5 research outputs found
Application of Mg-Mesoporous Alumina Prepared by Using Magnesium Stearate as a Template for the Removal of Nickel: Kinetics, Isotherm, and Error Analysis
Ultraclean Fuels Production and Utilization for the Twenty-First Century: Advances toward Sustainable Transportation Fuels
Hydrocracking of Vacuum Gasoil on NiMo/AAS-Al2O3 Catalysts Prepared from Citric Acid: Effect of the Catalyst Heat Treatment Temperature
Thermal spreading as an alternative for the wet impregnation method: Advantages and downsides in the preparation of MoO 3/SiO 2-Al 2O 3 metathesis catalysts
peer reviewedSilica-alumina-supported MoO 3 catalysts are classically prepared via impregnation of the support with a molybdenum salt solution, usually ammonium heptamolybdate, and subsequent drying and calcination (three steps). The downsides of such a route for the synthesis of heterogeneous metathesis catalysts are linked to the limited control on the nature of the MoO x stabilized at the surface, to the uneven distribution of the deposit in the pores of the support, and to the build up of inactive species that find their origin in the wet step of the preparation. In opposition, the direct thermal spreading of molybdenum oxide onto the support is a straightforward (one step) method involving no wet stage. It allows the conversion of bulk MoO 3 crystals to amorphous molybdate species dispersed at the surface of the silica-alumina support. This contribution shows that the catalysts obtained via both methods exhibit similar performances in the self-metathesis of propene to butene and ethene. However, based on XRD, XPS, Raman spectroscopy, ICP-AES, N 2 physisorption, TEM, and MAS-NMR spectroscopy, it is shown that the origin of active and inactive species in the two systems is different. Whereas the activity of wet-made catalysts is limited by the formation of bulky MoO 3 crystals and of aluminum molybdate, the performances of dry-made catalysts are limited by the incomplete spreading of MoO 3 nanocrystallites. © 2010 American Chemical Society