418 research outputs found
Influence of Quantum Hall Effect on Linear and Nonlinear Conductivity in the FISDW States of the Organic Conductor (TMTSF)_2PF_6
We report a detailed characterization of quantum Hall effect (QHE) influence
on the linear and non-linear resistivity tensor in FISDW phases of the organic
conductor (TMTSF)2PF6. We show that the behavior at low electric fields,
observed for nominally pure single crystals with different values of the
resistivity ratio, is fully consistent with a theoretical model, which takes
QHE nature of FISDW and residual quasi-particle density associated with
different crystal imperfection levels into account. The non-linearity in
longitudinal and diagonal resistivity tensor components observed at large
electric fields reconciles preceding contradictory results. Our theoretical
model offers a qualitatively good explanation of the observed features if a
sliding of the density wave with the concomitant destruction of QHE, switched
on above a finite electric field, is taken into account.Comment: 8 pages, 6 figures, submitted to EPJ
Coexistence of Superconductivity and Spin Density Wave orderings in the organic superconductor (TMTSF)_2PF_6
The phase diagram of the organic superconductor (TMTSF)_2PF_6 has been
revisited using transport measurements with an improved control of the applied
pressure. We have found a 0.8 kbar wide pressure domain below the critical
point (9.43 kbar, 1.2 K) for the stabilisation of the superconducting ground
state featuring a coexistence regime between spin density wave (SDW) and
superconductivity (SC). The inhomogeneous character of the said pressure domain
is supported by the analysis of the resistivity between T_SDW and T_SC and the
superconducting critical current. The onset temperature T_SC is practically
constant (1.20+-0.01 K) in this region where only the SC/SDW domain proportion
below T_SC is increasing under pressure. An homogeneous superconducting state
is recovered above the critical pressure with T_SC falling at increasing
pressure. We propose a model comparing the free energy of a phase exhibiting a
segregation between SDW and SC domains and the free energy of homogeneous
phases which explains fairly well our experimental findings.Comment: 13 pages, 10 figures, revised v: fig.9 added, section 4.2 rewritten,
accepted v: sections 4&5 improve
Two Intranasal Administration Techniques Give Two Different Pharmacokinetic Results
Minor changes in the administration technique used for intranasal instillation of clonazepam, have been found to influence the results significantly. A simple study was performed, where rabbits received 0.5 mg clonazepam intranasally. One group received the drug while fixed in a sitting position, where the other group was fixed in a supine position. The results show that both techniques where able to provide a rapid absorption with a tmax around 3-4 min. The Cmax and AUC, however, were very different. The Cmax was found to be 40 ng/ml and 86 ng/ml, respectively, and the AUC was found to be 891 and 2249 (ng/ml/min), respectively, for the sitting and the supine position. The relative bioavailability for sitting/supine was found to be 38%. These results show that the administration technique is very important and should not be underestimated.
Anomalous In-Plane Anisotropy of the Onset of Superconductivity in (TMTSF)2ClO4
We report the magnetic field-amplitude and field-angle dependence of the
superconducting onset temperature Tc_onset of the organic superconductor
(TMTSF)2ClO4 in magnetic fields H accurately aligned to the conductive ab'
plane. We revealed that the rapid increase of the onset fields at low
temperatures occurs both for H // b' and H // a, irrespective of the carrier
confinement. Moreover, in the vicinity of the Pauli limiting field, we report a
shift of a principal axis of the in-plane field-angle dependence of Tc_onset
away from the b' axis. This feature may be related to an occurrence of
Fulde-Ferrell-Larkin-Ovchinnikov phases.Comment: 4 pages, 4 figure
Self-organization of charge under pressure in the organic conductor (TMTSF)2ReO4
(TMTSF)2ReO4 presents a phase coexistence between two anion orderings defined
by their wave vectors q_2=(1/2,1/2,1/2) and q_3=(0,1/2,1/2) in a wide range of
pressure (8-11kbar) and temperature. From the determination of the anisotropy
of the conductivity and the superconducting transitions in this regime we were
able to extract the texture which results from a self-organization of the
orientations of the ReO4 anions in the sample. At the lowest pressures, the
metallic parts, related to the q_3 order, form droplets elongated along the
a-axis embedded in the semiconducting matrix associated with the q_2 order.
Above 10kbar, filaments along the a-axis extend from one end of the sample to
the other nearly up to the end of the coexistence regime. A mapping of the
system into an anisotropic Ising lattice is satisfactory to analyze the data.
satisfactory to analyze the data.Comment: 7 pages, 3 figures, EPL forma
Kinetics of glucose oxidase catalyzed electron transfer mediated by sulfur and selenium compounds
AbstractUnusually high electron transfer rates in Aspergillus niger glucose oxidase catalyzed oxidation of glucose using 5,6:11,12-Bis(dithio)tetracene (TTT), 1,2-dimethyltetraselenafulvalene (DMTSF) and tetrathiafulvalene (TTF) were observed. At pH 7.0 oxidation rate constants (TN/Km) in the range from 1.0 · 107 to 8.7 · 107 M · s−1 were deduced from experimental data. One of the investigated mediators, DMTSF, has been used for electrocatalytical glucose oxidation on graphite at a potential of 0.3 V vs. a standard calomel electrode (SCE). The prepared bioelectrodes have a sensitivity of 1.3 μA/(cm2 · mM), a pH optimum at 6.5-7.0, and a linear range which covers the relevant range for monitoring physiological levels of glucose. The bioelectrodes are stable for more than one month
Temperature-Modulated Differential Scanning Calorimetry Analysis of High-Temperature Silicate Glasses
Differential scanning calorimetry (DSC) is one of the most versatile probes
for silicate glasses, allowing determination of, e.g., transition temperatures
(glass, crystallization, melting) and the temperature dependence of heat
capacity. However, complications arise for glasses featuring overlapping
transitions and low sensitivity, e.g., arising from SiO2-rich compositions with
small change in heat capacity during glass transition or the low sensitivity of
thermocouples at high temperature. These challenges might be overcome using
temperature-modulated DSC (TM-DSC), which enables separation of overlapping
signals and improved sensitivity at the expense of increased measurement
duration
Upper critical field divergence induced by mesoscopic phase separation in the organic superconductor (TMTSF)2ReO4
Due to the competition of two anion orders, (TMTSF)2ReO4, presents a phase
coexistence between semiconducting and metallic (superconducting) regions
(filaments or droplets) in a wide range of pressure. In this regime, the
superconducting upper critical field for H parallel to both c* and b' axes
present a linear part at low fields followed by a divergence above a cross-over
field. This cross-over corresponds to the 3D-2D decoupling transition expected
in filamentary or granular superconductors. The sharpness of the transition
also demonstrates that all filaments are of similar sizes and self organize in
a very ordered way. The distance between the filaments and their cross-section
are estimated.Comment: 4 pages, 4 figure
- …