Lanthanide Ionization Energies and the Sub-Shell Break. Part 2. The Third and Fourth Ionization Energies

By interpolating a 4fq6s → 4fq7s transition within the sequence f1 → f14 rather than between f0 and f14, revised third and fourth ionization energies of the lanthanides have been obtained. The revised values, together with the second ionization energies calculated in a previous paper, are used to calculate values of the standard enthalpies of formation of the gaseous tripositive ions, ΔfHƟ(M3+,g), and of the lattice and hydration enthalpies of some lanthanide compounds and ions in the trivalent and tetravalent states. The displacements of f0 values from nearly smooth f1 → f14 variations exceed 30 kJ mol-1 and indicate substantial subshell breaks

Valencies of the lanthanides

The valencies of the lanthanides vary more than was once thought. In addition to valencies associated with a half-full shell, there are valencies associated with a quarter- and three-quarter-full shell. This can be explained on the basis of Slater’s theory of many-electron atoms. The same theory explains the variation in complexing constants in the trivalent state (the “tetrad effect”). Valency in metallic and organometallic compounds is also discussed

Deep-water turbidites as Holocene earthquake proxies: the Cascadia subduction zone and Northern San Andreas Fault systems

New stratigraphic evidence from the Cascadia margin demonstrates that 13 earthquakes ruptured the margin from Vancouver Island to at least the California border following the catastrophic eruption of Mount Mazama. These 13 events have occurred with an average repeat time of ?? 600 years since the first post-Mazama event ?? 7500 years ago. The youngest event ?? 300 years ago probably coincides with widespread evidence of coastal subsidence and tsunami inundation in buried marshes along the Cascadia coast. We can extend the Holocene record to at least 9850 years, during which 18 events correlate along the same region. The pattern of repeat times is consistent with the pattern observed at most (but not all) localities onshore, strengthening the contention that both were produced by plate-wide earthquakes. We also observe that the sequence of Holocene events in Cascadia may contain a repeating pattern, a tantalizing look at what may be the long-term behavior of a major fault system. Over the last ?? 7500 years, the pattern appears to have repeated at least three times, with the most recent A.D. 1700 event being the third of three events following a long interval of 845 years between events T4 and T5. This long interval is one that is also recognized in many of the coastal records, and may serve as an anchor point between the offshore and onshore records. Similar stratigraphic records are found in two piston cores and one box core from Noyo Channel, adjacent to the Northern San Andreas Fault, which show a cyclic record of turbidite beds, with thirty- one turbidite beds above a Holocene/.Pleistocene faunal «datum». Thus far, we have determined ages for 20 events including the uppermost 5 events from these cores. The uppermost event returns a «modern» age, which we interpret is likely the 1906 San Andreas earthquake. The penultimate event returns an intercept age of A.D. 1664 (2 ?? range 1505- 1822). The third event and fourth event are lumped together, as there is no hemipelagic sediment between them. The age of this event is A.D. 1524 (1445-1664), though we are not certain whether this event represents one event or two. The fifth event age is A.D. 1204 (1057-1319), and the sixth event age is A.D. 1049 (981-1188). These results are in relatively good agreement with the onshore work to date, which indicates an age for the penultimate event in the mid-1600 s, the most likely age for the third event of ?? 1500-1600, and a fourth event ?? 1300. We presently do not have the spatial sampling needed to test for synchroneity of events along the Northern San Andreas, and thus cannot determine with confidence that the observed turbidite record is earthquake generated. However, the good agreement in number of events between the onshore and offshore records suggests that, as in Cascadia, turbidite triggers other than earthquakes appear not to have added significantly to the turbidite record along the northernmost San Andreas margin during the last ?? 2000 years

Space-time dimensionality from brane collisions

Collisions and subsequent decays of higher dimensional branes leave behind three-dimensional branes and anti-branes, one of which could play the role of our universe. This process also leads to the production of one-dimensional branes and anti-branes, however their number is expected to be suppressed. Brane collisions may also lead to the formation of bound states of branes. Their existence does not alter this result, it just allows for the existence of one-dimensional branes captured within the three-dimensional ones.Comment: 4 pages, one minor modification to match version to appear in Phys. Let.

Endogenous human cytomegalovirus gB is efficiently presented by MHC class II molecules to CD4+ CTL

Human cytomegalovirus (HCMV) infects endothelial, epithelial, and glial cells in vivo. These cells can express MHC class II proteins, but are unlikely to play important roles in priming host immunity. Instead, it seems that class II presentation of endogenous HCMV antigens in these cells allows recognition of virus infection. We characterized class II presentation of HCMV glycoprotein B (gB), a membrane protein that accumulates extensively in endosomes during virus assembly. Human CD4+ T cells specific for gB were both highly abundant in blood and cytolytic in vivo. gB-specific CD4+ T cell clones recognized gB that was expressed in glial, endothelial, and epithelial cells, but not exogenous gB that was fed to these cells. Glial cells efficiently presented extremely low levels of endogenous gB--expressed by adenovirus vectors or after HCMV infection--and stimulated CD4+ T cells better than DCs that were incubated with exogenous gB. Presentation of endogenous gB required sorting of gB to endosomal compartments and processing by acidic proteases. Although presentation of cellular proteins that traffic into endosomes is well known, our observations demonstrate for the first time that a viral protein sorted to endosomes is presented exceptionally well, and can promote CD4+ T cell recognition and killing of biologically important host cells

Measurements of Photon and Neutral Pion Production in Heavy Ion Collisions at RHIC

Inclusive transverse momentum spectra of photons and neutral pions about mid-rapidity are presented for Au+Au collisions at sqrt(s_NN} = 130 GeV. Photon pair conversions have been reconstructed from charged tracks measured with the central Time Projection Chamber (TPC) of STAR. Contributions of the pi^0 -> \gamma\gamma decay in the inclusive photon spectra have been studied. It was found that this contribution begins to decrease at a transverse momentum of 1.65 GeV/c in the top 11% most central centrality class.Comment: 5 pages, 3 figures, contribution to the Proceedings of Quark Matter 2002, Nantes, France, July 18-24, 200