Fluxo de água em um Gleyic Luvisol usando traçador e sua relação com as propriedades físicas e morfológicas do solo

The understanding of the preferential water flow and solute transport is important with regard to losses of nutrients and pesticides that affect the quality of the groundwater or surface water resources. Experiments using the brilliant blue dye tracer, a tension infiltrometer (TI) and a double square infiltrometer (DI) were carried out in the experimental field site located around 15 km southeast of the city of Rostock (North-Eastern Germany) on arable land in a Pleistocene lowland landscape where corn (Zea mays L.) and barley (Hordeum spp.) had been cultivated. One day after dye the infiltration, a pit was dug and vertical profiles were prepared in the TI and DI sites to assess the dye pathways in the subsoil of a Gleyic Luvisol. We wanted to examine if the mottled red and white (bleached) colour-pattern of the Gleyic Luvisol subsoil resulting from temporally stagnant water could be related to flow paths as visualized by dye tracing and if the soil colour could be related to other physical soil properties. Biogenic soil structures were the main transport routes conducting water and solutes into great depth in short time. These pathways had lower bulk density and less cone resistance than the adjacent red or white (bleached) areas of the Gleyic Luvisol subsoil. The red areas were involved in transport because their water contents increased after as compared to before infiltration. However, the measured physical soil properties did not differ between white and red areas. We assume that red areas participate in transport at least by imbibing water from the adjacent biogenic flow paths.O fluxo preferencial de água e o transporte de solutos relacionam-se com perdas de nutrientes e pesticidas e afetam a qualidade de águas subterrâneas. Foram realizados experimentos utilizando o traçador Brilhante Blue, um infiltrômetro de tensão (TI) e um infiltrômetro com duplos quadrados (DI) num campo experimental localizado a cerca de 15 km a sudeste da cidade de Rostock (nordeste da Alemanha) num solo onde cultiva-se milho (Zea mays L.) e cevada (Hordeum spp.). Um dia após a infiltração do traçador, perfis de solo foram escavados no local do TI e do DI para observar o fluxo da água deixado pelo do traçador no solo. O objetivo era verificar se os mosqueados vermelhos e partes esbranquiçadas cor-padrão do subsolo do Gleyic Luvisol, resultante da água estagnada temporariamente, poderia estar relacionada ao fluxo da água visualizados pelo traçador e se a cor do solo poderia estar relacionada a outras propriedades físicas do solo. A estrutura biogênica do solo foi a principal rota de transporte conduzindo água e solutos em profundidade e em menor tempo. Esses caminhos tiveram menor densidade do solo e menor resistência do que as áreas vermelhas e esbranquiçadas adjacentes do subsolo do Gleyic Luvisol. Áreas vermelhas foram relacionadas com o transporte devido apresentarem maior conteúdo de água após o teste de infiltração. Entretanto, não houve diferenças entre as propriedades físicas do solo das áreas brancas e vermelhas. Assumiu-se que as áreas vermelhas participaram do transporte de água porque absorveram água do fluxo adjacente, ou seja, dos bioporos

Dye tracer and morphophysical properties to observe water flow in a Gleyic Luvisol

The understanding of the preferential water flow and solute transport is important with regard to losses of nutrients and pesticides that affect the quality of the groundwater or surface water resources. Experiments using the brilliant blue dye tracer, a tension infiltrometer (TI) and a double square infiltrometer (DI) were carried out in the experimental field site located around 15 km southeast of the city of Rostock (North-Eastern Germany) on arable land in a Pleistocene lowland landscape where corn (Zea mays L.) and barley (Hordeum spp.) had been cultivated. One day after dye the infiltration, a pit was dug and vertical profiles were prepared in the TI and DI sites to assess the dye pathways in the subsoil of a Gleyic Luvisol. We wanted to examine if the mottled red and white (bleached) colour-pattern of the Gleyic Luvisol subsoil resulting from temporally stagnant water could be related to flow paths as visualized by dye tracing and if the soil colour could be related to other physical soil properties. Biogenic soil structures were the main transport routes conducting water and solutes into great depth in short time. These pathways had lower bulk density and less cone resistance than the adjacent red or white (bleached) areas of the Gleyic Luvisol subsoil. The red areas were involved in transport because their water contents increased after as compared to before infiltration. However, the measured physical soil properties did not differ between white and red areas. We assume that red areas participate in transport at least by imbibing water from the adjacent biogenic flow paths.O fluxo preferencial de água e o transporte de solutos relacionam-se com perdas de nutrientes e pesticidas e afetam a qualidade de águas subterrâneas. Foram realizados experimentos utilizando o traçador Brilhante Blue, um infiltrômetro de tensão (TI) e um infiltrômetro com "duplos quadrados" (DI) num campo experimental localizado a cerca de 15 km a sudeste da cidade de Rostock (nordeste da Alemanha) num solo onde cultiva-se milho (Zea mays L.) e cevada (Hordeum spp.). Um dia após a infiltração do traçador, perfis de solo foram escavados no local do TI e do DI para observar o fluxo da água deixado pelo do traçador no solo. O objetivo era verificar se os mosqueados vermelhos e partes esbranquiçadas cor-padrão do subsolo do Gleyic Luvisol, resultante da água estagnada temporariamente, poderia estar relacionada ao fluxo da água visualizados pelo traçador e se a cor do solo poderia estar relacionada a outras propriedades físicas do solo. A estrutura biogênica do solo foi a principal rota de transporte conduzindo água e solutos em profundidade e em menor tempo. Esses caminhos tiveram menor densidade do solo e menor resistência do que as áreas vermelhas e esbranquiçadas adjacentes do subsolo do Gleyic Luvisol. Áreas vermelhas foram relacionadas com o transporte devido apresentarem maior conteúdo de água após o teste de infiltração. Entretanto, não houve diferenças entre as propriedades físicas do solo das áreas brancas e vermelhas. Assumiu-se que as áreas vermelhas participaram do transporte de água porque absorveram água do fluxo adjacente, ou seja, dos bioporos

Brief communication: Unravelling the composition and microstructure of a permafrost core using X-ray computed tomography

The microstructure of permafrost ground contains clues to its formation and hence its preconditioning to future change. We applied X-ray computed microtomography (CT) to obtain high-resolution data (Δx=50 µm) of the composition of a 164 cm long permafrost core drilled in a Yedoma upland in north-eastern Siberia. The CT analysis allowed the microstructures to be directly mapped and volumetric contents of excess ice, gas inclusions, and two distinct sediment types to be quantified. Using laboratory measurements of coarsely resolved core samples, we statistically estimated the composition of the sediment types and used it to indirectly quantify volumetric contents of pore ice, organic matter, and mineral material along the core. We conclude that CT is a promising method for obtaining physical properties of permafrost cores which opens novel research potentials

Applying Computed Tomography (CT) scanning for segmentation of permafrost constituents in drill cores

Computed X-ray Tomography is a non-destructive technique that allows three-dimensional imaging of soil samples' internal structures, determined by variations in their density and atomic composition. This study's objective was to develop an image processing workflow for the quantitative analysis of ice cores using high-resolution CT in order to determine the volume fraction and vertical distribution of ice, mineral, gas, and organic matter in permafrost cores. We analyzed a 155 cm permafrost core taken from a Yedoma permafrost upland on Kurungnakh Island in the Lena River Delta (northeast Siberia). The obtained results were evaluated and compared with the results of detailed, but sample-destructive laboratory analysis. The frozen permafrost core was subjected to a computerized X-ray imaging procedure with a resolution of 50 micrometers. As a result, we obtained 31000 images. Noise in the raw images is removed with a non-local means denoising filter. We chose multilevel thresholding method for the image segmentation step. Threshold values were determined based on the histograms of the images. We measured the volumetric ice content (VIC) using Java-based image processing software (ImageJ). In addition, the vertical profiles were analyzed in 1-2cm intervals. We received bulk densities and VIC by freeze-drying and standard laboratory analysis. From the top of the core and until roughly 86 cm, it mainly consists of ice and organic, with an average of 67% and 30% results, respectively. The rest of the volume is divided almost equally between air and mineral parts. Below 86 cm, it consists almost entirely of pure ice. The ice content constitutes around 97% of the composition, and air rises to roughly 3%, while mineral and organic are almost equal to zero. The difference between VIC derived through CT scan and laboratory-derived VIC lies within the range of -37% to 25%. However, the vast majority of values lie within the range of -10% to 10%. This image processing technique to quantify VIC provides a non-destructive analog to traditional laboratory analysis that could help increasing the vertical resolution for quantifying mineral, ice, gas, and organic components in permafrost cores as well as enhance the volumetric estimate

Coupled simulation of surface runoff and soil water flow using multi-objective parameter estimation

A comprehensive description of water flow in environmental and agricultural systems requires an account of both surface and subsurface pathways. We present a new model which combines a 1D overland flow model and the 2D subsurface flow HYDRUS-2D model, and uses the multi-objective global search method AMALGAM for inverse parameter estimation. Furthermore, we present data from bench-scale flow experiments which were conducted with two 5-m long replicate soil channels. While rainfall was applied, surface runoff was recorded at the downstream end of the soil channel, subsurface drainage waters were sampled at three positions equally spaced along the channels, and pressure heads were recorded at five depths. The experimental observations were used to evaluate the performance of our modeling system. The complexity of the modeling approach was increased in three steps. First, only runoff and total drainage were simulated, then drainage flows from individual compartments were additionally evaluated, and finally a surface crust and immobile soil water were also considered. The results showed that a good match between measured and observed surface runoff and total drainage does not guarantee accurate representation of the flow process. An inspection of the Pareto results of different multiobjective calibration runs revealed a significant trade-off between individual objectives, showing that no single solution existed to match spatial variability in the flow. In spite of the observed crust formation, its consideration in the more complex model structure did not ignificantly improve the fit between the model and measurements. Accounting for immobile water regions only slightly improved the fit for one of the two replicate soil channels. Discrepancies between relatively complex model simulations and seemingly simple soil channel experiments suggest the presence of additional unknowns, such as heterogeneity of the soil hydraulic properties. Nevertheless, with its versatile subsurface options and powerful inverse method, the model system shows promise for studying hillslope flow problems involving both surface runoff and subsurface flow

Transport and Retention of Sulfidized Silver Nanoparticles in Porous Media: The Role of Air-Water Interfaces, Flow Velocity, and Natural Organic Matter

The sulfidation and aging of silver nanoparticles (Ag-NPs) with natural organic matter (NOM) are major transformation processes along their pathway in wastewater treatment plants and surface waters. Although soils appear to be a sink for disposed Ag-NPs, the impact of variable saturation on the transport and retention behavior in porous media is still not fully understood. We studied the behavior of sulfidized silver nanoparticles (S-Ag-NPs, 1 mg L−1) in saturated and unsaturated sand columns regarding the effects of (i) the presence of NOM (5 mg L−1) in the aquatic phase on retention, transport, and remobilization of S-Ag-NPs and (ii) the distribution and quantity of air-water and solid-water interfaces for different flow velocities determined via X-ray microtomography (X-ray μCT). Unsaturated transport experiments were conducted under controlled conditions with unit gradients in water potential and constant water content along the flow direction for each applied flux. It was shown that (i) NOM in S-Ag-NP dispersion highly increased the NP-mobility; (ii) differences between saturated and unsaturated transport were increasing with decreasing flux and, consequently, decreasing water contents; (iii) both, solid-water and air-water interfaces were involved in retention of S-Ag-NPs aged by NOM. Using numerical model simulations and X-ray μCT of flow experiments, the breakthrough of Ag-NP could be explained by a disproportional increase in air-water interfaces and an increasing attachment efficiency with decreasing water content and flow velocity