CONSTRUCTION OF A LOW COST AIR SAMPLER AND IT'S APPLICATION IN SAMPLING VOLATILE CARBONYL COMPOUNDS

lntcrcxt is expanding in measuring. concentrations of volatile organic compounds inbuildings since it is rccogniscd that many peoples' exposure to these compounds occur inthe indoor environment. However. such data are not available in Sri Lanka primarily dueto lack 01"proper equipment for quantitation and their high maintenance cost. This paperdcxcribcx the construction of a low cost air sampler (Rs. 40()/=) using commonly availablematerials.The air sampler contains a muffler fan to pull .unhient air though a filrcrts) and/or a bed ofsorhcnt material. which are housed in a variable length pye tube. Battery poweredmuffler fan and lightweight are two of the convenient features of this air sampler thatminimisc operational and transportation difficulties to the user.Vularilc carbonyl compounds such as formaldehyde acetaldehyde and acetone arecommonly found in indoors ambient air due to the combustion sources and emissions fromsvnthcric household products. Since formaldehyde is a known carcinogen andacetaldehyde is a suspected carcinogen compound. they were selected as the modelcompounds for the evaluation of constructed sampler. A filter paper spiked with 2. 4-dinitrophcnylhydruzcnc is used to collect the airborne carbonyl compounds at a flow rate ofI.X Cill'/SCC. Filters were sonicated in methanol and extracts were separated using a C,xcolumn for qu.uuitation at lSO mm wavelength. Quanutaiion limits estimates thats.unpling of I () dm ' ambient air enables minimum quantitauon of O.S formaldehyde. 1.0acetaldehyde and 1.2 acetone accurately. The paper also reports quantified levels ofairborne carbonyls from different indoor environments.

INVESTIGATION OF SULFUR COMPOUNDS IN SELECTED STAGNANT WATER BODIES

Sulfur compounds, primarily in the form of sulfides (S2.), sulfites (50)'") andsulfates (50t) have been neglected but has a strong effect upon water quality.The dark colour sediments and strong unpleasant ordours often indicate the 52.contamination in aquatic bodies. To the best of our knowledge, no attempt hasbeen made to investigate these compounds and to asses their contribution to thedegradation of water quality. Both the bacteria and dissolved oxygen (DO) areplaying leading roles in determining the fate of 5 containing compounds inaquatic systems.In this investigation it was intended to study the possible relationships betweensulfur species and DO. Four urban stagnant water bodies effected by impropersewage disposal, industrial waste, wet and dry deposition of atmospheric 50/'were investigated along with a prawn farm and two coconut husk soaking pitsinherited with S compounds. These water bodies indicated the emission ofvolatile 5 compounds. These water bodies indicated the emission of volatile 5compounds From their characteristic rotten egg smell.Under this study 52., SO)·2 and 50t levels were monitored along with DO, pHand temperature to investigate the possible correlation method introduced byPawlak and Pawlak (1999) was employed in determination of 52. levels while allother parameters were measured by employing standard methods.Based on the results obtained, only S2. shows a significant correlation with DOunder ambient conditions. Finally, measured dissolved 52. levels were utilized todetermine the possible H25 emission levels. Calculations have shown that each ofthe water body is emitting gaseous H25 and in most cases, emission levels aregreater than the ordour thresholds accounting for the unpleasant smell near thesestagnant water bodies.*Correspondence author

Contribution of dissolved sulfates and sulfites in hydrogen sulfide emission from stagnant water bodies in Sri Lanka

Abstract Accumulation of sulfur-containing compounds and their bacterial mediated reductions have led to the emission of pungent odors from stagnant water bodies. This study is focused on the contribution of inorganic sulfur compounds in the emission of hydrogen sulfide. The measured dissolved oxygen levels have demonstrated good negative correlations with the dissolved sulfide levels implying the oxygen deficiency is the key for the reduction of sulfate ion and sulfite ion to sulfide ion. Particularly, the dissolved molar fractions of sulfide from the total dissolved sulfur compounds (sulfates, sulfites and sulfides) have a very good correlation with the dissolved oxygen for the stagnant water bodies except the artificially aerated prawn farms. For the stagnant water bodies with significant correlations, linear regressions are reported for them to be utilized in estimating one component of the regression from the measurement of the other. The measured data were further utilized to estimate the levels of hydrogen sulfide gas. The pH of the water bodies has confined much of the dissolved sulfides in the form of bisulfide ion and they can be easily escaped to the atmosphere upon acidification due to industrial discharges and/or acidic precipitations. The estimated levels of hydrogen sulfide just above the water surface were plotted for the most polluted stagnant water body in Sri Lanka for the pH range of 5-10 and temperature range of 25-35°C

Chikungunya as a cause of acute febrile illness in southern Sri Lanka

10.1371/journal.pone.0082259PLoS ONE812-POLN