Peptide-directed crystal growth modification in the formation of ZnO

Biomolecule-mediated synthesis is fascinating in terms of the level of control and the intricate hierarchical structures of the materials that can be produced. In this study we compare the behavior of a phage display identified peptide, EAHVMHKVAPRP (EM-12) with that of a mutant peptide EAHVCHKVAPRP (EC-12), having additional complexation capability, on the formation of ZnO from solution. The synthesis conditions (Zn(CH3COO)2–NH3 hydrothermal method at 50 °C) were chosen to generate rod-shaped ZnO via layered basic zinc salts (LBZs) as intermediates. Both peptides affected the crystal formation process by moderating the amount of Zn2+ ions in solution (EC12 having a greater effect than EM12) but only EC12 was shown to interact with the solid phase(s) formed during the reaction. Depending on the peptide concentration used, EM-12 was shown to delay and/or suppress ZnO formation. In contrast, additions of EC-12, although leading to the retention of higher levels of Zn2+ ions in solution did not similarly delay the transformation of the intermediate phases to ZnO but were found to dramatically modify the morphology of ZnO crystallites with mushroom shaped crystals being formed. From the results of detailed materials characterization and changes in the morphology observed, the interactions between the peptide(s) and solution and solid state species present during the process of ZnO crystal formation in the presence of EM-12 and EC-12 are proposed

LG MS 052 Sage Hylton (-Lemons) Papers

Description: Sage Hylton-Lemons grew up in Portland, Maine. In high school, Hylton-Lemons found sanctuary as a gay teenager in the youthdriven group Outright, where his involvement progressed from attending weekly meetings to being a member of the Board, then President of the Board. As an Outright member and activist, Hylton-Lemons spoke at schools and events, became a peer-advisor, and helped other communities organize their own Outrights. He was instrumental in conceiving and organizing Outright\u27s first annual prom in 1998. He was profoundly influenced by Christian T. Chenard, a nurse practitioner for the City of Portland Public Health Positive Healthcare Program. The papers include a scrapbook, photographs from the 1998 Outright Prom, a letter from the Maine Assistant Attorney General, a transcript of Hylton-Lemons\u27 testimony at a Portland City Council hearing regarding funding for Outright, and a transcript of his eulogy at the 2007 memorial service for Dr. Chenard along with other materials from the service. Date Range: 1996-1998, 2007 Size of Collection: 0.25 Linear Feet 1 Box (0.25 Linear Feet

Are low-energy nuclear observables sensitive to high-energy phase shifts?

Conventional nucleon-nucleon potentials with strong short-range repulsion require contributions from high-momentum wave function components even for low-energy observables such as the deuteron binding energy. This can lead to the misconception that reproducing high-energy phase shifts is important for such observables. Interactions derived via the similarity renormalization group decouple high-energy and low-energy physics while preserving the phase shifts from the starting potential. They are used to show that high-momentum components (and high-energy phase shifts) can be set to zero when using low-momentum interactions, without losing information relevant for low-energy observables.Comment: 13 pages, 5 figures; reference and acknowledgment adde

The NMR of High Temperature Superconductors without Anti-Ferromagnetic Spin Fluctuations

A microscopic theory for the NMR anomalies of the planar Cu and O sites in superconducting La_1.85Sr_0.15CuO_4 is presented that quantitatively explains the observations without the need to invoke anit-ferromagnetic spin fluctuations on the planar Cu sites and its significant discrepancy with the observed incommensurate neutron spin fluctuations. The theory is derived from the recently published ab-initio band structure calculations that correct LDA computations tendency to overestimate the self-coulomb repulsion for the half-filled Cu d_x2-y2 orbital for these ionic systems. The new band structure leads to two bands at the Fermi level with holes in the Cu d_z2 and apical O p_z orbitals in addition to the standard Cu d_x2-y2 and planar O p_sigma orbitals. This band structure is part of a new theory for the cuprates that explains a broad range of experiments and is based upon the formation of Cooper pairs comprised of a k up spin electron from one band and a -k down spin electron from another band (Interband Pairing Model).Comment: In Press, Journal of Physical Chemistry. See also http://www.firstprinciples.com. Minor changes to references and figure readabilit

Optical fibre sensors for monitoring prestressed concrete structures in nuclear power plants

This thesis was previously held under moratorium from 20th November and 20th November 2015.Lifetime extensions of nuclear fission reactors in the UK are required to satisfy growing demands for electrical power. Many of these reactors are nearing the end of their original design life, so the continued structural integrity, particularly of the reactors' prestressed concrete pressure vessels and containments is of prime concern. Currently, a lift-off inspection of a 1 % random sample of prestressing tendons is performed at 18 month to 5 year intervals to ensure adequate prestress is present in these structures, but the extended life times are making higher resolution, more frequent and in-depth monitoring techniques more desirable. In this thesis, a method of instrumenting prestressing strands with optical fibre Bragg grating strain sensors is outlined. An all-metal encapsulation and bonding technique is developed to ensure sensor reliability under the radioactive and high-stress environments of fission reactors. This 'smart strand' is complemented by a specially developed interrogation scheme capable of continuously and automatically monitoring static and dynamic nanoscale changes in Bragg grating strain. High-resolution interrogation was achieved by extending an interferrometric demodulation technique into the static measurement regime. By modulating the strain sensitivity using a fast optical switch, strain signals could be recovered independently of noise sources using various signal processing algorithms. The application of this technology could augment the continued monitoring of concrete vessel integrity, reducing both the risks and costs associated with performing lift-off measurements in the current and next generation of nuclear reactors.Lifetime extensions of nuclear fission reactors in the UK are required to satisfy growing demands for electrical power. Many of these reactors are nearing the end of their original design life, so the continued structural integrity, particularly of the reactors' prestressed concrete pressure vessels and containments is of prime concern. Currently, a lift-off inspection of a 1 % random sample of prestressing tendons is performed at 18 month to 5 year intervals to ensure adequate prestress is present in these structures, but the extended life times are making higher resolution, more frequent and in-depth monitoring techniques more desirable. In this thesis, a method of instrumenting prestressing strands with optical fibre Bragg grating strain sensors is outlined. An all-metal encapsulation and bonding technique is developed to ensure sensor reliability under the radioactive and high-stress environments of fission reactors. This 'smart strand' is complemented by a specially developed interrogation scheme capable of continuously and automatically monitoring static and dynamic nanoscale changes in Bragg grating strain. High-resolution interrogation was achieved by extending an interferrometric demodulation technique into the static measurement regime. By modulating the strain sensitivity using a fast optical switch, strain signals could be recovered independently of noise sources using various signal processing algorithms. The application of this technology could augment the continued monitoring of concrete vessel integrity, reducing both the risks and costs associated with performing lift-off measurements in the current and next generation of nuclear reactors

Theoretical studies of a hydrogen abstraction tool for nanotechnology

In the design of a nanoscale, site-specific hydrogen abstraction tool, the authors suggest the use of an alkynyl radical tip. Using ab initio quantum-chemistry techniques including electron correlation they model the abstraction of hydrogen from dihydrogen, methane, acetylene, benzene and isobutane by the acetylene radical. By conservative estimates, the abstraction barrier is small (less than 7.7 kcal mol^-1) in all cases except for acetylene and zero in the case of isobutane. Thermal vibrations at room temperature should be sufficient to supply the small activation energy. Several methods of creating the radical in a controlled vacuum setting should be feasible. The authors show how nanofabrication processes can be accurately and inexpensively designed in a computational framework

Initial bound state studies in light-front QCD

We present the first numerical QCD bound state calculation based on a renormalization group-improved light-front Hamiltonian formalism. The QCD Hamiltonian is determined to second order in the coupling, and it includes two-body confining interactions. We make a momentum expansion, obtaining an equal-time-like Schrodinger equation. This is solved for quark-antiquark constituent states, and we obtain a set of self-consistent parameters by fitting B meson spectra.Comment: 38 pages, latex, 5 latex figures include