Bioenergy

In contrast to fossil fuels, the use of biofuels for thermal applications and power generation provides significant environmental advantages. Since Bio-Oil is extracted from organic wastes, it is a CO2 Neutral technique and can generate CO2 credits. In the present scenario energy sectors and individual entrepreneurs can opt a new way of power generation using the most abundantly available renewable source of energy in the form of Biomass wastes. Rice husks, groundnut shells, powdery husks, sugar cane (baggasse), corn cobs are some of the carbonaceous biomass fuels. Among the Biomass resources Coconuts are the abundant renewable resource of Energy available all around the world. Literature review showed that limited research studies had been carried out on yielding the product from coconut shell pyrolysis. The objective of present work is to envisage the methodology of generating power from biomass wastes using pyrolysis techniques. Pyrolysis is a thermal decomposition technique which decomposes carbonaceous biowastes into liquids, gases, and char (solid residue) in the absence of oxygen. Bio-Oil can be used as a fuel in diesel engine with modifications in fuel pump, linings, and the injection system. High carbonaceous Bio-Oil extracted from pyrolysis of coconut shell can be used in oil burners for thermal applications and in combustion boilers to generate electricity. Also can be blended with standard diesel fuels to form a pollution free green bio-diesel fuel. Hence biofuels based power generation system would be a boon to the energy crisis in an environmental friendly way using coconut shells for rural electrification

Dependence of X-Ray Burst Models on Nuclear Reaction Rates

X-ray bursts are thermonuclear flashes on the surface of accreting neutron stars and reliable burst models are needed to interpret observations in terms of properties of the neutron star and the binary system. We investigate the dependence of X-ray burst models on uncertainties in (p,$\gamma$), ($\alpha$,$\gamma$), and ($\alpha$,p) nuclear reaction rates using fully self-consistent burst models that account for the feedbacks between changes in nuclear energy generation and changes in astrophysical conditions. A two-step approach first identified sensitive nuclear reaction rates in a single-zone model with ignition conditions chosen to match calculations with a state-of-the-art 1D multi-zone model based on the {\Kepler} stellar evolution code. All relevant reaction rates on neutron deficient isotopes up to mass 106 were individually varied by a factor of 100 up and down. Calculations of the 84 highest impact reaction rate changes were then repeated in the 1D multi-zone model. We find a number of uncertain reaction rates that affect predictions of light curves and burst ashes significantly. The results provide insights into the nuclear processes that shape X-ray burst observables and guidance for future nuclear physics work to reduce nuclear uncertainties in X-ray burst models.Comment: 24 pages, 13 figures, 4 tables, submitte

Paleoecology and paleoceanography of the Athel silicilyte, Ediacaran-Cambrian boundary, Sultanate of Oman

The Athel silicilyte is an enigmatic, hundreds of meters thick, finely laminated quartz deposit, in which silica precipitated in deep water (>~100–200 m) at the Ediacaran–Cambrian boundary in the South Oman Salt Basin. In contrast, Meso-Neoproterozoic sinks for marine silica were dominantly restricted to peritidal settings. The silicilyte is known to contain sterane biomarkers for demosponges, which today are benthic, obligately aerobic organisms. However, the basin has previously been described as permanently sulfidic and time-equivalent shallow-water carbonate platform and evaporitic facies lack silica. The Athel silicilyte thus represents a unique and poorly understood depositional system with implications for late Ediacaran marine chemistry and paleoecology. To address these issues, we made petrographic observations, analyzed biomarkers in the solvent-extractable bitumen, and measured whole-rock iron speciation and oxygen and silicon isotopes. These data indicate that the silicilyte is a distinct rock type both in its sedimentology and geochemistry and in the original biology present as compared to other facies from the same time period in Oman. The depositional environment of the silicilyte, as compared to the bounding shales, appears to have been more reducing at depth in sediments and possibly bottom waters with a significantly different biological community contributing to the preserved biomarkers. We propose a conceptual model for this system in which deeper, nutrient-rich waters mixed with surface seawater via episodic mixing, which stimulated primary production. The silica nucleated on this organic matter and then sank to the seafloor, forming the silicilyte in a sediment-starved system. We propose that the silicilyte may represent a type of environment that existed elsewhere during the Neoproterozoic. These environments may have represented an important locus for silica removal from the oceans

Adiabatic Formation of Rydberg Crystals with Chirped Laser Pulses

Ultracold atomic gases have been used extensively in recent years to realize textbook examples of condensed matter phenomena. Recently, phase transitions to ordered structures have been predicted for gases of highly excited, 'frozen' Rydberg atoms. Such Rydberg crystals are a model for dilute metallic solids with tunable lattice parameters, and provide access to a wide variety of fundamental phenomena. We investigate theoretically how such structures can be created in four distinct cold atomic systems, by using tailored laser-excitation in the presence of strong Rydberg-Rydberg interactions. We study in detail the experimental requirements and limitations for these systems, and characterize the basic properties of small crystalline Rydberg structures in one, two and three dimensions.Comment: 23 pages, 10 figures, MPIPKS-ITAMP Tandem Workshop, Cold Rydberg Gases and Ultracold Plasmas (CRYP10), Sept. 6-17, 201

Oak forest carbon and water simulations:Model intercomparisons and evaluations against independent data

Models represent our primary method for integration of small-scale, process-level phenomena into a comprehensive description of forest-stand or ecosystem function. They also represent a key method for testing hypotheses about the response of forest ecosystems to multiple changing environmental conditions. This paper describes the evaluation of 13 stand-level models varying in their spatial, mechanistic, and temporal complexity for their ability to capture intra- and interannual components of the water and carbon cycle for an upland, oak-dominated forest of eastern Tennessee. Comparisons between model simulations and observations were conducted for hourly, daily, and annual time steps. Data for the comparisons were obtained from a wide range of methods including: eddy covariance, sapflow, chamber-based soil respiration, biometric estimates of stand-level net primary production and growth, and soil water content by time or frequency domain reflectometry. Response surfaces of carbon and water flux as a function of environmental drivers, and a variety of goodness-of-fit statistics (bias, absolute bias, and model efficiency) were used to judge model performance. A single model did not consistently perform the best at all time steps or for all variables considered. Intermodel comparisons showed good agreement for water cycle fluxes, but considerable disagreement among models for predicted carbon fluxes. The mean of all model outputs, however, was nearly always the best fit to the observations. Not surprisingly, models missing key forest components or processes, such as roots or modeled soil water content, were unable to provide accurate predictions of ecosystem responses to short-term drought phenomenon. Nevertheless, an inability to correctly capture short-term physiological processes under drought was not necessarily an indicator of poor annual water and carbon budget simulations. This is possible because droughts in the subject ecosystem were of short duration and therefore had a small cumulative impact. Models using hourly time steps and detailed mechanistic processes, and having a realistic spatial representation of the forest ecosystem provided the best predictions of observed data. Predictive ability of all models deteriorated under drought conditions, suggesting that further work is needed to evaluate and improve ecosystem model performance under unusual conditions, such as drought, that are a common focus of environmental change discussions

Shape and structure of N=Z 64Ge; Electromagnetic transition rates from the application of the Recoil Distance Method to knock-out reaction

Transition rate measurements are reported for the first and the second 2+ states in N=Z 64Ge. The experimental results are in excellent agreement with large-scale Shell Model calculations applying the recently developed GXPF1A interactions. Theoretical analysis suggests that 64Ge is a collective gamma-soft anharmonic vibrator. The measurement was done using the Recoil Distance Method (RDM) and a unique combination of state-of-the-art instruments at the National Superconducting Cyclotron Laboratory (NSCL). States of interest were populated via an intermediate-energy single-neutron knock-out reaction. RDM studies of knock-out and fragmentation reaction products hold the promise of reaching far from stability and providing lifetime information for excited states in a wide range of nuclei

Production cross sections of neutron rich isotopes from a 82Se beam

Production cross sections for neutron-rich nuclei from the fragmentation of a 82Se beam at 139 MeV/u were measured. The longitudinal momentum distributions of 122 neutron-rich isotopes of elements $11 \le Z \le 32$ were determined by varying the target thickness. Production cross sections with beryllium and tungsten targets were determined for a large number of nuclei including several isotopes first observed in this work. These are the most neutron-rich nuclides of the elements $22 \le Z \le 25$ (64Ti, 67V, 69Cr, 72Mn). One event was registered consistent with 70Cr, and another one with 75Fe. A one-body Qg systematics is used to describe the production cross sections based on thermal evaporation from excited prefragments. The current results confirm those of our previous experiment with a 76Ge beam: enhanced production cross sections for neutron-rich fragments near Z=20.Comment: Talk given at the 11th International Conference on Nucleus-Nucleus Collisions (NN2012), San Antonio, Texas, USA, May 27-June 1, 2012. To appear in the NN2012 Proceedings in Journal of Physics: Conference Series (JPCS

TOF-Brho Mass Measurements of Very Exotic Nuclides for Astrophysical Calculations at the NSCL

Atomic masses play a crucial role in many nuclear astrophysics calculations. The lack of experimental values for relevant exotic nuclides triggered a rapid development of new mass measurement devices around the world. The Time-of-Flight (TOF) mass measurements offer a complementary technique to the most precise one, Penning trap measurements, the latter being limited by the rate and half-lives of the ions of interest. The NSCL facility provides a well-suited infrastructure for TOF mass measurements of very exotic nuclei. At this facility, we have recently implemented a TOF-Brho technique and performed mass measurements of neutron-rich nuclides in the Fe region, important for r-process calculations and for calculations of processes occurring in the crust of accreting neutron stars.Comment: 8 pages, 4 figures, submitted to Journal of Physics G, proceedings of Nuclear Physics in Astrophysics II

Beta-delayed proton emission in the 100Sn region

Beta-delayed proton emission from nuclides in the neighborhood of 100Sn was studied at the National Superconducting Cyclotron Laboratory. The nuclei were produced by fragmentation of a 120 MeV/nucleon 112Sn primary beam on a Be target. Beam purification was provided by the A1900 Fragment Separator and the Radio Frequency Fragment Separator. The fragments of interest were identified and their decay was studied with the NSCL Beta Counting System (BCS) in conjunction with the Segmented Germanium Array (SeGA). The nuclei 96Cd, 98Ing, 98Inm and 99In were identified as beta-delayed proton emitters, with branching ratios bp = 5.5(40)%, 5.5+3 -2%, 19(2)% and 0.9(4)%, respectively. The bp for 89Ru, 91,92Rh, 93Pd and 95Ag were deduced for the first time with bp = 3+1.9 -1.7%, 1.3(5)%, 1.9(1)%, 7.5(5)% and 2.5(3)%, respectively. The bp = 22(1)% for 101Sn was deduced with higher precision than previously reported. The impact of the newly measured bp values on the composition of the type-I X-ray burst ashes was studied.Comment: 15 pages, 14 Figures, 4 Table

Quasimonoenergetic electron acceleration in the self-modulated laser wakefield regime

Details on the generation of (multiple) quasimonoenergetic electron bunches in the self-modulated laser wakefield acceleration (SMLWFA) regime are presented. This type of laser-plasma interaction can result in pronounced longitudinal laser pulse fragmentation, dependent on plasma density and laser intensity. It is shown by experiments and particle-in-cell simulations that these laser pulse fragments can be powerful enough to trigger nonlinear plasma wave breaking, injection, and acceleration of electrons to quasimonoenergetic energies. With high plasma densities, self-modulation is promoted, and the advantages of SMLWFA such as especially high accelerating fields and short electron bunches (<5 fs) can be harvested. In addition, more than one quasimonoenergetic electron bunch can be created, with a temporal spacing between each bunch of only few tens of femtoseconds, again governed by plasma density