij, M. Dijkstra, and J.-P. Hansen, \PR E {\bf 59}, 2010 (1999); P. B. Warren, \JCP {\bf 112}, 4683 (2000)]. It is concluded that nonlinear screening can modify phase behavior but does not necessarily suppress bulk phase separation of deionized suspensions.Comment: 14 pages of text + 9 figure

The MobyDick Project: A Mobile Heterogeneous All-IP Architecture

Proceedings of Advanced Technologies, Applications and Market Strategies for 3G (ATAMS 2001). Cracow, Poland: 17-20 June, 2001.This paper presents the current stage of an IP-based architecture for heterogeneous environments, covering UMTS-like W-CDMA wireless access technology, wireless and wired LANs, that is being developed under the aegis of the IST Moby Dick project. This architecture treats all transmission capabilities as basic physical and data-link layers, and attempts to replace all higher-level tasks by IP-based strategies. The proposed architecture incorporates aspects of mobile-IPv6, fast handover, AAA-control, and Quality of Service. The architecture allows for an optimised control on the radio link layer resources. The Moby dick architecture is currently under refinement for implementation on field trials. The services planned for trials are data transfer and voice-over-IP.Publicad

Nonlinear Screening and Effective Electrostatic Interactions in Charge-Stabilized Colloidal Suspensions

A nonlinear response theory is developed and applied to electrostatic interactions between spherical macroions, screened by surrounding microions, in charge-stabilized colloidal suspensions. The theory describes leading-order nonlinear response of the microions (counterions, salt ions) to the electrostatic potential of the macroions and predicts microion-induced effective many-body interactions between macroions. A linear response approximation [Phys. Rev. E 62, 3855 (2000)] yields an effective pair potential of screened-Coulomb (Yukawa) form, as well as a one-body volume energy, which contributes to the free energy. Nonlinear response generates effective many-body interactions and essential corrections to both the effective pair potential and the volume energy. By adopting a random-phase approximation (RPA) for the response functions, and thus neglecting microion correlations, practical expressions are derived for the effective pair and triplet potentials and for the volume energy. Nonlinear screening is found to weaken repulsive pair interactions, induce attractive triplet interactions, and modify the volume energy. Numerical results for monovalent microions are in good agreement with available ab initio simulation data and demonstrate that nonlinear effects grow with increasing macroion charge and concentration and with decreasing salt concentration. In the dilute limit of zero macroion concentration, leading-order nonlinear corrections vanish. Finally, it is shown that nonlinear response theory, when combined with the RPA, is formally equivalent to the mean-field Poisson-Boltzmann theory and that the linear response approximation corresponds, within integral-equation theory, to a linearized hypernetted-chain closure.Comment: 30 pages, 8 figures, Phys. Rev. E (in press