Molybdenum Disulfide Catalytic Coatings via Atomic Layer Deposition for Solar Hydrogen Production from Copper Gallium Diselenide Photocathodes

We demonstrate that applying atomic layer deposition-derived molybdenum disulfide (MoS2) catalytic coatings on copper gallium diselenide (CGSe) thin film absorbers can lead to efficient wide band gap photocathodes for photoelectrochemical hydrogen production. We have prepared a device that is free of precious metals, employing a CGSe absorber and a cadmium sulfide (CdS) buffer layer, a titanium dioxide (TiO2) interfacial layer, and a MoS2 catalytic layer. The resulting MoS2/TiO2/CdS/CGSe photocathode exhibits a photocurrent onset of +0.53 V vs RHE and a saturation photocurrent density of -10 mA cm-2, with stable operation for >5 h in acidic electrolyte. Spectroscopic investigations of this device architecture indicate that overlayer degradation occurs inhomogeneously, ultimately exposing the underlying CGSe absorber

Quark Distributions in a Medium

We derive the formal expressions needed to discuss the change of the twist-two parton distribution functions when a hadron is placed in a medium with relativistic scalar and vector mean fieldsComment: 6 page

Overcoming stability problems in microwave-assisted heterogeneous catalytic processes affected by catalyst coking

Microwave-assisted heterogeneous catalysis (MHC) is gaining attention due to its exciting prospects related to selective catalyst heating, enhanced energy-efficiency, and partial inhibition of detrimental side gas-phase reactions. The induced temperature difference between the catalyst and the comparatively colder surrounding reactive atmosphere is pointed as the main factor of the process selectivity enhancement towards the products of interest in a number of hydrocarbon conversion processes. However, MHC is traditionally restricted to catalytic reactions in the absence of catalyst coking. As excellent MW-susceptors, carbon deposits represent an enormous drawback of the MHC technology, being main responsible of long-term process malfunctions. This work addresses the potentials and limitations of MHC for such processes affected by coking (MHCC). It also intends to evaluate the use of different catalyst and reactor configurations to overcome heating stability problems derived from the undesired coke deposits. The concept of long-term MHCC operation has been experimentally tested/applied to for the methane non-oxidative coupling reaction at 700¿C on Mo/ZSM-5@SiC structured catalysts. Preliminary process scalability tests suggest that a 6-fold power input increases the processing of methane flow by 150 times under the same controlled temperature and spatial velocity conditions. This finding paves the way for the implementation of high-capacity MHCC processes at up-scaled facilities

Baryons in O(4) and Vibron Model

The structure of the reported excitation spectra of the light unflavored baryons is described in terms of multi-spin valued Lorentz group representations of the so called Rarita-Schwinger (RS) type (K/2, K/2)* [(1/ 2,0)+ (0,1/2)] with K=1,3, and 5. We first motivate legitimacy of such pattern as fundamental fields as they emerge in the decomposition of triple fermion constructs into Lorentz representations. We then study the baryon realization of RS fields as composite systems by means of the quark version of the U(4) symmetric diatomic rovibron model. In using the U(4)/ O(4)/ O(3)/ O(2) reduction chain, we are able to reproduce quantum numbers and mass splittings of the above resonance assemblies. We present the essentials of the four dimensional angular momentum algebra and construct electromagnetic tensor operators. The predictive power of the model is illustrated by ratios of reduced probabilities concerning electric de-excitations of various resonances to the nucleon.Comment: Phys. Rev. D (in press, 2001

Nucleons or diquarks? Competition between clustering and color superconductivity in quark matter

We study the instabilities of quark matter in the framework of a generalized Nambu--Jona-Lasinio model, in order to explore possible competition between three-quark clustering to form nucleons and diquark formation leading to color superconductivity. Nucleon and $\Delta$ solutions are obtained for the relativistic Faddeev equation at finite density and their binding energies are compared with those for the scalar and axial-vector diquarks found from the Bethe-Salpeter equation. In a model with interactions in both scalar and axial diquark channels, bound nucleons exist up to nuclear matter density. However, except at densities below about a quarter of that of nuclear matter, we find that scalar diquark formation is energetically favored. This raises the question of whether a realistic phase diagram of baryonic matter can be obtained from any model which does not incorporate color confinement.Comment: 23 pages (RevTeX), 5 figures (epsf

Non-perturbative Propagators, Running Coupling and Dynamical Quark Mass of Landau gauge QCD

The coupled system of renormalized Dyson-Schwinger equations for the quark, gluon and ghost propagators of Landau gauge QCD is solved within truncation schemes. These employ bare as well as non-perturbative ansaetze for the vertices such that the running coupling as well as the quark mass function are independent of the renormalization point. The one-loop anomalous dimensions of all propagators are reproduced. Dynamical chiral symmetry breaking is found, the dynamically generated quark mass agrees well with phenomenological values and corresponding results from lattice calculations. The effects of unquenching the system are small. In particular the infrared behavior of the ghost and gluon dressing functions found in previous studies is almost unchanged as long as the number of light flavors is smaller than four.Comment: 34 pages, 10 figures, version to be published by Phys. Rev.

Mesons in a Poincare Covariant Bethe-Salpeter Approach

We develop a covariant approach to describe the low-lying scalar, pseudoscalar, vector and axialvector mesons as quark-antiquark bound states. This approach is based on an effective interaction modeling of the non--perturbative structure of the gluon propagator that enters the quark Schwinger-Dyson and meson Bethe-Salpeter equations. We consistently treat these integral equations by precisely implementing the quark propagator functions that solve the Schwinger-Dyson equations into the Bethe-Salpeter equations in the relevant kinematical region. We extract the meson masses and compute the pion and kaon decay constants. We obtain a quantitatively correct description for pions, kaons and vector mesons while the calculated spectra of scalar and axialvector mesons suggest that their structure is more complex than being quark-antiquark bound states.Comment: 18 pages LaTeX, 5 figures; some changes in the presentation, new results on axial vector mesons in enlarged mixing scheme; version to be published in Physical Review

Production Processes as a Tool to Study Parameterizations of Quark Confinement

We introduce diquarks as separable correlations in the two-quark Green's function to facilitate the description of baryons as relativistic three-quark bound states. These states then emerge as solutions of Bethe-Salpeter equations for quarks and diquarks that interact via quark exchange. When solving these equations we consider various dressing functions for the free quark and diquark propagators that prohibit the existence of corresponding asymptotic states and thus effectively parameterize confinement. We study the implications of qualitatively different dressing functions on the model predictions for the masses of the octet baryons as well as the electromagnetic and strong form factors of the nucleon. For different dressing functions we in particular compare the predictions for kaon photoproduction, $\gamma p\to K\Lambda$, and associated strangeness production, $pp\to pK\Lambda$ with experimental data. This leads to conclusions on the permissibility of different dressing functions.Comment: 43 pages, Latex, 28 eps files included via epsfig; version to be published in Physical Review

Bethe-Salpeter equation and a nonperturbative quark-gluon vertex

A Ward-Takahashi identity preserving Bethe-Salpeter kernel can always be calculated explicitly from a dressed-quark-gluon vertex whose diagrammatic content is enumerable. We illustrate that fact using a vertex obtained via the complete resummation of dressed-gluon ladders. While this vertex is planar, the vertex-consistent kernel is nonplanar and that is true for any dressed vertex. In an exemplifying model the rainbow-ladder truncation of the gap and Bethe-Salpeter equations yields many results; e.g., pi- and rho-meson masses, that are changed little by including higher-order corrections. Repulsion generated by nonplanar diagrams in the vertex-consistent Bethe-Salpeter kernel for quark-quark scattering is sufficient to guarantee that diquark bound states do not exist.Comment: 16 pages, 12 figures, REVTEX