The Homogeneous Nucleation Of Nonane

The homogeneous nucleation rate of n-nonane has been measured as a function of temperature and supersaturation ratio in a precision fast-expansion chamber. The measured nucleation rate ranges from 102 to 105 drops/cm3 over the temperature range 215-270 K. The results have been compared to the classical theory and to the classical theory with the RKC replacement factor. The RKC theory functional form is the basis for an empirical rate equation to fit the data. A full listing of the thermodynamic constants used for the reduction of the data is given. © 1984 American Institute of Physics

Homogeneous Nucleation Of Ethanol

The authors have used an expansion cloud chamber to measure homogeneous nucleation rate as a function of temperature and supersaturation in ethanol. Nucleation rates from 102 to 105 drops/cm3 sec were measured in the temperature range 252-272 °K. An empirical functional fit to the data is used to extrapolate for comparison with other data in the literature at a nucleation rate of 1 drop/cm3 sec and to compare with the predictions of the classical Becker-Doring homogeneous nucleation theory. A full listing of the data and thermodynamics constants used in the reduction of the data is given in an appendix. © 1982 American Institute of Physics

Homogeneous Nucleation Of Toluene

The authors have used a fast expansion chamber to measure the homogeneous nucleation rate of toluene as a function of temperature and supersaturation. The measured nucleation rate ranges from 102 to 105 drops/cm3 s over a temperature range of 215-267 K. The measurements are compared with the classical nucleation theory and with the RKC theory. The inclusion of the RKC replacement factor brings the data into good agreement with theory using physically realistic values of the surface tension and the sticking coefficient. An empirical curve fit to the data is presented as well as a full listing of the thermodynamic constants used for the calculations. © 1983 American Institute of Physics

The University of Minnesota Supplemental Fertilizer Nitrogen Worksheet

The University of Minnesota Supplemental Fertilizer N Worksheet was developed as a simple, quick, reliable, and inexpensive alternative decision aid tool to assess potential fertilizer N losses. The worksheet is a series of three questions with multiple-choice answers. Depending on the answers, numbers are assigned for each question that are summed, and then the recommendation is made for supplemental N applications. It has been used with success for 10 years in Minnesota as a decision aid as well as an educational tool regarding fertilizer N management strategies

A double-diffusive interface tank for dynamic-response studies

Author Posting. © Sears Foundation for Marine Research, 2005. This article is posted here by permission of Sears Foundation for Marine Research for personal use, not for redistribution. The definitive version was published in Journal of Marine Research 63 (2005): 263-289, doi:10.1357/0022240053693842.A large tank capable of long-term maintenance of a sharp temperature-salinity interface has been developed and applied to measurements of the dynamical response of oceanographic sensors. A two-layer salt-stratified system is heated from below and cooled from above to provide two convectively mixed layers with a thin double-diffusive interface separating them. A temperature jump exceeding 10°C can be maintained over 1–2 cm (a vertical temperature gradient of order 103°C/m) for several weeks. A variable speed-lowering system allows testing of the dynamic response of conductivity and temperature sensors in full-size oceanographic instruments. An acoustic echo sounder and shadowgraph system provide nondisruptive monitoring of the interface and layer microstructure. Tests of several sensor systems show how data from the facility is used to determine sensor response times using several fitting techniques and the speed dependence of thermometer time constants is illustrated. The linearity of the conductivity–temperature relationship across the interface is proposed as a figure of merit for design of lag-correction filters to accurately match temperature and conductivity sensors for the computation of salinity. The effects of finite interface thickness, slow sensor sampling rates and the thermal mass of the conductivity cell are treated. Sensor response characterization is especially important for autonomous instruments where data processing and compression must be performed in-situ, but is also helpful in the development of new sensors and in assuring accurate salinity records from traditional wire-lowered and towed systems.This research was supported by the National Science Foundation, grants OCE-97-11869 and OCE-02-40956, NOAA CORC grant 154368 and a WHOI Mellon Technical Staff Award

Binary Nucleation Of Ethanol And Water

The authors have used a fast expansion cloud chamber to measure binary homogeneous nucleation rates in several ethanol-water mixtures as a function of temperature, ethanol and water activities and nucleation rate. Data (ethanol and water activities) are presented for a range in nucleation rate from 10 3 to 105 drops/cm3 s from 263 to 293 K for mixtures having mole ratios (ethanol/water) of 10, 4, 0.1, 0.01, and 0.001. A comparison of the extensive data set to other data in the literature shows good agreement. We find current theory, as expected, is unable to accurately predict the data at low ethanol concentrations. © 1990 American Institute of Physics

Portable Apparatus for Electrochemical Sensing of Ethylene

A small, lightweight, portable apparatus based on an electrochemical sensing principle has been developed for monitoring low concentrations of ethylene in air. Ethylene has long been known to be produced by plants and to stimulate the growth and other aspects of the development of plants (including, notably, ripening of fruits and vegetables), even at concentrations as low as tens of parts per billion (ppb). The effects are magnified in plant-growth and -storage chambers wherein ethylene can accumulate. There is increasing recognition in agriculture and related industries that it is desirable to monitor and control ethylene concentrations in order to optimize the growth, storage, and ripening of plant products. Hence, there are numerous potential uses for the present apparatus in conjunction with equipment for controlling ethylene concentrations. The ethylene sensor is of a thick-film type with a design optimized for a low detection limit. The sensor includes a noble metal sensing electrode on a chip and a hydrated solid-electrolyte membrane that is held in contact with the chip. Also located on the sensor chip are a counter electrode and a reference electrode. The sensing electrode is held at a fixed potential versus the reference electrode. Detection takes place at active-triple-point areas where the sensing electrode, electrolyte, and sample gas meet. These areas are formed by cutting openings in the electrolyte membrane. The electrode current generated from electrochemical oxidation of ethylene at the active triple points is proportional to the concentration of ethylene. An additional film of the solid-electrolyte membrane material is deposited on the sensing electrode to increase the effective triple-point areas and thereby enhance the detection signal. The sensor chip is placed in a holder that is part of a polycarbonate housing. When fully assembled, the housing holds the solid-electrolyte membrane in contact with the chip (see figure). The housing includes a water reservoir for keeping the solid-electrolyte membrane hydrated. The housing also includes flow channels for circulating a sample stream of air over the chip: ethylene is brought to the sensing surface predominately by convection in this sample stream. The sample stream is generated by a built-in sampling pump. The forced circulation of sample air contributes to the attainment of a low detection limit

Concentrations of Metals in Aquatic Invertebrates from the Ozark National Scenic Riverways, Missouri

This report summarizes the findings of a study conducted as a pilot for part of a park-wide monitoring program being developed for the Ozark National Scenic Riverways (ONSR) of southeastern Missouri. The objective was to evaluate using crayfish (Orconectes spp.) and Asian clam (Corbicula fluminea) for monitoring concentrations of metals associated with lead-zinc mining. Lead-zinc mining presently (2007) occurs near the ONSR and additional mining has been proposed. Three composite samples of each type (crayfish and Asian clam), each comprising ten animals of approximately the same size, were collected during late summer and early fall of 2005 from five sites on the Current River and Jacks Fork within the ONSR and from one site on the Eleven Point River and the Big River, which are outside the ONSR. The Big River has been contaminated by mine tailings from historical leadzinc mining. Samples were analyzed by inductively coupled plasma mass spectrometry for lead, zinc, cadmium, cobalt, and nickel concentrations. All five metals were detected in all samples; concentrations were greatest in samples of both types from the Big River, and lowest in samples from sites within the ONSR. Concentrations of zinc and cadmium typically were greater in Asian clams than in crayfish, but differences were less evident for the other metals. In addition, differences among sites were small for cobalt in Asian clams and for zinc in crayfish, indicating that these metals are internally regulated to some extent. Consequently, both sample types are recommended for monitoring. Concentrations of metals in crayfish and Asian clams were consistent with those reported by other studies and programs that sampled streams in southeast Missouri

Inhibitory Control Processes and the Strategies That Support Them during Hand and Eye Movements

Background and Aims: Adaptive behavior depends on the ability to voluntarily suppress context-inappropriate behaviors, a process referred to as response inhibition. Stop Signal tests (SSTs) are the most frequently studied paradigm used to assess response inhibition. Previous studies of SSTs have indicated that inhibitory control behavior can be explained using a common model in which GO and STOP processes are initiated independent from one and another, and the process that is completed first determines whether the behavior is elicited (GO process) or terminated (STOP process). Consistent with this model, studies have indicated that individuals strategically delay their behaviors during SSTs in order to increase their stopping abilities. Despite being controlled by distinct neural systems, prior studies have largely documented similar inhibitory control performance across eye and hand movements. Though, no existing studies have compared the extent to which individuals strategically delay behavior across different effectors is not yet clear. Here, we compared the extent to which inhibitory control processes and the cognitive strategies that support them during oculomotor and manual motor behaviors. Methods: We examined 29 healthy individuals who performed parallel oculomotor and manual motor SSTs. Participants also completed a separate block of GO trials administered prior to the Stop Signal tests to assess baseline reaction times for each effector and reaction time increases during interleaved GO trials of the SST. Results: Our results showed that stopping errors increased for both effectors as the interval between GO and STOP cues was increased (i.e., stop signal delay), but performance deteriorated more rapidly for eye compared to hand movements with increases in stop signal delay. During GO trials, participants delayed the initiation of their responses for each effector, and greater slowing of reaction times on GO trials was associated with increased accuracy on STOP trials for both effectors. However, participants delayed their eye movements to a lesser degree than their hand movements, and strategic reaction time slowing was a stronger determinant of stopping accuracy for hand compared to eye movements. Overall, stopping accuracies for eye and hand movements were only modestly correlated, and the time it took individuals to cancel a response was not related for eye and hand movements. Discussion and Conclusion: Our findings that GO and STOP processes are independent and that individuals strategically delay their behavioral responses to increase stopping accuracy regardless of effector indicate that inhibitory control of Frontiers in Psychology | www.frontiersin.org 1 December 2016 | Volume 7 | Article 1927 Schmitt et al. Inhibitory Control of Hand and Eye Movements oculomotor and manual motor behaviors both follow common guiding principles. Yet, our findings document that eye movements are more difficult to inhibit than hand movements, and the timing, magnitude, and impact of cognitive control strategies used to support voluntary response inhibition are less robust for eye compared to hand movements. This suggests that inhibitory control systems also show unique characteristics that are behavior-dependent. This conclusion is consistent with neurophysiological evidence showing important differences in the architecture and functional properties of the neural systems involved in inhibitory control of eye and hand movements. It also suggests that characterizing inhibitory control processes in health and disease requires effector-specific analysis.NIH Autism Center of Excellence P50HD055751; MH092696, and the Kansas Center for Autism Research and Training Research Investment Council Strategic Initiative Gran

Concentrations of Metals in Aquatic Invertebrates from the Ozark National Scenic Riverways, Missouri

This report summarizes the findings of a study conducted as a pilot for part of a park-wide monitoring program being developed for the Ozark National Scenic Riverways (ONSR) of southeastern Missouri. The objective was to evaluate using crayfish (Orconectes spp.) and Asian clam (Corbicula fluminea) for monitoring concentrations of metals associated with lead-zinc mining. Lead-zinc mining presently (2007) occurs near the ONSR and additional mining has been proposed. Three composite samples of each type (crayfish and Asian clam), each comprising ten animals of approximately the same size, were collected during late summer and early fall of 2005 from five sites on the Current River and Jacks Fork within the ONSR and from one site on the Eleven Point River and the Big River, which are outside the ONSR. The Big River has been contaminated by mine tailings from historical leadzinc mining. Samples were analyzed by inductively coupled plasma mass spectrometry for lead, zinc, cadmium, cobalt, and nickel concentrations. All five metals were detected in all samples; concentrations were greatest in samples of both types from the Big River, and lowest in samples from sites within the ONSR. Concentrations of zinc and cadmium typically were greater in Asian clams than in crayfish, but differences were less evident for the other metals. In addition, differences among sites were small for cobalt in Asian clams and for zinc in crayfish, indicating that these metals are internally regulated to some extent. Consequently, both sample types are recommended for monitoring. Concentrations of metals in crayfish and Asian clams were consistent with those reported by other studies and programs that sampled streams in southeast Missouri