Determination of gas volume trapped in a closed fluid system

Technique involves extracting known volume of fluid and measuring system before and after extraction, volume of entrapped gas is then computed. Formula derived from ideal gas laws is basis of this method. Technique is applicable to thermodynamic cycles and hydraulic systems

Lightweight reflector assembly

An inexpensive, lightweight reflective assembly member having good optical quality and particularly adaptable to accommodating temperature variations without providing destructive thermal stresses and reflective slope errors is described. The reflective assembly consists of a thin sheet of glass with appropriate reflective coating and a cellular glass block substrate bonded together. The method of fabrication includes abrading the cellular substrate with an abrasive master die to form an appropriate concave surface. An adhesive is applied to the abraded surface and a lamina reflective surface is placed under a uniform pressure to conform the reflective surface onto the desired abraded surface of the substrate

Rifting and Mafic Magmatism in the Hebridean Basins

Acknowledgements and Funding Research in the BPIP was supported by NERC grant GR9/1581, and the Carnegie Trust for the Universities of Scotland. H. Rollinson and E. Gazel are thanked for helpful and constructive criticisms, particularly of the modelling aspects of the paper, and T. Rooney is thanked for invaluable scientific and editorial assistance.Peer reviewedPostprin

Scientific drilling of the Boltysh impact crater, Ukraine

Introduction: The Boltysh crater has been known for several decades and was first drilled in the 1960s as part of a study of economic oil shale deposits. Unfortunately, the cores were not curated and have been lost. We have re-drilled the impact crater and have recovered a near continuous record of ~400 m of organicrich sediments together with 15 m of suevite

Frontier exploration and the North Atlantic Igneous Province : new insights from a 2.6 km offshore volcanic sequence in the NE Faroe–Shetland Basin

Acknowledgements and Funding This work was funded by Chevron. The authors would like to acknowledge the Chevron West of Shetlands team along with the Joint Venture partners OMV, Faroe Petroleum and Indemitsu for access to data along with permission to publish this study. PGS is thanked for access to the Corona Ridge Regional Geostreamer (CRRG) data and permission to publish the seismic line. The paper was improved thanks to insightful reviews by S. M. Jones and A. Saunders, which substantially improved an earlier draft. J. Still and F. Thompson gave invaluable technical support at the University of Aberdeen, and K. Wall helped with real-time cuttings analysis.Peer reviewedPostprin

Organic geochemistry of the crater-fill sediments from Boltysh impact crater, Ukraine

The Boltysh impact crater, is a complex structure formed on the basement rocks of the Ukrainian shield which has been dated at 65.17±0.64 Ma [1]. The Boltysh crater has been know for several decades and was originally drilled in the 1960s-1980s in a study of economic oil shale deposits. Unfortunately, the cores were not curated and have been lost. However we have recently re-drilled the impact crater and have recovered a near continuous record of ~400 m of organic rich sediments deposited in a deep isolated lake which overlie the basement rocks spanning a period ~10 Ma. At 24km diameter, Boltysh will not have contributed substantially to the worldwide devastation at the end of the Cretaceous. However, the precise age of the Boltysh impact relative to the Chicxulub impact and its location on a stable low lying coastal plain which allowed formation of the postimpact crater lake make it a particularly important locality. After the impact, the crater quickly filled with water in a short marine phase but returned to fresh water which persisted for >10Ma [2]. These strata contain a valuable record of Paleogene environmental change in central Europe, and one of very few terrestrial records of the KT event. This pre-eminent record of the Paleogene can help us to answer several related scientific questions including the relative age of Boltysh compared with Chicxulub, recovery from the impact, and later climate signals. The organic geochemistry and playnology indicate main inputs to be algal and higher plant within most of the core although there are some marked changes in inputs in some sections. A number of carbon isotope excursions are also present within the core which are currently being further investigated

Microencapsulation of Self Healing Agents for Corrosion Control Coatings

Corrosion, the environmentally induced degradation of materials, is a very costly problem that has a major impact on the global economy. Results from a 2-year breakthrough study released in 2002 by the U.S. Federal Highway Administration (FHWA) showed that the total annual estimated direct cost associated with metallic corrosion in nearly every U.S. industry sector was a staggering $276 billion, approximately 3.1% of the nation's Gross Domestic Product (GOP). Corrosion protective coatings are widely used to protect metallic structures from the detrimental effects of corrosion but their effectiveness can be seriously compromised by mechanical damage, such as a scratch, that exposes the metallic substrate. The incorporation of a self healing mechanism into a corrosion control coating would have the potential to significantly increase its effectiveness and useful lifetime. This paper describes work performed to incorporate a number of microcapsule-based self healing systems into corrosion control coatings. The work includes the preparation and evaluation of self-healing systems based on curable epoxy, acrylate, and siloxane resins, as well as, microencapsulated systems based on passive, solvent born, healing agent delivery. The synthesis and optimization of microcapsule-based self healing systems for thin coating (less than 100 micron) will be presented

Two large meteorite impacts at the Cretaceous–Paleogene boundary

The end-Cretaceous mass extinction has been attributed by most to a single asteroid impact at Chicxulub on the Yucatán Peninsula, Mexico. The discovery of a second smaller crater with a similar age at Boltysh in the Ukraine has raised the possibility that a shower of asteroids or comets impacted Earth close to the Cretaceous-Paleogene (K-Pg) boundary. Here we present palynological and δ13C evidence from crater-fill sediments in the Boltysh impact crater. Our analyses demonstrate that a post-impact flora, formed on the ejecta layer, was in turn devastated by the K-Pg event. The sequence of floral recovery from the K-Pg event is directly comparable with that in middle North America. We conclude that the Boltysh crater predated Chicxulub by ∼2–5 k.y., a time scale that constrains the likely origin of the bodies that formed the two known K-Pg craters

Changes in serogroup and genotype prevalence among carried meningococci in the United Kingdom during vaccine implementation.

BACKGROUND: Herd immunity is important in the effectiveness of conjugate polysaccharide vaccines against encapsulated bacteria. A large multicenter study investigated the effect of meningococcal serogroup C conjugate vaccine introduction on the meningococcal population. METHODS: Carried meningococci in individuals aged 15-19 years attending education establishments were investigated before and for 2 years after vaccine introduction. Isolates were characterized by multilocus sequence typing, serogroup, and capsular region genotype and changes in phenotypes and genotypes assessed. RESULTS: A total of 8462 meningococci were isolated from 47 765 participants (17.7%). Serogroup prevalence was similar over the 3 years, except for decreases of 80% for serogroup C and 40% for serogroup 29E. Clonal complexes were associated with particular serogroups and their relative proportions fluctuated, with 12 statistically significant changes (6 up, 6 down). The reduction of ST-11 complex serogroup C meningococci was probably due to vaccine introduction. Reasons for a decrease in serogroup 29E ST-254 meningococci (from 1.8% to 0.7%) and an increase in serogroup B ST-213 complex meningococci (from 6.7% to 10.6%) were less clear. CONCLUSIONS: Natural fluctuations in carried meningococcal genotypes and phenotypes a can be affected by the use of conjugate vaccines, and not all of these changes are anticipatable in advance of vaccine introduction

Rhinosporidium seeberi: a human pathogen from a novel group of aquatic protistan parasites.

Rhinosporidium seeberi, a microorganism that can infect the mucosal surfaces of humans and animals, has been classified as a fungus on the basis of morphologic and histochemical characteristics. Using consensus polymerase chain reaction (PCR), we amplified a portion of the R. seeberi 18S rRNA gene directly from infected tissue. Analysis of the aligned sequence and inference of phylogenetic relationships showed that R. seeberi is a protist from a novel clade of parasites that infect fish and amphibians. Fluorescence in situ hybridization and R. seeberi- specific PCR showed that this unique 18S rRNA sequence is also present in other tissues infected with R. seeberi. Our data support the R. seeberi phylogeny recently suggested by another group. R. seeberi is not a classic fungus, but rather the first known human pathogen from the DRIPs clade, a novel clade of aquatic protistan parasites (Ichthyosporea)