Theory of interfacial charge-transfer complex photophysics in π\pi-conjugated polymer-fullerene blends

We present a theory of the electronic structure and photophysics of 1:1 blends of derivatives of polyparaphenylenevinylene and fullerenes. Within the same Coulomb-correlated Hamiltonian applied previously to interacting chains of single-component $\pi$-conjugated polymers, we find an exciplex state that occurs below the polymer's optical exciton. Weak absorption from the ground state occurs to the exciplex. We explain transient photoinduced absorptions in the blend, observed for both above-gap and below-gap photoexcitations, within our theory. Photoinduced absorptions for above-gap photoexcitation are from the optical exciton as well as the exciplex, while for below-gap photoexcitation induced absorptions are from the exciplex alone. In neither case are free polarons generated in the time scale of the experiment. Importantly, the photophysics of films of single-component $\pi$-conjugated polymers and blends can both be understood by extending Mulliken's theory of ground-state charge transfer to the case of excited-state charge transfer.Comment: 9 pages, 8 figure

A Link to the Past: Using Markov Chain Monte Carlo Fitting to Constrain Fundamental Parameters of High-Redshift Galaxies

We have a developed a new method for fitting spectral energy distributions (SEDs) to identify and constrain the physical properties of high-redshift (4 < z < 8) galaxies. Our approach uses an implementation of Bayesian based Markov Chain Monte Carlo (PiMC^2) that allows us to compare observations to arbitrarily complex models and to compute 95% credible intervals that provide robust constraints for the model parameters. The work is presented in 2 sections. In the first, we test PiMC^2 using simulated SEDs to not only confirm the recovery of the known inputs but to assess the limitations of the method and identify potential hazards of SED fitting when applied specifically to high redshift (z>4) galaxies. Our tests reveal five critical results: 1) the ability to confidently constrain metallicity, population ages, and Av all require photometric accuracy better than what is currently achievable (i.e. less than a few percent); 2) the ability to confidently constrain stellar masses (within a factor of two) can be achieved without the need for high-precision photometry; 3) the addition of IRAC photometry does not guarantee that tighter constraints of the stellar masses and ages can be defined; 4) different assumptions about the star formation history can lead to significant biases in mass and age estimates; and 5) we are able to constrain stellar age and Av of objects that are both young and relatively dust free. In the second part of the paper we apply PiMC^2 to 17 4<z<8 objects, including the GRAPES Ly alpha sample (4<z<6), supplemented by HST/WFC3 near-IR observations, and several broad band selected z>6 galaxies. Using PiMC^2, we are able to constrain the stellar mass of these objects and in some cases their stellar age and find no evidence that any of these sources formed at a redshift much larger than z_f=8, a time when the Universe was ~ 0.6 Gyr old.Comment: Submitted to ApJ (Full abstract, 47 pages, 17 figures, 7 tables

A Link to the Past: Using Markov Chain Monte Carlo Fitting to Constrain Fundamental Parameters of High-Redshift Galaxies

We have a developed a new method for fitting spectral energy distributions (SEDs) to identify and constrain the physical properties of high-redshift (4 < z < 8) galaxies. Our approach uses an implementation of Bayesian based Markov Chain Monte Carlo (PiMC^2) that allows us to compare observations to arbitrarily complex models and to compute 95% credible intervals that provide robust constraints for the model parameters. The work is presented in 2 sections. In the first, we test PiMC^2 using simulated SEDs to not only confirm the recovery of the known inputs but to assess the limitations of the method and identify potential hazards of SED fitting when applied specifically to high redshift (z>4) galaxies. Our tests reveal five critical results: 1) the ability to confidently constrain metallicity, population ages, and Av all require photometric accuracy better than what is currently achievable (i.e. less than a few percent); 2) the ability to confidently constrain stellar masses (within a factor of two) can be achieved without the need for high-precision photometry; 3) the addition of IRAC photometry does not guarantee that tighter constraints of the stellar masses and ages can be defined; 4) different assumptions about the star formation history can lead to significant biases in mass and age estimates; and 5) we are able to constrain stellar age and Av of objects that are both young and relatively dust free. In the second part of the paper we apply PiMC^2 to 17 4<z<8 objects, including the GRAPES Ly alpha sample (4<z<6), supplemented by HST/WFC3 near-IR observations, and several broad band selected z>6 galaxies. Using PiMC^2, we are able to constrain the stellar mass of these objects and in some cases their stellar age and find no evidence that any of these sources formed at a redshift much larger than z_f=8, a time when the Universe was ~ 0.6 Gyr old.Comment: Submitted to ApJ (Full abstract, 47 pages, 17 figures, 7 tables

The Correlation Between Galaxy HI Linewidths and K' Luminosities

The relationship between galaxy luminosities and rotation rates is studied with total luminosities in the K' band. Extinction problems are essentially eliminated at this band centered at 2.1 micron. A template luminosity-linewidth relation is derived based on 65 galaxies drawn from two magnitude-limited cluster samples. The zero-point is determined using 4 galaxies with accurately known distances. The calibration is applied to give the distance to the Pisces Cluster (60 Mpc) at a redshift in the CMB frame of 4771 km/s. The resultant value of the Hubble Constant is 81 km/s/Mpc. The largest sources of uncertainty arises from the small number of zero-point calibrators at this time at K' and present application to only one cluster.Comment: 13 pages including 5 figures and 2 tables. Accepted for publication in Astrophysical Journa

Evidence for Excimer Photoexcitations in an Ordered {\pi}-Conjugated Polymer Film

We report pressure-dependent transient picosecond and continuous-wave photomodulation studies of disordered and ordered films of 2-methoxy-5-(2-ethylhexyloxy) poly(para-phenylenevinylene). Photoinduced absorption (PA) bands in the disordered film exhibit very weak pressure dependence and are assigned to intrachain excitons and polarons. In contrast, the ordered film exhibits two additional transient PA bands in the midinfrared that blueshift dramatically with pressure. Based on high-order configuration interaction calculations we ascribe the PA bands in the ordered film to excimers. Our work brings insight to the exciton binding energy in ordered films versus disordered films and solutions. The reduced exciton binding energy in ordered films is due to new energy states appearing below the continuum band threshold of the single strand.Comment: 5.5 pages, 5 figure

Buried Black Hole Growth in IR-selected Mergers: New Results from Chandra

Observations and theoretical simulations suggest that a significant fraction of merger-triggered accretion onto supermassive black holes is highly obscured, particularly in late-stage galaxy mergers, when the black hole is expected to grow most rapidly. Starting with the Wide-Field Infrared Survey Explorer all-sky survey, we identified a population of galaxies whose morphologies suggest ongoing interaction and which exhibit red mid-infrared colors often associated with powerful active galactic nuclei (AGNs). In a follow-up to our pilot study, we now present Chandra/ACIS and XMM-Newton X-ray observations for the full sample of the brightest 15 IR-preselected mergers. All mergers reveal at least one nuclear X-ray source, with 8 out of 15 systems exhibiting dual nuclear X-ray sources, highly suggestive of single and dual AGNs. Combining these X-ray results with optical line ratios and with near-IR coronal emission line diagnostics, obtained with the near-IR spectrographs on the Large Binocular Telescope, we confirm that 13 out of the 15 mergers host AGNs, two of which host dual AGNs. Several of these AGNs are not detected in the optical. All X-ray sources appear X-ray weak relative to their mid-infrared continuum, and of the nine X-ray sources with sufficient counts for spectral analysis, eight reveal strong evidence of high absorption with column densities of $N_\mathrm{H} \gtrsim 10^{23}$~cm$^{-2}$. These observations demonstrate that a significant population of single and dual AGNs are missed by optical studies, due to high absorption, adding to the growing body of evidence that the epoch of peak black hole growth in mergers occurs in a highly obscured phase.Comment: 29 pages, 22 figures; (Main text: 17 pages, 4 figures

Polarization dependence of four-wave mixing in a degenerate two-level system

Nearly degenerate four-wave mixing (NDFWM) within a closed degenerate two-level atomic transition is theoretically and experimentally examined. Using the model presented by A. Lezama et al [Phys. Rev. A 61, 013801 (2000)] the NDFWM spectra corresponding to different pump and probe polarization cases are calculated and discussed. The calculated spectra are compared to the observation of NDFWM within the $6S_{1/2}(F=4)\to 6P_{3/2}(F=5)$ transition of cesium in a phase conjugation experiment using magneto optically cooled atomsComment: 10 pages, 13 figures; submitted to Phys. Rev.

Photogeneration Dynamics of a Soliton Pair in Polyacetylene

Dynamical process of the formation of a soliton pair from a photogenerated electron-hole pair in polyacetylene is studied numerically by adopting the SSH Hamiltonian. A weak local disorder is introduced in order to trigger the formation. Starting from an initial configuration with an electron at the bottom of the conduction band and a hole at the top of the valence band, separated by the Peierls gap, the time dependent Schr${\rm \ddot{o}}$ndinger equation for the electron wave functions and the equation of motion for the lattice displacements are solved numerically. After several uniform oscillations of the lattice system at the early stage, a large distortion corresponding to a pair of a soliton and an anti-soliton develops from a point which is determined by the location and type of the disorder. In some cases, two solitons run in opposite directions, leaving breather like oscillations behind, and in other cases they form a bound state emitting acoustic lattice vibrational modes.Comment: 16 pages 7 figure

A Deep HST H-Band Imaging Survey of Massive Gas-Rich Mergers. II. The QUEST PG QSOs

We report the results from a deep HST NICMOS H-band imaging survey of 28 z < 0.3 QSOs from the Palomar-Green (PG) sample. This program is part of QUEST (Quasar / ULIRG Evolution STudy) and complements a similar set of data on 26 highly-nucleated ULIRGs presented in Paper I. Our analysis indicates that the fraction of QSOs with elliptical hosts is higher among QSOs with undetected far-infrared (FIR) emission, small infrared excess, and luminous hosts. The hosts of FIR-faint QSOs show a tendency to have less pronounced merger-induced morphological anomalies and larger QSO-to-host luminosity ratios on average than the hosts of FIR-bright QSOs, consistent with late-merger evolution from FIR-bright to FIR-faint QSOs. The spheroid sizes and total host luminosities of the radio-quiet PG QSOs in our sample are statistically indistinguishable from the ULIRG hosts presented in Paper I, while those of radio-loud PG QSOs are systematically larger and more luminous. ULIRGs and PG QSOs with elliptical hosts fall near, but not exactly on, the fundamental plane of inactive spheroids. We confirm the systematic trend noted in Paper I for objects with small (< 2 kpc) spheroids to be up to ~1 mag. brighter than inactive spheroids. The host colors and wavelength dependence of their sizes support the idea that these deviations are due at least in part to non-nuclear star formation. However, the amplitudes of these deviations does not depend on host R-H colors. Taken at face value (i.e., no correction for extinction or the presence of a young stellar population), the H-band spheroid-host luminosities imply BH masses ~5 -- 200 x 10^7 M_sun and sub-Eddington mass accretion rates for both QSOs and ULIRGs. These results are compared with published BH mass estimates derived from other methods. (abridged)Comment: Accepted for publication in the Astrophysical Journal, Vol. 701, August 20 issue. Paper with high-resolution figures can be downloaded at http://www.astro.umd.edu/~veilleux/pubs/nicmos2.pd

Black Hole Masses and Star Formation Rates of z >1 Dust Obscured Galaxies (DOGs): Results from Keck OSIRIS Integral Field Spectroscopy

We have obtained high spatial resolution Keck OSIRIS integral field spectroscopy of four z~1.5 ultra-luminous infrared galaxies that exhibit broad H-alpha emission lines indicative of strong AGN activity. The observations were made with the Keck laser guide star adaptive optics system giving a spatial resolution of 0.1", or <1 kpc at these redshifts. These high spatial resolution observations help to spatially separate the extended narrow-line regions --- possibly powered by star formation --- from the nuclear regions, which may be powered by both star formation and AGN activity. There is no evidence for extended, rotating gas disks in these four galaxies. Assuming dust correction factors as high as A(H-alpha)=4.8 mag, the observations suggest lower limits on the black hole masses of (1 - 9) x 10^8 solar masses, and star formation rates <100 solar masses per year. The black hole masses and star formation rates of the sample galaxies appear low in comparison to other high-z galaxies with similar host luminosities. We explore possible explanations for these observations including, host galaxy fading, black hole growth, and the shut down of star formation.Comment: Accepted for publication in the Astronomical Journal. 12 pages, 6 figures, 5 table