Atmospheric Polycyclic Aromatic Hydrocarbons: An Aspect of Air Pollution in Fairbanks, Alaska

Quantitative analysis of atmospheric polycyclic aromatic hydrocarbons (PAH) in Fairbanks, Alaska revealed significant levels of representative components. A fairly constant PAH pattern was observed throughout the winter of 1976-77, and the absolute PAH level correlated with air stagnation. Consideration of relative levels of individual PAH components reveals vehicular emissions as the major source but also provides evidence for contributions from power plant emissions. Fairbanks' PAH levels approach those of major cities in more moderate climates, and this situation emphasizes the importance of air quality problems in development of the Arctic

Laser surface colouring of titanium for contemporary jewellery

This paper describes work which emerged through a need to understand more about the potential of laser surface engineering for use in the creative industries. The method of creation of contemporary jewellery pieces and the resultant 'Ocular' jewellery series are described from the creative point of view. The work demonstrates how laser controlled oxide growth on Ti–6Al–4V alloy under ambient conditions can be used as an artistic tool by producing precisely defined colours. Use of the method to produce regular areas of even colour and to reproduce freehand drawings on a titanium alloy surface is described. Analysis highlights interference as the main colouring mechanism and suggests a graded surface layer, progressing from an outer layer of TiO2 to lower layers rich in TiO and Ti2O. The model of research by practice presented in this paper offers a contribution to the current debate on partnerships between art and science and engineering

An index-based framework for assessing patterns and trends in river fragmentation and flow regulation by global dams at multiple scales

The global number of dam constructions has increased dramatically over the past six decades and is forecast to continue to rise, particularly in less industrialized regions. Identifying development pathways that can deliver the benefits of new infrastructure while also maintaining healthy and productive river systems is a great challenge that requires understanding the multifaceted impacts of dams at a range of scales. New approaches and advanced methodologies are needed to improve predictions of how future dam construction will affect biodiversity, ecosystem functioning, and fluvial geomorphology worldwide, helping to frame a global strategy to achieve sustainable dam development. Here, we respond to this need by applying a graph-based river routing model to simultaneously assess flow regulation and fragmentation by dams at multiple scales using data at high spatial resolution. We calculated the cumulative impact of a set of 6374 large existing dams and 3377 planned or proposed dams on river connectivity and river flow at basin and subbasin scales by fusing two novel indicators to create a holistic dam impact matrix for the period 1930–2030. Static network descriptors such as basin area or channel length are of limited use in hierarchically nested and dynamic river systems, so we developed the river fragmentation index and the river regulation index, which are based on river volume. These indicators are less sensitive to the effects of network configuration, offering increased comparability among studies with disparate hydrographies as well as across scales. Our results indicate that, on a global basis, 48% of river volume is moderately to severely impacted by either flow regulation, fragmentation, or both. Assuming completion of all dams planned and under construction in our future scenario, this number would nearly double to 93%, largely due to major dam construction in the Amazon Basin. We provide evidence for the importance of considering small to medium sized dams and for the need to include waterfalls to establish a baseline of natural fragmentation. Our versatile framework can serve as a component of river fragmentation and connectivity assessments; as a standardized, easily replicable monitoring framework at global and basin scales; and as part of regional dam planning and management strategies

Saltmarshes on peat substrate on the southwest coast of Ireland: edaphic parameters and plant species distribution

Abstract. Saltmarshes on peat substrate are common along the western Atlantic coast of Ireland. The peat which underlies these marshes was formed under freshwater conditions in post glacial times, after which these systems were subjected to a marine transgression. The aim of this study was to determine the relationship between edaphic factors, substrate type and saltmarsh vegetation, specifically investigating the role of edaphic factors in determining the distribution of saltmarsh species Atriplex portulacoides in Ireland. Edaphic parameters measured for each substrate included pH, moisture content, ammonium and nitrate. The peat was found to differ markedly from other substrates. Using canonical correspondence analysis it was found that pH and ammonium were the major drivers in influencing saltmarsh vegetation on peat substrate. Under both in situ and ex situ conditions Atriplex portulacoides showed an affinity for drier substrate and its absence from fringe marshes in Ireland is likely due to a combination of both biotic and abiotic factors, including intolerance to high soil moisture levels

Structural Studies on Alkylisocyanate Polymers by Thermal Degradation Tandem Mass Spectrometry

AbstractHomopolymers and copolymers of alkylisocyanates having n-hexyl, 2,6-dimethylheptyl, 3,7-dimethyloctyl, and (2,2-dimethyl-1,3-dioxolan-4-yl)methyl substituents underwent thermal degradation in the course of desorption electron ionization to yield trimers and monomers that were characterized in situ by tandem mass spectrometry. The trimers were trisubstituted cyanuric acids, the protonated molecules displaying a characteristic series of alkene eliminations on collision-induced dissociation to yield protonated cyanuric acid, m/z 130. Confirmation of the identity of the pyrolysates was obtained by using two types of MS3 experiments: the reaction intermediate scan and the two-dimensional familial scan. The ion chemistry of the trimers and of the protonated monomer, the alkylisocyanate, was elucidated. Among the many interesting fragmentation processes undergone by the ionized trimers were α and β CC bond cleavages and charge-remote fragmentations, which provided information on branching in the alkyl substituent. The dioxolane-containing substituent showed unique ion chemistry. The monomer distribution in the copolymers was deduced from the abundances of the various protonated trimers. The distribution was found to be random in all copolymers except that containing the dioxolane substituent

Effects on performance, carcass and meat quality of replacing maize silage and concentrate by grass silage and corn-cob mix in the diet of growing bulls

Grass silage is barely used in intensive beef production, but it is unclear if its lower energy supply compared to maize-silage feeding really impairs growth performance. Diets with 100, 300, 500 or 750 g grass silage/kg dry matter replacing maize silage and concentrate were tested with or without dried corn-cob mix (CCM). Performance, carcass and meat quality were studied in 30 Limousin-sired bulls. Feeding grass silage, CCM, and concentrate in a ratio of 500:300:200 allowed to maintain a similar animal performance, carcass and meat quality compared to a conventional maize silage/concentrate diet. Increasing the dietary grass silage proportion to 750 g/kg decreased the shear force of the meat. The proportion of n–3 fatty acids in intramuscular fat increased with dietary grass silage proportion. Consequently, a strategic combination of grass silage with energyrich forages may facilitate grassland-based feeding strategies in intensive beef production with favourable meat fatty acid profiles and a performance comparable to that with maize-silage based diets

Text Messaging for Disease Monitoring in Childhood Nephrotic Syndrome

© 2019 International Society of Nephrology Introduction: There is limited information on effective disease monitoring for prompt interventions in childhood nephrotic syndrome. We examined the feasibility and effectiveness of a novel text messaging system (SMS) for disease monitoring in a multicenter, prospective study. Methods: A total of 127 patients results, symptoms, and medication adherence were sent to a designated caregiver (n = 116) or adolescent patient (n = 3). Participants responded by texting. Feasibility of SMS was assessed by SMS adoption, retention, and engagement, and concordance between participant-reported results and laboratory/clinician assessments. The number of disease relapses and time-to-remission data captured by SMS were compared with data collected by conventional visits. Results: A total of 119 of 127 (94%) patients agreed to SMS monitoring. Retention rate was 94%, with a median follow-up of 360 days (interquartile range [IQR] 353–362). Overall engagement was high, with a median response rate of 87% (IQR, 68–97). Concordance between SMS-captured home urine protein results and edema status with same-day in-person study visit was excellent (kappa values 0.88 and 0.92, respectively). SMS detected a total of 108 relapse events compared with 41 events captured by scheduled visits. Median time to remission after enrollment was 22 days as captured by SMS versus 50 days as captured by scheduled visits. Conclusion: SMS was well accepted by caregivers and adolescent patients and reliably captured nephrotic syndrome disease activity between clinic visits. Additional studies are needed to explore the impact of SMS on disease outcomes