Classification and characterisation of magmatic-hydrothermal tourmaline by combining field observations and microanalytical techniques

Tourmaline from the St. Byron lobe of the Land’s End granite, SW England, was assessed by macroscopic, optical and quantitative microanalytical methods. In total, seven types of tourmaline were distinguished. The seven types reflect different crystallisation environments and stages in the magmatic-hydrothermal transition. Types 1-3 are interpreted to represent a gradual transition from tourmaline crystallising from a silicate melt to precipitation from magmatic aqueous fluids. Types 5-7 crystallised at subsolidus conditions from a different fluid generation than types 1-3. These fluids may be magmatic or mixed with other fluids (e.g., meteoric or formation waters). The Sn-mineralisation in the area is mostly related to the latter fluid generation, and the mineralising potential is reflected by the tourmaline composition.This is an open access article, available to all readers online, published under a creative commons licensing Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Published under licence by IOP Publishing Lt

Fractionation of Li, Be, Ga, Nb, Ta, In, Sn, Sb, W and Bi in the peraluminous Early Permian Variscan granites of the Cornubian Batholith: precursor processes to magmatic-hydrothermal mineralisation

The Early Permian Variscan Cornubian Batholith is a peraluminous, composite pluton intruded into Devonian and Carboniferous metamorphosed sedimentary and volcanic rocks. Within the batholith there are: G1 (two-mica), G2 (muscovite), G3 (biotite), G4 (tourmaline) and G5 (topaz) granites. G1-G2 and G3-G4 are derived from greywacke sources and linked through fractionation of assemblages dominated by feldspars and biotite, with minor mantle involvement in G3. G5 formed though flux-induced biotite-dominate melting in the lower crust during granulite facies metamorphism. Fractionation enriched G2 granites in Li (average 315 ppm), Be (12 ppm), Ta (4.4 ppm), In (74 ppb), Sn (18 ppm) and W (12 ppm) relative to crustal abundances and G1 granites. Gallium (24 ppm), Nb (16 ppm) and Bi (0.46 ppm) are not significantly enriched during fractionation, implying they are more compatible in the fractionating assemblage. Sb (0.16 ppm) is depleted in G1-G2 relative to the average upper and lower continental crust. Muscovite, a late-stage magmatic/subsolidus mineral, is the major host of Li, Nb, In, Sn and W in G2 granites. G2 granites are spatially associated with W-Sn greisen mineralisation. Fractionation within the younger G3-G4 granite system enriched Li (average 364 ppm), Ga (28 ppm), In (80 ppb), Sn (14 ppm), Nb (27 ppm), Ta (4.6 ppm), W (6.3 ppm) and Bi (0.61 ppm) in the G4 granites with retention of Be in G3 granites due to partitioning of Be into cordierite during fractionation. The distribution of Nb and Ta is controlled by accessory phases such as rutile within the G4 granites, facilitated by high F and lowering the melt temperature, leading to disseminated Nb and Ta mineralisation. Lithium, In, Sn and W are hosted in biotite micas which may prove favourable for breakdown on ingress of hydrothermal fluids. Higher degrees of scattering on trace element plots may be attributable to fluid–rock interactions or variability within the magma chamber. The G3-G4 system is more boron-rich, evidenced by a higher modal abundance of tourmaline. In this system, there is a stronger increase of Sn compared to G1-G2 granites, implying Sn in tourmaline-dominated mineral lodes may represent exsolution from G4 granites. G1-G4 granite abundances can be accounted for by 20–30% partial melting and 10–40% fractionation of a greywacke source. G5 granites are analogues of Rare Metal Granites described in France and Germany. These granites are enriched in Li (average 1363 ppm), Ga (38 ppm), Sn (21 ppm), W (24 ppm), Nb (52 ppm) and Ta (15 ppm). Within G5 granites, the metals partition into accessory minerals such as rutile, columbite-tantalite and cassiterite, forming disseminated magmatic mineralisation. High observed concentrations of Li, In, Sn, W, Nb and Ta in G4 and G5 granites are likely facilitated by high F, Li and P, which lower melt temperature and promote retention of these elements in the melt, prior to crystallisation of disseminated magmatic mineralisation

Sedimentary facies and mineral provenance of Upper Triassic sandstones offshore Kvitøya, Svalbard: implications for palaeogeographic interpretations in the northern Barents Shelf area

Upper Triassic (Carnian) sandstones of the De Geerdalen Formation cored south of the island of Kvitøya (80°N), north-easternmost Svalbard, are described in terms of sedimentary facies and petrography and compared regionally in the northern Barents Shelf. The succession off Kvitøya is characterized by its great thickness and is dominated by deltaic deposits with high sand content of lithic–feldspathic compositions. Comparison of sediment facies and sandstone compositions with adjacent areas suggest that the succession off Kvitøya is part of a larger delta system with its main sediment source from the east. The delta sedimentation was terminated by marine transgression in the earliest Norian. The sandstone compositions off Kvitøya differ from nearby locations by the higher content of cherty rock fragments and reworked volcanic debris in the Kvitøya sandstone, which is most distinct in the lower part of the succession. Provenance signatures are investigated by mineral–chemical analysis of detrital feldspars, rock fragments, garnet and Cr-spinel, characterizing a wide variety of igneous, metamorphic and sedimentary terranes, including palaeo-Urals and areas farther to east. Additional, more proximal sediment source areas may also have existed that could explain the increased sediment thickness and the mineralogical immature sandstone compositions of the Carnian sediments off Kvitøya

From Fossil to Active Hydrothermal Outflow in the Back-Arc of the Central Apennines (Zannone Island, Italy)

Post-orogenic back-arc magmatism is accompanied by hydrothermal ore deposits and mineralizations derived from mantle and crustal sources. We investigate Zannone Island (ZI), back-arc Tyrrhenian basin, Italy, to define the source(s) of mineralizing hydrothermal fluids and their relationships with the regional petrological-tectonic setting. On ZI, early Miocene thrusting was overprinted by late Miocene post-orogenic extension and related hydrothermal alteration. Since active submarine hydrothermal outflow is reported close to the island, Zannone provides an ideal site to determine the P-T-X evolution of the long-lived hydrothermal system. We combined field work with microstructural analyses on syn-tectonic quartz veins and carbonate mineralizations, X-ray diffraction analysis, microthermometry and element mapping of fluid inclusions (FIs), C, O, and clumped isotopes, and analyses of noble gases (He-Ne-Ar) and CO2 content in FIs. Our results document the evolution of a fluid system of magmatic origin with increasing mixing of meteoric fluids. Magmatic fluids were responsible for quartz veins precipitation at similar to 125 to 150 MPa and similar to 300 degrees C-350 degrees C. With the onset of extensional faulting, magmatic fluids progressively interacted with carbonate rocks and mixed with meteoric fluids, leading to (a) host rock alteration with associated carbonate and minor ore mineral precipitation, (b) progressive fluid neutralization, (c) cooling of the hydrothermal system (from similar to 320 degrees C to similar to 86 degrees C), and (d) embrittlement and fracturing of the host rocks. Both quartz and carbonate mineralizations show noble gases values lower than those from the adjacent active volcanic areas and submarine hydrothermal systems, indicating that the fossil-to-active hydrothermal history is associated with the emplacement of multiple magmatic intrusions.ISSN:1525-202

From Fossil to Active Hydrothermal Outflow in the Back-Arc of the Central Apennines (Zannone Island, Italy)

Post-orogenic back-arc magmatism is accompanied by hydrothermal ore deposits and mineralizations derived from mantle and crustal sources. We investigate Zannone Island (ZI), back-arc Tyrrhenian basin, Italy, to define the source(s) of mineralizing hydrothermal fluids and their relationships with the regional petrological-tectonic setting. On ZI, early Miocene thrusting was overprinted by late Miocene post-orogenic extension and related hydrothermal alteration. Since active submarine hydrothermal outflow is reported close to the island, Zannone provides an ideal site to determine the P-T-X evolution of the long-lived hydrothermal system. We combined field work with microstructural analyses on syn-tectonic quartz veins and carbonate mineralizations, X-ray diffraction analysis, microthermometry and element mapping of fluid inclusions (FIs), C, O, and clumped isotopes, and analyses of noble gases (He-Ne-Ar) and CO2 content in FIs. Our results document the evolution of a fluid system of magmatic origin with increasing mixing of meteoric fluids. Magmatic fluids were responsible for quartz veins precipitation at similar to 125 to 150 MPa and similar to 300 degrees C-350 degrees C. With the onset of extensional faulting, magmatic fluids progressively interacted with carbonate rocks and mixed with meteoric fluids, leading to (a) host rock alteration with associated carbonate and minor ore mineral precipitation, (b) progressive fluid neutralization, (c) cooling of the hydrothermal system (from similar to 320 degrees C to similar to 86 degrees C), and (d) embrittlement and fracturing of the host rocks. Both quartz and carbonate mineralizations show noble gases values lower than those from the adjacent active volcanic areas and submarine hydrothermal systems, indicating that the fossil-to-active hydrothermal history is associated with the emplacement of multiple magmatic intrusions

Regional tectonic implications on the tectonic contact at Zannone Island, Italy

Zannone is a very important island, located in the Neogene-Quaternary extensional domain of the Tyrrhenian back-arc basin, as it is the unique spot where the Paleozoic (?) crystalline basement is hypotesized to be exposed in central Apennines. The exposure of such hypothetical basement in the Zannone Island is very problematic as it implies very large normal displacements (> 3 km) along surrounding faults. No such displacements are known along faults close to Zannone Island. In this work, we study the hypothetical Paleozoic crystalline basement exposed in the Zannone Island with the main aim of understanding its geological nature and relationships with the surrounding rocks. We use a multidisciplinary approach including 1) field survey; 2) petro-textural observations; 3) petrologic analyses of the host rocks; 4) microthermometry on fluid inclusions; 5) geochemical analyses of stable and clumped isotopes; 6) analyses of minor gaseous species (He, Ne, and Ar concentrations and isotope ratios) in fluid inclusions; 7) U-Pb geochronology of syn-tectonic calcite; 7) K-Ar dating of syn-kinematic clay minerals, and 8) X-ray diffraction (XRD) analysis of the clay size fraction. Our results show that the hypothetical Paleozoic (?) crystalline basement exposed on the Zannone Island is, instead, represented by siliciclastic rocks of very low metamorphic grade. This is testified by the presence of chloritoid and by the observed incipient foliation marked by fine-grained white micas and disposed parallel to the bedding. The contact between such siliciclastic rocks and the overlapping Triassic Dolostones is represented by a low-angle thrust cut by sets of high-angle normal faults with associated calcite mineralizations. K-Ar dating on clay minerals in fault gouge reveals a strong contamination of K- bearing minerals from the protolith. In detail, we obtained an age of ~22 Ma which reveals that at least one event of authigenesis (i.e. fluid-assisted tectonic activity) occurred in Zannone Island <22 Ma ago. U-Pb dating on sin-tectonic calcite mineralizations allowed to constrain the compressional deformation and subsequent normal faulting in the study area at around 7 Ma. This result is consistent with the 1) described emplacement of imbricate thrust sheets onshore close to Zannone Island and 2) syn-tectonic sediments-filling basins observed by seismic reflection studies. Petrographic observations on fluid inclusions in tectonic quartz and calcite mineralizations allowed to determine that such inclusions were entrapped at the same time and therefore at the same depth. Microthermometry on fluid inclusions allowed to constrain a wide range on P-T entrapment conditions. For this reason, we highlighted a transition from lithostatic toward hydrostatic pressure during precipitation of syn-tectonic quartz and calcite mineralizations. Microthermometry on fluid inclusions highlighted also the presence of two fluids during tectonic processes. One characterized by low salinity (as NaCl equivalent) and one by high salinity (as NaCl equivalent). Coupled stable isotopes analyses on the same calcite mineralizations, we highlighted a mixing between meteoric and deep fluids, as testified by the high spread of calculates values of δ18O and δ13C