90 research outputs found
Molecular coupling of light with plasmonic waveguides
We use molecules to couple light into and out of microscale plasmonic
waveguides. Energy transfer, mediated by surface plasmons, from donor molecules
to acceptor molecules over ten micrometer distances is demonstrated. Also
surface plasmon coupled emission from the donor molecules is observed at
similar distances away from the excitation spot. The lithographic fabrication
method we use for positioning the dye molecules allows scaling to nanometer
dimensions. The use of molecules as couplers between far-field and near-field
light offers the advantages that no special excitation geometry is needed, any
light source can be used to excite plasmons and the excitation can be localized
below the diffraction limit. Moreover, the use of molecules has the potential
for integration with molecular electronics and for the use of molecular
self-assembly in fabrication. Our results constitute a proof-of-principle
demonstration of a plasmonic waveguide where signal in- and outcoupling is done
by molecules.Comment: 9 pages, 5 figure
High-Yield of Memory Elements from Carbon Nanotube Field-Effect Transistors with Atomic Layer Deposited Gate Dielectric
Carbon nanotube field-effect transistors (CNT FETs) have been proposed as
possible building blocks for future nano-electronics. But a challenge with CNT
FETs is that they appear to randomly display varying amounts of hysteresis in
their transfer characteristics. The hysteresis is often attributed to charge
trapping in the dielectric layer between the nanotube and the gate. This study
includes 94 CNT FET samples, providing an unprecedented basis for statistics on
the hysteresis seen in five different CNT-gate configurations. We find that the
memory effect can be controlled by carefully designing the gate dielectric in
nm-thin layers. By using atomic layer depositions (ALD) of HfO and
TiO in a triple-layer configuration, we achieve the first CNT FETs with
consistent and narrowly distributed memory effects in their transfer
characteristics.Comment: 6 pages, 3 figures; added one reference, text reformatted with
smaller addition
Trapping of 27 bp - 8 kbp DNA and immobilization of thiol-modified DNA using dielectrophoresis
Dielectrophoretic trapping of six different DNA fragments, sizes varying from
the 27 to 8416 bp, has been studied using confocal microscopy. The effect of
the DNA length and the size of the constriction between nanoscale fingertip
electrodes on the trapping efficiency have been investigated. Using finite
element method simulations in conjunction with the analysis of the experimental
data, the polarizabilities of the different size DNA fragments have been
calculated for different frequencies. Also the immobilization of trapped
hexanethiol- and DTPA-modified 140 nm long DNA to the end of gold
nanoelectrodes was experimentally quantified and the observations were
supported by density functional theory calculations.Comment: 17 pages (1 column version), 8 figure
Modeling optical constants from the absorption of organic thin films using a modified Lorentz oscillator model
Optical constants of organic thin films can be evaluated using the Lorentz oscillator model (LOM) which fails to fit inhomogeneously broadened absorption of highly concentrated molecular films. In modified LOM (MLOM), the inhomogeneous broadening is implemented through a frequency-dependent adjustable broadening function. In this work, we evaluate the optical constants of rhodamine 6G doped poly-vinyl alcohol thin films with varying doping concentration (including also extensively high concentrations) using MLOM, which outperforms LOM by showing a better agreement with the experimental results. Our proposed method provides a way to accurately determine optical constants of isotropic organic thin films only from their absorption spectra without spectroscopic ellipsometry.Peer reviewe
Exocrine pancreas function decreases during the progression of the beta-cell damaging process in young prediabetic children
Objective: The function of the exocrine pancreas is decreased in patients with type 1 diabetes but it is not known when this defect develops. The current study set out to determine whether the reduced exocrine function becomes manifest after the initiation of islet autoimmunity. Methods: The study was nested in the prospective Type 1 Diabetes Prediction and Prevention study where children with human leukocyte antigen (HLA)-conferred susceptibility are observed from birth. Elastase-1 levels were analyzed from stool samples collected at the time of seroconversion to islet autoantibody positivity and at diagnosis of type 1 diabetes, as well as from samples taken from matched control children of similar age. Results: Elastase levels were lower in case children at the time of the diagnosis of diabetes when compared to the control children. However, elastase concentrations did not differ between cases and controls at the time when autoantibodies appeared. Conclusion: The results suggest that the defect in the exocrine function develops after the appearance of islet autoantibodies. Further studies are needed to assess whether reduced elastase levels predict rapid progression of islet autoimmunity to clinical disease.Peer reviewe
Modeling optical constants from the absorption of organic thin films using a modified Lorentz oscillator model
Optical constants of organic thin films can be evaluated using the Lorentz oscillator model (LOM) which fails to fit inhomogeneously broadened absorption of highly concentrated molecular films. In modified LOM (MLOM), the inhomogeneous broadening is implemented through a frequency-dependent adjustable broadening function. In this work, we evaluate the optical constants of rhodamine 6G doped poly-vinyl alcohol thin films with varying doping concentration (including also extensively high concentrations) using MLOM, which outperforms LOM by showing a better agreement with the experimental results. Our proposed method provides a way to accurately determine optical constants of isotropic organic thin films only from their absorption spectra without spectroscopic ellipsometry
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