Dielectric properties of epoxy nanocomposites containing TiO2, Al2O3 and ZnO fillers

The paper presents results of dielectric spectroscopy and space charge (PEA) measurements on epoxy resin filled with 10% w/w micro- and nano- sized particles of TiO2, Al3O2 and ZnO. The results appear to show that the material from which the nano-particle is made is not highly significant in influencing these results. The results support the proposition that the dielectric properties of such nano-filled composites are controlled by Stern-Gouy-Chapman layers (“interaction zones”) around the particles

Improving the Dielectric Properties of Polymers by Incorporating Nano-particles.

The paper presents a brief review of the promise of nanotechnology applied to polymeric insulation materials and discusses the electrical properties found. For a variety of nanocomposites, the dielectric behaviour has shown that the interface between the embedded particles and host matrix holds the key to the understanding of the bulk phenomena being observed. Dielectric spectroscopy verified the motion of carriers through the interaction zones that surround the particles. The obvious improvements in endurance and breakdown strength of nanocomposites may be due to a reduction of charge accumulation. PEA space charge tests confirm this charge dissipation. By examining the onset field of space charge accumulation, it may be possible to determine whether a system is likely to be useful

Dust obscuration studies along quasar sight lines using simulated galaxies

We use the results of a set of three-dimensional SPH-Treecode simulations which model the formation and early evolution of disk galaxies, including the generation of heavy elements by star formation, to investigate the effects of dust absorption in quasar absorption line systems. Using a simple prescription for the production of dust, we have compared the column density, zinc abundance and optical depth properties of our models to the known properties of Damped Lyman alpha systems. We find that a significant fraction of our model galaxy disks have a higher column density than any observed DLA system. We are also able to show that such parts of the disk tend to be optically thick, implying that any background quasar would be obscured through much of the disk. This would produce the selection effect against the denser absorption systems thought to be present in observations.Comment: 7 pages, 8 figures, to be published in MNRA

Competition and cooperation in one-dimensional stepping stone models

Cooperative mutualism is a major force driving evolution and sustaining ecosystems. Although the importance of spatial degrees of freedom and number fluctuations is well-known, their effects on mutualism are not fully understood. With range expansions of microbes in mind, we show that, even when mutualism confers a distinct selective advantage, it persists only in populations with high density and frequent migrations. When these parameters are reduced, mutualism is generically lost via a directed percolation process, with a phase diagram strongly influenced by an exceptional DP2 transition.Comment: 8 pages, 4 figure

Extracting Spooky-activation-at-a-distance from Considerations of Entanglement

Following an early claim by Nelson & McEvoy \cite{Nelson:McEvoy:2007} suggesting that word associations can display `spooky action at a distance behaviour', a serious investigation of the potentially quantum nature of such associations is currently underway. This paper presents a simple quantum model of a word association system. It is shown that a quantum model of word entanglement can recover aspects of both the Spreading Activation equation and the Spooky-activation-at-a-distance equation, both of which are used to model the activation level of words in human memory.Comment: 13 pages, 2 figures; To appear in Proceedings of the Third Quantum Interaction Symposium, Lecture Notes in Artificial Intelligence, vol 5494, Springer, 200

Primary and secondary dissociation pathways in the ultraviolet photolysis of Cl_2O

The photodissociation of dichlorine monoxide (Cl_2O) at 308, 248, and 193 nm was studied by photofragment translational energy spectroscopy. The primary channel upon excitation at 308 and 248 nm was Cl–O bond fission with production of ClO+Cl. A fraction of the ClO photoproducts also underwent spontaneous secondary dissociation at 248 nm. The center-of-mass translational energy distribution for the ClO+Cl channel at 248 nm appeared to be bimodal with a high energy component that was similar in shape to the 308 nm distribution and a second, low energy component with a maximum close to the threshold for the 2Cl+O(3P) channel. Observation of a bimodal distribution suggests that two pathways with different dissociation dynamics lead to ClO+Cl products. The high product internal energy of the second component raises the possibility that ClO is formed in a previously unobserved spin-excited state a 4∑−. Following excitation at 193 nm, a concerted dissociation pathway leading to Cl_2+O was observed in addition to primary Cl–O bond breakage. In both processes, most of the diatomic photofragments were formed with sufficient internal energy that they spontaneously dissociated. The time-of-flight distributions of the Cl_2+O products suggest that these fragments are formed in two different channels Cl_2(3II)+O(3P) and Cl_2(X1∑)+O(1D)

The influence of physical and chemical linkage on the properties of nanocomposites

It has been shown by several groups that the mechanical and electrical behavior of composites changes quite substantially, and often beneficially, when the filler particle size is less than 100 nm in diameter. There is also good reason to believe that the interface between the embedded particulates and the polymer matrix holds the key to understanding the bulk phenomena observed. Materials based on an SiO2-polyolefin system have been formulated with functionalized particulates so as to affect the physical and chemical linkages. The agents used to achieve this include amino-silane, hexamethyl-disilazane and triethoxyvinylsilane. The emerging picture of the interface is supported by detailed dielectric spectroscopy and internal space charge assessment. The nature of the internal structure has been related to the bulk properties observed such as the breakdown strength, voltage endurance, and the measurement of internal charges resulting from interfacial polarization

The Benefits of Peer Review and a Multisemester Capstone Writing Series on Inquiry and Analysis Skills in an Undergraduate Thesis.

This study examines the relationship between the introduction of a four-course writing-intensive capstone series and improvement in inquiry and analysis skills of biology senior undergraduates. To measure the impact of the multicourse write-to-learn and peer-review pedagogy on student performance, we used a modified Valid Assessment of Learning in Undergraduate Education rubric for Inquiry and Analysis and Written Communication to score senior research theses from 2006 to 2008 (pretreatment) and 2009 to 2013 (intervention). A Fisher-Freeman-Halton test and a two-sample Student's t test were used to evaluate individual rubric dimensions and composite rubric scores, respectively, and a randomized complete block design analysis of variance was carried out on composite scores to examine the impact of the intervention across ethnicity, legacy (e.g., first-generation status), and research laboratory. The results show an increase in student performance in rubric scoring categories most closely associated with science literacy and critical-thinking skills, in addition to gains in students' writing abilities