Low-energy ion beamline scattering apparatus for surface science investigations

We report on the design, construction, and performance of a high current (monolayers/s), mass-filtered ion beamline system for surface scattering studies using inert and reactive species at collision energies below 1500 eV. The system combines a high-density inductively coupled plasma ion source, high-voltage floating beam transport line with magnet mass-filter and neutral stripping, decelerator, and broad based detection capabilities (ions and neutrals in both mass and energy) for products leaving the target surface. The entire system was designed from the ground up to be a robust platform to study ion-surface interactions from a more global perspective, i.e., high fluxes (>100 µA/cm2) of a single ion species at low, tunable energy (50–1400±5 eV full width half maximum) can be delivered to a grounded target under ultrahigh vacuum conditions. The high current at low energy problem is solved using an accel-decel transport scheme where ions are created at the desired collision energy in the plasma source, extracted and accelerated to high transport energy (20 keV to fight space charge repulsion), and then decelerated back down to their original creation potential right before impacting the grounded target. Scattered species and those originating from the surface are directly analyzed in energy and mass using a triply pumped, hybrid detector composed of an electron impact ionizer, hemispherical electrostatic sector, and rf/dc quadrupole in series. With such a system, the collision kinematics, charge exchange, and chemistry occurring on the target surface can be separated by fully analyzing the scattered product flux. Key design aspects of the plasma source, beamline, and detection system are emphasized here to highlight how to work around physical limitations associated with high beam flux at low energy, pumping requirements, beam focusing, and scattered product analysis. Operational details of the beamline are discussed from the perspective of available beam current, mass resolution, projectile energy spread, and energy tunability. As well, performance of the overall system is demonstrated through three proof-of-concept examples: (1) elastic binary collisions at low energy, (2) core-level charge exchange reactions involving 20Ne+ with Mg/Al/Si/P targets, and (3) reactive scattering of CF2+/CF3+ off Si. These studies clearly demonstrate why low, tunable incident energy, as well as mass and energy filtering of products leaving the target surface is advantageous and often essential for studies of inelastic energy losses, hard-collision charge exchange, and chemical reactions that occur during ion-surface scattering

Charge-exchange mechanisms at the threshold for inelasticity in Ne+ collisions with surfaces

We present a study on scattering of 100–1400 eV Ne+ ions off Mg, Al, Si, and P surfaces. Exit energy distributions and yields of single-scattered Ne+ and Ne2+ were separately measured to investigate charge exchange mechanisms occurring at the onset of inelastic losses in binary hard collision events. At low incident energies, collisions appear elastic and projectile ion survival is dominated by nonlocal Auger-type neutralization involving the target valence band. However, once a critical Rmin (distance of closest approach) is reached, three phenomena occur simultaneously: Ne2+ generation, reversal of the Ne+ yield trend, and inelastic losses in Ne+ and Ne2+. Rmin values for the Ne2+ turn-on agree very well with the L-shell overlap distances of the colliding partners, suggesting that electron transfer involving the highly promoted 4fsigma molecular orbital (correlated to the Ne 2p) at close internuclear distance (~0.5 Å) is responsible. For the Ne+ yield, a clear transition from nonlocal neutralization to Rmin-dependent collision induced neutralization was observed. Binary collision inelasticities (Qbin) were evaluated for Ne+ and Ne2+ off Al and Si by taking into account electron straggling. Saturation-like behavior at RminNe** (2p43s2, 41–45 eV) and Ne+-->Ne+** (2p33s2/3s3p, 69–72 eV), followed by autoionization as the projectile leaves the surface region to give Ne+ and Ne2+. In contrast, Qbin values for Ne2+ at the +2 turn-on were seen much lower (35–40 eV off Al, 55–60 eV off Si) than that required for double promotion—eliminating the possibility that Ne2+ is only generated in double excitation of surviving Ne+. Thus single-electron excitation appears to be more important in the threshold region compared to the two-electron events seen at higher collision energies. In addition, the Ne+[Single Bond]P system shows striking similarities with the other target cases from the perspective of a well-defined Ne2+ turn-on, continually increasing Ne2+ yield with impact energy, and inelasticity values which point to the same 4fsigma excitation pathway. The decreasing Rmin requirement for higher target Z in terms of Ne2+ production has been confirmed for the Mg through P series, where hard collision excitation is governed by L-shell orbital overlaps

Evidence of Simultaneous Double-Electron Promotion in F+ Collisions with Surfaces

A high-flux beam of mass-filtered F+ at low energy (100–1300 eV) was scattered off Al and Si surfaces to study core-level excitations of F0 and F+. Elastic scattering behavior for F+ was observed at energies 450 (700) eV off Al (Si) produces F2+—behavior which is remarkably similar to Ne+ off the same surfaces. Inelasticities measured for single collision events agree well with the energy deficits required to form (doubly excited) F** and F+** states from F0 and F+, respectively; these excited species most likely decay to inelastic F+ and F2+ via autoionization

Harnessing the power of AI in business

The the first of the two masterclasses delivered to local microcompanies, SMEs and businesses designed to help them learn about digital technologies and AI and strategies helping them to implementing digital tools/ AI into their business. Key themes and objectives: - Introduction to AI in business and AI technologies - Challenges and benefits of AI to business – real-world examples and tips - Adoption challenges and how to overcome them - Responsible and ethical use of AI - Application of AI in your business (marketing, finance, healthcare) Benefits: - Organisations will gain an understanding of digital transformation in small business - Learn practical tips about tools that can be applied in the workplace to support change Who for? Small to medium sized organisations (SMEs) with an appetite for enhancing business capabilities and staying ahead in today’s competitive landscape

Measuring Extinction Curves of Lensing Galaxies

We critique the method of constructing extinction curves of lensing galaxies using multiply imaged QSOs. If one of the two QSO images is lightly reddened or if the dust along both sightlines has the same properties then the method works well and produces an extinction curve for the lensing galaxy. These cases are likely rare and hard to confirm. However, if the dust along each sightline has different properties then the resulting curve is no longer a measurement of extinction. Instead, it is a measurement of the difference between two extinction curves. This "lens difference curve'' does contain information about the dust properties, but extracting a meaningful extinction curve is not possible without additional, currently unknown information. As a quantitative example, we show that the combination of two Cardelli, Clayton, & Mathis (CCM) type extinction curves having different values of R(V) will produce a CCM extinction curve with a value of R(V) which is dependent on the individual R(V) values and the ratio of V band extinctions. The resulting lens difference curve is not an average of the dust along the two sightlines. We find that lens difference curves with any value of R(V), even negative values, can be produced by a combination of two reddened sightlines with different CCM extinction curves with R(V) values consistent with Milky Way dust (2.1 < R(V) < 5.6). This may explain extreme values of R(V) inferred by this method in previous studies. But lens difference curves with more normal values of R(V) are just as likely to be composed of two dust extinction curves with R(V) values different than that of the lens difference curve. While it is not possible to determine the individual extinction curves making up a lens difference curve, there is information about a galaxy's dust contained in the lens difference curves.Comment: 15 pages, 4 figues, ApJ in pres

User's guide for the Total-Ozone Mapping Spectrometer (TOMS) instrument first year ozone T data set

The TOMS experiment and algorithms are described. Detailed information on the data available on computer tape is provided