37 research outputs found
The vortex state in geologic materials: a micromagnetic perspective
A wide variety of Earth and planetary materials are very good recorders of paleomagnetic information. However, most magnetic grains in these materials are not in the stable single domain grain size range but are larger and in nonuniform vortex magnetization states. We provide a detailed account of vortex phenomena in geologic materials by simulating firstâorder reversal curves (FORCs) via finiteâelement micromagnetic modeling of magnetite nanoparticles with realistic morphologies. The particles have been reconstructed from focused ion beam nanotomography of magnetiteâbearing obsidian and accommodate single and multiple vortex structures. Single vortex (SV) grains have fingerprints with contributions to both the transient and transientâfree zones of FORC diagrams. A fundamental feature of the SV fingerprint is a central ridge, representing a distribution of negative saturation vortex annihilation fields. SV irreversible events at multiple field values along different FORC branches determine the asymmetry in the upper and lower lobes of generic bulk FORC diagrams of natural materials with grains predominantly in the vortex state. Multivortex (MV) FORC signatures are modeled here for the first time. MV grains contribute mostly to the transientâfree zone of a FORC diagram, averaging out to create a broad central peak. The intensity of the central peak is higher than that of the lobes, implying that MV particles are more abundant than SV particles in geologic materials with vortex state fingerprints. The abundance of MV particles, as well as their single domainâlike properties point to MV grains being the main natural remanent magnetization carriers in geologic materials
Hybrid FIB milling strategy for the fabrication of plasmonic nanostructures on semiconductor substrates
The optical properties of plasmonic semiconductor devices fabricated by focused ion beam (FIB) milling deteriorate because of the amorphisation of the semiconductor substrate. This study explores the effects of combining traditional 30 kV FIB milling with 5 kV FIB patterning to minimise the semiconductor damage and at the same time maintain high spatial resolution. The use of reduced acceleration voltages is shown to reduce the damage from higher energy ions on the example of fabrication of plasmonic crystals on semiconductor substrates leading to 7-fold increase in transmission. This effect is important for focused-ion beam fabrication of plasmonic structures integrated with photodetectors, light-emitting diodes and semiconductor lasers
Helium ion microscope â secondary ion mass spectrometry for geological materials
The helium ion microscope (HIM) is a focussed ion beam instrument with unprecedented spatial resolution for secondary electron imaging but has traditionally lacked microanalytical capabilities. With the addition of the secondary ion mass spectrometry (SIMS) attachment, the capabilities of the instrument have expanded to microanalysis of isotopes from Li up to hundreds of atomic mass units, effectively opening up the analysis of all natural and geological systems. However, the instrument has thus far been underutilised by the geosciences community, due in no small part to a lack of a thorough understanding of the quantitative capabilities of the instrument. Li represents an ideal element for an exploration of the instrument as a tool for geological samples, due to its importance for economic geology and a green economy, and the difficult nature of observing Li with traditional microanalytical techniques. Also Li represents a âbest-caseâ scenario for isotopic measurements. Here we present details of sample preparation, instrument sensitivity, theoretical, and measured detection limits for both elemental and isotopic analysis as well as practicalities for geological sample analyses of Li alongside a discussion of potential geological use cases of the HIMâSIMS instrument
The Vortex State in Geologic Materials: A Micromagnetic Perspective
A wide variety of Earth and planetary materials are very good recorders of paleomagnetic information. However, most magnetic grains in these materials are not in the stable single domain grain size range but are larger and in nonuniform vortex magnetization states. We provide a detailed account of vortex phenomena in geologic materials by simulating firstâorder reversal curves (FORCs) via finiteâelement micromagnetic modeling of magnetite nanoparticles with realistic morphologies. The particles have been reconstructed from focused ion beam nanotomography of magnetiteâbearing obsidian and accommodate single and multiple vortex structures. Single vortex (SV) grains have fingerprints with contributions to both the transient and transientâfree zones of FORC diagrams. A fundamental feature of the SV fingerprint is a central ridge, representing a distribution of negative saturation vortex annihilation fields. SV irreversible events at multiple field values along different FORC branches determine the asymmetry in the upper and lower lobes of generic bulk FORC diagrams of natural materials with grains predominantly in the vortex state. Multivortex (MV) FORC signatures are modeled here for the first time. MV grains contribute mostly to the transientâfree zone of a FORC diagram, averaging out to create a broad central peak. The intensity of the central peak is higher than that of the lobes, implying that MV particles are more abundant than SV particles in geologic materials with vortex state fingerprints. The abundance of MV particles, as well as their single domainâlike properties point to MV grains being the main natural remanent magnetization carriers in geologic materials
Nanomagnetic properties of the meteorite cloudy zone.
Meteorites contain a record of their thermal and magnetic history, written in the intergrowths of iron-rich and nickel-rich phases that formed during slow cooling. Of intense interest from a magnetic perspective is the "cloudy zone," a nanoscale intergrowth containing tetrataenite-a naturally occurring hard ferromagnetic mineral that has potential applications as a sustainable alternative to rare-earth permanent magnets. Here we use a combination of high-resolution electron diffraction, electron tomography, atom probe tomography (APT), and micromagnetic simulations to reveal the 3D architecture of the cloudy zone with subnanometer spatial resolution and model the mechanism of remanence acquisition during slow cooling on the meteorite parent body. Isolated islands of tetrataenite are embedded in a matrix of an ordered superstructure. The islands are arranged in clusters of three crystallographic variants, which control how magnetic information is encoded into the nanostructure. The cloudy zone acquires paleomagnetic remanence via a sequence of magnetic domain state transformations (vortex to two domain to single domain), driven by Fe-Ni ordering at 320 °C. Rather than remanence being recorded at different times at different positions throughout the cloudy zone, each subregion of the cloudy zone records a coherent snapshot of the magnetic field that was present at 320 °C. Only the coarse and intermediate regions of the cloudy zone are found to be suitable for paleomagnetic applications. The fine regions, on the other hand, have properties similar to those of rare-earth permanent magnets, providing potential routes to synthetic tetrataenite-based magnetic materials.European Research Counci
On three-dimensional misorientation spaces.
Determining the local orientation of crystals in engineering and geological materials has become routine with the advent of modern crystallographic mapping techniques. These techniques enable many thousands of orientation measurements to be made, directing attention towards how such orientation data are best studied. Here, we provide a guide to the visualization of misorientation data in three-dimensional vector spaces, reduced by crystal symmetry, to reveal crystallographic orientation relationships. Domains for all point group symmetries are presented and an analysis methodology is developed and applied to identify crystallographic relationships, indicated by clusters in the misorientation space, in examples from materials science and geology. This analysis aids the determination of active deformation mechanisms and evaluation of cluster centres and spread enables more accurate description of transformation processes supporting arguments regarding provenance
Secondary magnetic inclusions in detrital zircons from the Jack Hills, Western Australia, and implications for the origin of the geodynamo
The time of origin of Earthâs dynamo is unknown. Detrital zircon crystals containing ferromagnetic inclusions from the Jack Hills of Western Australia have the potential to contain the oldest records of the geodynamo. It has recently been argued that magnetization in these zircons indicates that an active dynamo existed as far back as 4.2 Ga. However, the ages of ferromagnetic inclusions in the zircons are unknown. Here we present the first detailed characterization of the mineralogy and spatial distribution of ferromagnetic minerals in Jack Hills detrital zircons. We demonstrate that ferromagnetic minerals in most Jack Hills zircons are commonly located in cracks and on the zirconsâ exteriors. Hematite is observed to dominate the magnetization of many zircons, while other zircons also contain significant quantities of magnetite and goethite. This indicates that the magnetization of most zircons is likely to be dominantly carried by secondary minerals that could be hundreds of millions to billions of years younger than the zirconsâ crystallization ages. We conclude that the existence of the geodynamo prior to 3.5 Ga has yet to be established
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Reevaluating the evidence for a Hadean-Eoarchean dynamo.
The time of origin of the geodynamo has important implications for the thermal evolution of the planetary interior and the habitability of early Earth. It has been proposed that detrital zircon grains from Jack Hills, Western Australia, provide evidence for an active geodynamo as early as 4.2 billion years (Ga) ago. However, our combined paleomagnetic, geochemical, and mineralogical studies on Jack Hills zircons indicate that most have poor magnetic recording properties and secondary magnetization carriers that postdate the formation of the zircons. Therefore, the existence of the geodynamo before 3.5 Ga ago remains unknown
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Secondary magnetic inclusions in detrital zircons from the Jack Hills, Western Australia, and implications for the origin of the geodynamo
The time of origin of Earthâs dynamo is unknown. Detrital zircon
crystals containing ferromagnetic inclusions from the Jack Hills of
Western Australia have the potential to contain the oldest records of
the geodynamo. It has recently been argued that magnetization in
these zircons indicates that an active dynamo existed as far back as 4.2
Ga. However, the ages of ferromagnetic inclusions in the zircons are
unknown. Here we present the first detailed characterization of the
mineralogy and spatial distribution of ferromagnetic minerals in Jack
Hills detrital zircons. We demonstrate that ferromagnetic minerals in
most Jack Hills zircons are commonly located in cracks and on the
zirconsâ exteriors. Hematite is observed to dominate the magnetization
of many zircons, while other zircons also contain significant quantities
of magnetite and goethite. This indicates that the magnetization of
most zircons is likely to be dominantly carried by secondary minerals
that could be hundreds of millions to billions of years younger than
the zirconsâ crystallization ages. We conclude that the existence of the
geodynamo prior to 3.5 Ga has yet to be establishe