33 research outputs found

    Long-Range Structures of Amorphous Solid Water

    Get PDF

    Analysis of the ITER ECH Upper Port Launcher remote maintenance using virtual reality

    No full text
    All ITER sub-systems of remote handling (RH) classes 1 and 2 have to be remotely maintainable. The maintenance strategy for these components has to ensure system availability after failure or scheduled maintenance. This paper shows how virtual reality (VR) simulation [1] can be used as a tool to analyze the maintenance process, to predict the mean time to repair and to ensure the RH compatibility of one ITER sub-system, the Upper Port Launcher (UPL) [2]. Special emphasis is put on the development of RH procedures and the identification of tooling requirements. The possibility to simulate RH logistics and repair actions in an early stage of the design process allows for the identification of those maintenance actions that require dedicated tests in the Launcher Handling Test Facility at Karlsruhe. The VR analysis, together with dedicated mock-up tests will demonstrate the RH compatibility of the UPL plug, provide input to the design of the Port Plug maintenance area in the ITER Hot Cell, and support the development of RH maintenance tooling. © 2009

    Following the Crystallization of Amorphous Ice after Ultrafast Laser Heating

    No full text
    [Image: see text] Using time-resolved wide-angle X-ray scattering, we investigated the early stages (10 μs–1 ms) of crystallization of supercooled water, obtained by the ultrafast heating of high- and low-density amorphous ice (HDA and LDA) up to a temperature T = 205 K ± 10 K. We have determined that the crystallizing phase is stacking disordered ice (I(sd)), with a maximum cubicity of χ = 0.6, in agreement with predictions from molecular dynamics simulations at similar temperatures. However, we note that a growing small portion of hexagonal ice (I(h)) was also observed, suggesting that within our timeframe, I(sd) starts annealing into I(h). The onset of crystallization, in both amorphous ice, occurs at a similar temperature, but the observed final crystalline fraction in the LDA sample is considerably lower than that in the HDA sample. We attribute this discrepancy to the thickness difference between the two samples

    Diffusive dynamics during the high-to-low density transition in amorphous ice

    No full text
    Water exists in high- and low-density amorphous ice forms (HDA and LDA), which could correspond to the glassy states of high- (HDL) and low-density liquid (LDL) in the metastable part of the phase diagram. However, the nature of both the glass transition and the high-to-low-density transition are debated and new experimental evidence is needed. Here we combine wide-angle X-ray scattering (WAXS) with X-ray photon-correlation spectroscopy (XPCS) in the small-angle X-ray scattering (SAXS) geometry to probe both the structural and dynamical properties during the high-to-low-density transition in amorphous ice at 1 bar. By analyzing the structure factor and the radial distribution function, the coexistence of two structurally distinct domains is observed at T = 125 K. XPCS probes the dynamics in momentum space, which in the SAXS geometry reflects structural relaxation on the nanometer length scale. The dynamics of HDA are characterized by a slow component with a large time constant, arising from viscoelastic relaxation and stress release from nanometer-sized heterogeneities. Above 110 K a faster, strongly temperature-dependent component appears, with momentum transfer dependence pointing toward nanoscale diffusion. This dynamical component slows down after transition into the low-density form at 130 K, but remains diffusive. The diffusive character of both the high- and low-density forms is discussed among different interpretations and the results are most consistent with the hypothesis of a liquid–liquid transition in the ultraviscous regime
    corecore