Calculation of the Voronoi boundary for lens-shaped particles and spherocylinders

We have recently developed a mean-field theory to estimate the packing fraction of non-spherical particles [A. Baule et al., Nature Commun. (2013)]. The central quantity in this framework is the Voronoi excluded volume, which generalizes the standard hard-core excluded volume appearing in Onsager's theory. The Voronoi excluded volume is defined from an exclusion condition for the Voronoi boundary between two particles, which is usually not tractable analytically. Here, we show how the technical difficulties in calculating the Voronoi boundary can be overcome for lens-shaped particles and spherocylinders, two standard prolate and oblate shapes with rotational symmetry. By decomposing these shapes into unions and intersections of spheres analytical expressions can be obtained.Comment: 19 pages, 8 figure

CHEMICALLY MODIFIED PHOTOSYNTHETIC BACTERIAL REACTION CENTERS: CIRCULAR DICHROISM, RAMAN RESONANCE, LOW TEMPERATURE ABSORPTION, FLUORESCENCE AND ODMR SPECTRA AND POLYPEPTIDE COMPOSITION OF BOROHYDRIDE TREATED REACTION CENTERS FROM Rhodobacter sphaeroides R26

Reaction centers from Rhodobacter sphaeroides have been modified by treatment with sodium borohydride similar to the original procedure [Ditson et al., Biochim. Biophys. Acta 766, 623 (1984)], and investigated spectroscopically and by gel electrophoresis. (1) Low temperature (1.2 K) absorption, fluorescence, absorption- and fluorescence-detected ODMR, and microwave-induced singlet-triplet absorption difference spectra (MIA) suggest that the treatment produces a spectroscopically homogeneous preparation with one of the ‘additional’ bacteriochlorophylls being removed. The modification does not alter the zero field splitting parameters of the primary donor triplet (TP870). (2) From the circular dichroism and Raman resonance spectra in the1500–1800 cm-1 region, the removed pigment is assigned to BchlM, e.g. the "extra" Bchl on the "inactive" M-branch. (3) A strong coupling among all pigment molecules is deduced from the circular dichroism spectra, because pronounced band-shifts and/or intensity changes occur in the spectral components assigned to all pigments. This is supported by distinct differences among the MIA spectra of untreated and modified reaction centers, as well as by Raman resonance. (4) The modification is accompanied by partial proteolytic cleavage of the M-subunit. The preparation is thus spectroscopically homogeneous, but biochemically heterogenous

The DWD climate predictions website: Towards a seamless outlook based on subseasonal, seasonal and decadal predictions

The climate predictions website of the Deutscher Wetterdienst (DWD, https://www.dwd.de/climatepredictions) presents a consistent operational outlook for the coming weeks, months and years, focusing on the needs of German users. At global scale, subseasonal predictions from the European Centre of Medium-Range Weather Forecasts as well as seasonal and decadal predictions from the DWD are used. Statistical downscaling is applied to achieve high resolution over Germany. Lead-time dependent bias correction is performed on all time scales. Additionally, decadal predictions are recalibrated. The website offers ensemble mean and probabilistic predictions for temperature and precipitation combined with their skill (mean squared error skill score, ranked probability skill score). Two levels of complexity are offered: basic climate predictions display simple, regionally averaged information for Germany, German regions and cities as maps, time series and tables. The skill is presented as traffic light. Expert climate predictions show complex, gridded predictions for Germany (at high resolution), Europe and the world as maps and time series. The skill is displayed as the size of dots. Their color is related to the signal in the prediction. The website was developed in cooperation with users from different sectors via surveys, workshops and meetings to guarantee its understandability and usability. The users realize the potential of climate predictions, but some need advice in using probabilistic predictions and skill. Future activities will include the further development of predictions to improve skill (multi-model ensembles, teleconnections), the introduction of additional products (data provision, extremes) and the further clarification of the information (interactivity, video clips)

Effective Monopoles within Thick Branes

The monopole mass is revealed to be considerably modified in the thick braneworld paradigm, and depends on the position of the monopole in the brane as well. Accordingly, the monopole radius continuously increases, leading to an unacceptable setting that can be circumvented when the brane thickness has an upper limit. Despite such peculiar behavior, the quantum corrections accrued -- involving the classical monopole solution -- are shown to be still under control. We analyze the monopole's peculiarities also taking into account the localization of the gauge fields. Furthermore, some additional analysis in the thick braneworld context and the similar behavior evinced by the topological string are investigated.Comment: 7 pages, 1 figur

Carbon-grain sublimation: a new top-down component of protostellar chemistry

Earth's carbon deficit has been an outstanding problem in our understanding of the formation of our Solar System. A possible solution would be the sublimation of carbon grains at the so-called soot line (~300 K) early in the planet-formation process. Here, we argue that the most likely signatures of this process are an excess of hydrocarbons and nitriles inside the soot line, and a higher excitation temperature for these molecules compared to oxygen-bearing complex organics that desorb around the water snowline (~100 K). Such characteristics have been reported in the literature, for example, in Orion KL, although not uniformly, potentially due to differences in observational settings and analysis methods of different studies or related to the episodic nature of protostellar accretion. If this process is active, this would mean that there is a heretofore unknown component to the carbon chemistry during the protostellar phase that is acting from the top down - starting from the destruction of larger species - instead of from the bottom up from atoms. In the presence of such a top-down component, the origin of organic molecules needs to be re-explored.Comment: Accepted for publication in ApJL. 14 pages, 2 figures, 1 table (4 pages

Evaluation of Electrostatic Particle Ionization and BioCurtain Technologies to Reduce Dust, Odor and other Pollutants from Broiler Houses Final Report

Confined poultry production has increased in Texas and along with it, complaints of odor and dust. These issues are a major problem in the United States not only for confined animal health but also for the increasing urban migration to the rural areas where the poultry industry is expanding. Particulate matter and volatile organic compound (VOC) produced in the poultry houses can be offensive to neighbors, and if not properly vented, pose a serious health hazard to the animals. Some technologies available attempt to strike a balance between reducing poultry house emissions and maintaining bird health; however there is a lack of sufficient pollutant- reduction data to make a sound fiscal judgment in the implementation of this equipment. Two possible management tools that have shown promise and were chosen for evaluation during this project were an Electrostatic Particle Ionization (EPI™) system and a BioCurtain™. The EPI™ system includes an antenna-like array of wire strung through the poultry house with a small electric charge running through it. The resulting electric field ionizes the particulate matter suspended in the air, causing it to attract to grounded materials. The BioCurtain™ consists of a black geotextile fabric stretched over a quadrant-shaped, metal frame skeleton, and placed over the exhaust fans of the poultry houses. Air moving out of the house flows down along the top of the quadrant and particulate matter settles out on the ground. The air, without the particulate matter, then flows vertically out through the top of the BioCurtain™. This project tested the effectiveness of a BioCurtain™ and Electrostatic Particle Ionization (EPI™) system in reducing NH3, H2S, and TSP emissions from a broiler house during short periods in September and December 2010. This project found: 1) A reduction of about 9%, in the emission of NH3 and H2S gases (1060 vs. 960 g/hr for NH3 and 9.3 vs. 8.5 g/hr. for H2S) in December when only the BioCurtain™ was active. 2) The BioCurtain™ resulted in a 34% (325 vs. 213 g/hr. in September) to 43% (396 vs. 227 g/hr in December) reduction in the TSP emission. 3) The EPI™ system reduced the NH3 and TSP emission rates by as much as 17% and 39%, respectively

Developmental changes in spinal neuronal properties, motor network configuration, and neuromodulation at free-swimming stages of Xenopus tadpoles

We describe a novel preparation of the isolated brainstem and spinal cord from pro-metamorphic tadpole stages of the South African clawed frog (Xenopus laevis) that permits whole cell patch-clamp recordings from neurons in the ventral spinal cord. Previous research on earlier stages of the same species has provided one of the most detailed understandings of the design and operation of a CPG circuit. Here we have addressed how development sculpts complexity from this more basic circuit. The preparation generates bouts of fictive31 swimming activity either spontaneously or in response to electrical stimulation of the optic tectum, allowing an investigation into how the neuronal properties, activity patterns and neuromodulation of locomotor rhythm generation change during development. We describe an increased repertoire of cellular responses compared to younger larval stages and investigate the cellular level effects of nitrergic neuromodulation as well as the development of a sodium pump-mediated ultra-slow afterhyperpolarisation (usAHP) in these free-swimming larval animals.PostprintPeer reviewe