2,292 research outputs found
Hot Atom Chemistry and Recoil Implantation Induced Reaction in Geometrical Isomers of Tris-(benzoylacetonato)Cr(III)
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Charge-Density-Wave Ordering in the Metal-Insulator Transition Compound PrRu4P12
X-ray and electron diffraction measurements on the metal-insulator (M-I)
transition compound PrRuP have revealed the emergence of a periodic
ordering of charge density around the Pr atoms. It is found that the ordering
is associated with the onset of a low temperature insulator phase. These
conclusions are supported by the facts that the space group of the crystal
structure transforms from Im to Pm below the M-I transition
temperature and also that the temperature dependence of the superlattice peaks
in the insulator phase follows the squared BCS function. The M-I transition
could be originated from the perfect nesting of the Fermi surface and/or the
instability of the electrons.Comment: 4 pages, 5 figures, Phys. Rev. B (2004) (in press
Metal-insulator transition in PrRuP and SmRuP investigated by optical spectroscopy
Electronic structures of the filled-skutterudite compounds PrRuP
and SmRuP, which undergo a metal-insulator transition (MIT) at
= 60 K and 16 K, respectively, have been studied by means of
optical spectroscopy. Their optical conductivity spectra develop an energy gap
of 10 meV below . The observed characteristics of the energy
gap are qualitatively different from those of the Kondo semiconductors. In
addition, optical phonon peaks in the spectra show anomalies upon the MIT,
including broadening and shifts at and an appearance of new peaks
below . These results are discussed in terms of density waves or
orbital ordering previously predicted for these compounds.Comment: 4pages, 4figures, submitted to Physical Review
Theory of Metal-Insulator Transition in PrRu4P12 and PrFe4P12
All symmetry allowed couplings between the 4f^2-electron ground state doublet
of trivalent praseodymium in PrRu4P12 and PrFe4P12 and displacements of the
phosphorus, iron or ruthenium ions are considered. Two types of displacements
can change the crystal lattice from body-centred cubic to simple orthorhombic
or to simple cubic. The first type lowers the point group symmetry from
tetrahedral to orthorhombic, while the second type leaves it unchanged, with
corresponding space group reductions Im3 --> Pmmm and Im3 --> Pm3 respectively.
In former case, the lower point-group symmetry splits the degeneracy of the
4f^2 doublet into states with opposite quadrupole moment, which then leads to
anti-quadrupolar ordering, as in PrFe4P12. Either kind of displacement may
conspire with nesting of the Fermi surface to cause the metal-insulator or
partial metal-insulator transition observed in PrFe4P12 and PrRu4P12. We
investigate this scenario using band-structure calculations, and it is found
that displacements of the phosphorus ions in PrRu4P12 (with space group
reduction Im3 --> Pm3) open a gap everywhere on the Fermi surface.Comment: 6 page
31P-NMR and muSR Studies of Filled Skutterudite Compound SmFe4P12: Evidence for Heavy Fermion Behavior with Ferromagnetic Ground State
The 31P-NMR (nuclear magnetic resonance) and muSR (muon spin relaxation)
measurements on the filled skutterudite system SmFe4P12 have been carried out.
The temperature T dependence of the 31P-NMR spectra indicates the existence of
the crystalline electric field effect splitting of the Sm3+$ (J = 5/2)
multiplet into a ground state and an excited state of about 70 K. The
spin-lattice relaxation rate 1/T1 shows the typical behavior of the Kondo
system, i.e., 1/T1 is nearly T independent above 30 K, and varies in proportion
to T (the Korringa behavior, 1/T1 \propto T) between 7.5 K and 30 K. The T
dependence deviated from the Korringa behavior below 7 K, which is independent
of T in the applied magnetic field of 1 kOe, and suppressed strongly in higher
fields. The behavior is explained as 1/T1is determined by ferromagnetic
fluctuations of the uncovered Sm3+ magnetic moments by conduction electrons.
The muSR measurements in zero field show the appearance of a static internal
field associated with the ferromagnetic order below 1.6 K.Comment: 6 pages, 9 figures, to be published in J. Phys. Soc. Jpn. 75 (2006
Snthesis of Technetium Complexes in High Oxidation State I: Formation of Nitridotechnetium(VI) μ-oxo Dimer Compexes with Edta and Edda
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