Submillimetric spectroscopic observations of volatiles in comet C/2004 Q2 (Machholz)

We aim to determine the production rates of several parent and product volatiles and the 12C/13C isotopic carbon ratio in the long-period comet C/2004 Q2 (Machholz), which is likely to originate from the Oort Cloud. The line emission from several molecules in the coma was measured with high signal-to-noise ratio in January 2005 at heliocentric distance of 1.2 AU by means of high-resolution spectroscopic observations using the Submillimeter Telescope (SMT). We have obtained production rates of several volatiles (CH3OH, HCN, H13CN, HNC, H2CO, CO and CS) by comparing the observed and simulated line-integrated intensities. Furthermore, multiline observations of the CH3OH (7-6) series allow us to estimate the rotational temperature using the rotation diagram technique. We find that the CH3OH population distribution of the levels sampled by these lines can be described by a rotational temperature of 40 \pm 3 K. Derived mixing ratios relative to hydrogen cyanide are CO/CH3OH/H2CO/CS/HNC/H13CN/HCN = 30.9/24.6/4.8/0.57/0.031/0.013/1 assuming a pointing offset of 8" due to the uncertain ephemeris at the time of the observations and the telescope pointing error. The measured relative molecular abundances in C/2004 Q2 (Machholz) are between low- to typical values of those obtained in Oort Cloud comets, suggesting that it has visited the inner solar system previously and undergone thermal processing. The HNC/HCN abundance ratio of ~3.1% is comparable to that found in other comets, accounting for the dependence on the heliocentric distance, and could possibly be explained by ion-molecule chemical processes in the low-temperature atmosphere. From a tentative H13CN detection, the measured value of 97 \pm 30 for the H12CN/H13CN isotopologue pair is consistent with a telluric value.Comment: 14 pages with 11 figures, abridged abstrac

A survey of volatile species in Oort cloud comets C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR) at millimeter wavelengths

The line emission in the coma was measured in the comets C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR), that were observed on five consecutive nights, 7-11 May 2004, at heliocentric distances of 1.0 and 0.7 AU, respectively, by means of high-resolution spectroscopy using the 10-m Submillimeter Telescope (SMT). We present a search for six parent- and product-volatile species (HCN, H2CO, CO, CS, CH3OH, and HNC) in both comets. Multiline observations of the CH3OH J = 5-4 series allow us to estimate the rotational temperature using the rotation diagram technique. We derive rotational temperatures of 54(9) K for C/2001 Q4 (NEAT) and 119(34) K for C/2002 T7 (LINEAR) that are roughly consistent with observations of other comets at similar distances from the Sun. The gas production rates of material are computed using a spherically symmetric molecular excitation code that includes collisions between neutrals and electrons. We find an HCN production rate of 2.96(5)e26 molec.s-1 for comet C/2001 Q4 (NEAT), corresponding to a mixing ratio with respect to H2O of 1.12(2)e-3. The mean HCN production rate during the observing period is 4.54(10)e26 molec.s-1 for comet C/2002 T7 (LINEAR), which gives a Q_HCN/Q_H2O mixing ratio of 1.51(3)e-3. With systematically lower mixing ratios in comet C/2001 Q4 (NEAT), production rate ratios of the observed species with respect to H2O lie within the typical ranges of dynamically new comets in both objects. We find a relative low abundance of CO in C/2001 Q4 (NEAT) compared to the observed range in other comets based on millimeter/submillimeter observations, and a significant upper limit on the CO production in C/2002 T7 (LINEAR) is derived. Depletion of CO suggests partial evaporation from the surface layers during previous visits to the outer Solar System and agrees with previous measurements of dynamically new comets.Comment: 20 pages, 18 figures. Minor changes to match the published versio

The Domain Chaos Puzzle and the Calculation of the Structure Factor and Its Half-Width

The disagreement of the scaling of the correlation length xi between experiment and the Ginzburg-Landau (GL) model for domain chaos was resolved. The Swift-Hohenberg (SH) domain-chaos model was integrated numerically to acquire test images to study the effect of a finite image-size on the extraction of xi from the structure factor (SF). The finite image size had a significant effect on the SF determined with the Fourier-transform (FT) method. The maximum entropy method (MEM) was able to overcome this finite image-size problem and produced fairly accurate SFs for the relatively small image sizes provided by experiments. Correlation lengths often have been determined from the second moment of the SF of chaotic patterns because the functional form of the SF is not known. Integration of several test functions provided analytic results indicating that this may not be a reliable method of extracting xi. For both a Gaussian and a squared SH form, the correlation length xibar=1/sigma, determined from the variance sigma^2 of the SF, has the same dependence on the control parameter epsilon as the length xi contained explicitly in the functional forms. However, for the SH and the Lorentzian forms we find xibar ~ xi^1/2. Results for xi determined from new experimental data by fitting the functional forms directly to the experimental SF yielded xi ~ epsilon^-nu} with nu ~= 1/4 for all four functions in the case of the FT method, but nu ~= 1/2, in agreement with the GL prediction, in the the case of the MEM. Over a wide range of epsilon and wave number k, the experimental SFs collapsed onto a unique curve when appropriately scaled by xi.Comment: 15 pages, 26 figures, 1 tabl

Finite Size Scaling of Domain Chaos

Numerical studies of the domain chaos state in a model of rotating Rayleigh-Benard convection suggest that finite size effects may account for the discrepancy between experimentally measured values of the correlation length and the predicted divergence near onset

Ammonia and other parent molecules in comet 10P/Tempel 2 from Herschel/HIFI and ground-based radio observations

The Jupiter-family comet 10P/Tempel 2 was observed during its 2010 return with the Herschel Space Observatory. We present here the observation of the (J, K) = (1, 0)-(0, 0) transition of ammonia at 572 GHz in this comet with the Heterodyne Instrument for the Far Infrared (HIFI) of Herschel. We also report on radio observations of other molecules (HCN, CH3OH, H2S and CS) obtained during the 1999 return of the comet with the CSO telescope and the JCMT, and during its 2010 return with the IRAM 30-m telescope. Molecular abundances relative to water are 0.09%, 1.8%, 0.4%, and 0.08% for HCN, CH3OH, H2S, and CS, respectively. An abundance of 0.5% for NH3 is obtained, which is similar to the values measured in other comets. The hyperfine structure of the ammonia line is resolved for the first time in an astronomical source. Strong anisotropy in the outgassing is present in all observations from 1999 to 2010 and is modelled to derive the production rates.Comment: 6 pages and 8 figures. Accepted for publication in Astronomy & Astrophysic

Searches for HCl and HF in comets 103P/Hartley 2 and C/2009 P1 (Garradd) with the Herschel space observatory

HCl and HF are expected to be the main reservoirs of fluorine and chlorine wherever hydrogen is predominantly molecular. They are found to be strongly depleted in dense molecular clouds, suggesting freeze-out onto grains in such cold environments. We can then expect that HCl and HF were also the major carriers of Cl and F in the gas and icy phases of the outer solar nebula, and were incorporated into comets. We aimed to measure the HCl and HF abundances in cometary ices as they can provide insights on the halogen chemistry in the early solar nebula. We searched for the J(1-0) lines of HCl and HF at 626 and 1232 GHz, respectively, using the HIFI instrument on board the Herschel Space Observatory. HCl was searched for in comets 103P/Hartley 2 and C/2009 P1 (Garradd), whereas observations of HF were conducted in comet C/2009 P1. In addition, observations of H$_2$O and H$_2^{18}$O lines were performed in C/2009 P1 to measure the H$_2$O production rate. Three lines of CH$_3$OH were serendipitously observed in the HCl receiver setting. HCl is not detected, whereas a marginal (3.6-$\sigma$) detection of HF is obtained. The upper limits for the HCl abundance relative to water are 0.011% and 0.022%, for 103P and C/2009 P1, respectively, showing that HCl is depleted with respect to the solar Cl/O abundance by a factor more than 6$^{+6}_{-3}$ in 103P, where the error is related to the uncertainty in the chlorine solar abundance. The marginal HF detection obtained in C/2009 P1 corresponds to an HF abundance relative to water of (1.8$\pm$0.5) $\times$ 10$^{-4}$, which is approximately consistent with a solar photospheric F/O abundance. The observed depletion of HCl suggests that HCl was not the main reservoir of chlorine in the regions of the solar nebula where these comets formed. HF was possibly the main fluorine compound in the gas phase of the outer solar nebula.Comment: Accepted for publication in Astronomy & Astrophysic

Experimental Success and the Revelation of Reality: The Miracle Argument for Scientific Realism

Carrier M. Experimental Success and the Revelation of Reality: The Miracle Argument for Scientific Realism. In: Carrier M, Roggenhofer J, Küppers G, Blanchard P, eds. Knowledge and the World: Challenges Beyond the Science Wars. The frontiers collection. Berlin [u.a.]: Springer; 2004: 137-161

Defect Chaos of Oscillating Hexagons in Rotating Convection

Using coupled Ginzburg-Landau equations, the dynamics of hexagonal patterns with broken chiral symmetry are investigated, as they appear in rotating non-Boussinesq or surface-tension-driven convection. We find that close to the secondary Hopf bifurcation to oscillating hexagons the dynamics are well described by a single complex Ginzburg-Landau equation (CGLE) coupled to the phases of the hexagonal pattern. At the bandcenter these equations reduce to the usual CGLE and the system exhibits defect chaos. Away from the bandcenter a transition to a frozen vortex state is found.Comment: 4 pages, 6 figures. Fig. 3a with lower resolution no