272 research outputs found

    Sparse Estimation of Cox Proportional Hazards Models via Approximated Information Criteria

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    We propose a new sparse estimation method for Cox (1972) proportional hazards models by optimizing an approximated information criterion. The main idea involves approximation of the inline image norm with a continuous or smooth unit dent function. The proposed method bridges the best subset selection and regularization by borrowing strength from both. It mimics the best subset selection using a penalized likelihood approach yet with no need of a tuning parameter. We further reformulate the problem with a reparameterization step so that it reduces to one unconstrained nonconvex yet smooth programming problem, which can be solved efficiently as in computing the maximum partial likelihood estimator (MPLE). Furthermore, the reparameterization tactic yields an additional advantage in terms of circumventing postselection inference. The oracle property of the proposed method is established. Both simulated experiments and empirical examples are provided for assessment and illustration

    Constructing Multivariate Survival Trees: The MST Package for R

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    Multivariate survival trees require few statistical assumptions, are easy to interpret, and provide meaningful diagnosis and prediction rules. Trees can handle a large number of predictors with mixed types and do not require predictor variable transformation or selection. These are useful features in many application fields and are often required in the current era of big data. The aim of this article is to introduce the R package MST. This package constructs multivariate survival trees using marginal model and frailty model based approaches. It allows the user to control and see how the trees are constructed. The package can also simulate high-dimensional, multivariate survival data from marginal and frailty models

    Defect-enriched iron fluoride-oxide nanoporous thin films bifunctional catalyst for water splitting

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    Developing cost-effective electrocatalysts operated in the same electrolyte for water splitting, including oxygen and hydrogen evolution reactions, is important for clean energy technology and devices. Defects in electrocatalysts strongly influence their chemical properties and electronic structures, and can dramatically improve electrocatalytic performance. However, the development of defect-activated electrocatalyst with an efficient and stable water electrolysis activity in alkaline medium remains a challenge, and the understanding of catalytic origin is still limited. Here, we highlight defect-enriched bifunctional eletrocatalyst, namely, three-dimensional iron fluoride-oxide nanoporous films, fabricated by anodization/fluorination process. The heterogeneous films with high electrical conductivity possess embedded disorder phases in crystalline lattices, and contain numerous scattered defects, including interphase boundaries, stacking faults, oxygen vacancies, and dislocations on the surfaces/interface. The heterocatalysts efficiently catalyze water splitting in basic electrolyte with remarkable stability. Experimental studies and first-principle calculations suggest that the surface/edge defects contribute significantly to their high performance

    THE CLASSIFICATION OF SOME MODULAR FROBENIUS GROUPS

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