39,936 research outputs found
Strong electron correlations in cobalt valence tautomers
We have examined cobalt based valence tautomer molecules such as
Co(SQ)(phen) using density functional theory (DFT) and variational
configuration interaction (VCI) approaches based upon a model Hamiltonian. Our
DFT results extend earlier work by finding a reduced total energy gap (order
0.6 eV) between high temperature and low temperature states when we fully relax
the coordinates (relative to experimental ones). Futhermore we demonstrate that
the charge transfer picture based upon formal valence arguments succeeds
qualitatively while failing quantitatively due to strong covalency between the
Co 3 orbitals and ligand orbitals. With the VCI approach, we argue that
the high temperature, high spin phase is strongly mixed valent, with about 30 %
admixture of Co(III) into the predominantly Co(II) ground state. We confirm
this mixed valence through a fit to the XANES spectra. Moreover, the strong
electron correlations of the mixed valent phase provide an energy lowering of
about 0.2-0.3 eV of the high temperature phase relative to the low temperature
one. Finally, we use the domain model to account for the extraordinarily large
entropy and enthalpy values associated with the transition.Comment: 10 pages, 4 figures, submitted to J. Chem. Phy
Sequential Flavour Symmetry Breaking
The gauge sector of the Standard Model (SM) exhibits a flavour symmetry which
allows for independent unitary transformations of the fermion multiplets. In
the SM the flavour symmetry is broken by the Yukawa couplings to the Higgs
boson, and the resulting fermion masses and mixing angles show a pronounced
hierarchy. In this work we connect the observed hierarchy to a sequence of
intermediate effective theories, where the flavour symmetries are broken in a
step-wise fashion by vacuum expectation values of suitably constructed spurion
fields. We identify the possible scenarios in the quark sector and discuss some
implications of this approach.Comment: 22 pages latex, no figure
Collective effects in charge transfer within a hybrid organic-inorganic system
A collective electron transfer (ET) process was discovered by studying the
current noise in a field effect transistor with light-sensitive gate formed by
nanocrystals linked by organic molecules to its surface. Fluctuations in the ET
through the organic linker are reflected in the fluctuations of the transistor
conductivity. The current noise has an avalanche character. Critical exponents
obtained from the noise power spectra, avalanche distributions, and the
dependence of the average avalanche size on avalanche duration are consistent
with each other. A plausible model is proposed for this phenomenonComment: 15 pages 4 figures. Accepted for publication in Physical Review
Letter
Ab initio formulation of the four-point conductance of interacting electronic systems
We derive an expression for the four-point conductance of a general quantum junction in terms of the density response function. Our formulation allows us to show that the four-point conductance of an interacting electronic system possessing either a geometrical constriction and/or an opaque barrier becomes identical to the macroscopically measurable two-point conductance. Within time-dependent density-functional theory the formulation leads to a direct identification of the functional form of the exchange-correlation kernel that is important for the conductance. We demonstrate the practical implementation of our formula for a metal-vacuum-metal interface
Use of the KlADH4 promoter for ethanol-dependent production of recombinant human serum albumine in Kluyveromyces lactis
KlADH4 is a gene of Kluyveromyces lactis encoding a mitochondrial alcohol dehydrogenase activity which is specifically induced by ethanol. The promoter of this gene was used for the expression of heterologous proteins in K. lactis, a very promising organism which can be used as an alternative host to Saccharomyces cerevisiae due to its good secretory properties. In this paper we report the ethanol-driven expression in K. lactis of the bacterial beta-glucuronidase and of the human serum albumin (HSA) genes under the control of the KlADH4 promoter. In particular, we studied the extracellular production of recombinant HSA (rHSA) with integrative and replicative vectors and obtained a significant increase in the amount of the protein with multicopy vectors, showing that no limitation of KlADH4 trans-acting factors occurred in the cells. By deletion analysis of the promoter, we identified an element (UASE) which is sufficient for the induction of KlADH4 by ethanol and, when inserted in the respective promoters, allows ethanol-dependent activation of other yeast genes, such as PGK and LAC4. We also analyzed the effect of medium composition on cell growth and protein secretion. A clear improvement in the production of the recombinant protein was achieved by shifting from batch cultures (0.3 g/liter) to fed-batch cultures (1 g/liter) with ethanol as the preferred carbon source
Spectra and positions of galactic gamma-ray sources
The UCSD/MIT Hard X-Ray and Low Energy Gamma-Ray Experiment aboard HEAO-1 scanned the galactic center region during three epochs in 1977 and 1978 from 13 to 180 keV. The results are presented from the scanning epoch of 1978 September. Twenty-two known 2 to 10 keV source positions were necessary for an acceptable fit to the data. The spectra of the 16 strongest, least confused sources are all consistent with power laws with photon spectral indices ranging from 2.1 to 7.2. Acceptable fits to thermal bremsstrahlung models are also possible for most sources. No one source in this survey can be extrapolated to higher energy to match the intensity of the gamma-ray continuum as measured by HEAO-1 large field of view detectors, which implies that the continuum is a composite of contributions from a number of sources
Spectrum of the gamma-ray diffuse component observed from HEAO-1
The spectrum of the diffuse X and gamma ray background was measured between 15 keV and 4 MeV with the scintillation detectors aboard the HEAO 1 satellite. The apertures of the detectors were modulated on time scales of hours and the difference in counting rates measured the diffuse component flux. The observed spectrum is presented and compared with other measurements. At least two components are indicated, one below -100 keV and the other above. Possible origins are discussed
Characterization of a nondestructive beam profile monitor using luminescent emission
The LHC (large hadron collider) [LHC study group: LHC. The large hadron collider conceptual design; CERN/AC/95-05] is the future p-p collider under construction at CERN, Geneva. Over a circumference of 26.7 km a set of cryogenic dipoles and rf cavities will store and accelerate proton and ion beams up to energies of the order of 7 TeV. Injection in LHC will be performed by the CERN complex of accelerators, starting from the source and passing through the linac, the four booster rings, the proton synchrotron (PS), and super proton synchrotron (SPS) accelerators. One of the main constraints on LHC performance is emittance preservation along the whole chain of CERN accelerators. The accepted relative normalized emittance blowup after filamentation is ±7%. To monitor the beam and the emittance blowup process, a study of different prototypes of nonintercepting beam profile monitors has been performed. In this context a monitor using the luminescent emission of gases excited by ultrarelativistic protons (450 GeV) was developed and tested in the SPS ring. The results of beam size measurements and their evolution as a function of the machine parameters are presented. The image quality and resolution attainable in the LHC case have been assessed. A first full characterization of the luminescence cross section, spectrum, decay time, and afterglow effect for an ultrarelativistic proton beam is provided. Some significant results are also provided for lead ion beams
Flexible high-voltage supply for experimental electron microscope
Scanning microscope uses a field-emission tip for the electron source, an electron gun that simultaneously accelerates and focuses electrons from the source, and one auxiliary lens to produce a final probe size at the specimen on the order of angstroms
Unsupervised Diverse Colorization via Generative Adversarial Networks
Colorization of grayscale images has been a hot topic in computer vision.
Previous research mainly focuses on producing a colored image to match the
original one. However, since many colors share the same gray value, an input
grayscale image could be diversely colored while maintaining its reality. In
this paper, we design a novel solution for unsupervised diverse colorization.
Specifically, we leverage conditional generative adversarial networks to model
the distribution of real-world item colors, in which we develop a fully
convolutional generator with multi-layer noise to enhance diversity, with
multi-layer condition concatenation to maintain reality, and with stride 1 to
keep spatial information. With such a novel network architecture, the model
yields highly competitive performance on the open LSUN bedroom dataset. The
Turing test of 80 humans further indicates our generated color schemes are
highly convincible
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