Data report: late Miocene to early Pliocene coccolithophore and foraminiferal preservation at Site U1338 from scanning electron microscopy

The late Miocene to early Pliocene carbonate-rich sediments recovered at Integrated Ocean Drilling Program (IODP) Site U1338 during the Expedition 320/321 Pacific Equatorial Age Transect (PEAT) program contain abundant calcareous nanno- and microfossils. Geochemical proxies from benthic and planktonic foraminiferal and coccolithophore calcite could be very useful at this location; however, good preservation of the calcite is crucial for the proxies to be robust. Here, we evaluate the preservation of specific benthic and planktonic foraminifer species and coccolithophores in fine fraction sediment at Site U1338 using backscattered electron (topography mode) scanning electron microscopy (BSE-TOPO SEM). Both investigated foraminiferal species, Cibicidoides mundulus and Globigerinoides sacculifer, have undergone some alteration. The C. mundulus show minor evidence for dissolution, and only some specimens show evidence of overgrowth. The Gs. sacculifer show definite signs of alteration and exhibit variable preservation, ranging from fair to poor; some specimens show minor overgrowth and internal recrystallization but retain original features such as pores, spine pits, and internal testwall growth structure, whereas in other specimens the recrystallization and overgrowth disguise many of the original features. Secondary electron and BSE-TOPO SEM images show that coccolith calcite preservation is moderate or moderate to poor. Slight to moderate etching has removed central heterococcolith features, and a small amount of secondary overgrowth is also visible. Energy dispersive spectroscopy analyses indicate that the main sedimentary components of the fine fraction sediment are biogenic CaCO3 and SiO2, with some marine barite. Based on the investigations in this data report, geochemical analyses on benthic foraminifers are unlikely to be affected by preservation, although geochemical analyses on the planktonic foraminifers should be treated cautiously because of the fair to poor and highly variable preservation

Significance of Fracture-Filling Rose-Like Calcite Crystal Clusters in the SE Pyrenees

Fracture-filling rose-like clusters of bladed calcite crystals are found in the northern sector of the Cadí thrust sheet (SE Pyrenees). This unusual calcite crystal morphology has been characterized by using optical and electron microscope, X-ray diffraction, Raman spectroscopy, 18O, 13C, 87Sr/86Sr, clumped isotopes, and major and rare earth elements + yttrium (REEs + Y) analysis. Petrographic observations and powder X-ray diffraction measurements indicate that these bladed crystals are mainly made of massive rhombic crystals with the conventional (104) faces, as well as of possibly younger, less abundant, and smaller laminar crystals displaying (108) and/or (108) rhombic faces. Raman analysis of liquid fluid inclusions indicates the presence of aromatic hydrocarbons and occasionally alkanes. Clumped isotopes thermometry reflects that bladed calcite precipitated from meteoric fluids at ~60-65 C. The 87Sr/86Sr ratios and major elements and REEs content of calcite indicate that these fluids interacted with Eocene marine carbonates. The presence of younger 'nailhead' calcite indicates later migration of shallow fresh groundwater. The results reveal that rose-like calcite clusters precipitated, at least in the studied area, due to a CO2 release by boiling of meteoric waters that mixed with benzene and aromatic hydrocarbons. This mixing decreased the boiling temperature at ~60-65 C. The results also suggest that the high Sr content in calcite, and probably the presence of proteins within hydrocarbons trapped in fluid inclusions, controlled the precipitation of bladed crystals with (104) rhombohedral faces

Evolution of hot fluids in the Chingshui geothermal field inferred from crystal morphology and geochemical vein data

The Chingshui geothermal field once hosted the first geothermal power plant in Taiwan from 1981 to 1993. After a long period of inactivity, this field is attracting renewed interest to meet the need for clean energy. A 213-m length of cores (IC-21) with continuous recovery, the longest in the Chingshui geothermal field, was recovered from 600 m to 813 m below the surface in 2010. Three types of calcite crystal morphologies have been identified in the veins of the cores of well IC-21: bladed, rhombic and massive crystals. Bladed calcites are generated via degassing under boiling conditions with a precipitation temperature of ∼165 °C and calculated δ18O value of −6.8‰ to −10.2‰ VSMOW for the thermal water. Rhombic calcites grow in low concentration Ca2+ and CO32− meteoric fluids and precipitate at approximately ∼180 °C. Finally, massive calcites are characterized by co-precipitation with quartz in the mixing zone between meteoric water and magmatic or metamorphic fluids with calculated δ18O value of up to 1.5 ± 0.7‰ VSMOW. Furthermore, the scaling and hot fluids at a nearby pilot geothermal power plant confirm a meteoric origin. Based on these observations, we propose that the current orientations of the main conduits for geothermal fluids are oriented at N10°E with a dip of 70°E. This result provides the basic information needed for deploying production and injection wells in future developments of the geothermal power plant in this region

Crestal graben fluid evolution during growth of the Puig-reig anticline (South Pyrenean fold and thrust belt)

tThe Puig-reig anticline, located in the South Pyrenean fold and thrust belt, developed during the Alpinecompression, which affected the upper Eocene-lower Oligocene sediments of the Solsona and BergaFormations. In this study, we highlight the controls on formation of joints and reverse, strike-slip andnormal faults developed in the crest domain of the Puig-reig anticline as well as the relationships betweenfluids and these fractures. We integrated structural, petrographic and geochemical studies, using for thefirst time in the SE Pyrenees the clumped isotopes thermometry to obtain reliable temperatures of calciteprecipitation.Structural and microstructural analysis demonstrate that at outcrop scale fracturing was controlledby rigidity contrasts between layers, diagenesis and structural position within the anticline, whereasgrain size, cementation and porosity controlled deformation at the microscopic scale. Petrographic andgeochemical studies of calcite precipitated in host rock porosity and fault planes reveal the presence oftwo migrating fluids, which represents two different stages of evolution of the Puig-reig anticline. Duringthe layer-parallel shortening, hydrothermal fluids with temperatures between 92 and 130◦C circulatedthrough the main thrusts to the permeable host rocks, reverse and most of strike-slip faults precipitatingas cement Cc1. During the fold growth, meteoric waters circulated downwards through normal and somestrike-slip faults and mixed at depth with the previous hydrothermal fluid, precipitating as cement Cc2at temperatures between 77 and 93◦C.Integration of the results from the Puig-reig anticline in this work and the El Guix anticline indicatesthat hydrothermal fluids did not reach the El Guix anticline, in which only meteoric and evolved meteoricwaters circulated along the fold

Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone

Calcite veins precipitated in the Estamariu thrust during two tectonic events decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and determine the influence of basement rocks on the fluid chemistry during deformation. Structural and petrological observations constrain the timing of fluid migration and vein formation, whilst geochemical analyses (δ13C, δ18O, 87Sr/86Sr, clumped isotope thermometry and elemental composition) 15 of the related calcite cements and host rocks indicate the fluid origin, pathways and extent of fluid-rock interaction. The first tectonic event, recorded by calcite cements Cc1a and Cc2, is related to the Alpine reactivation of the Estamariu thrust, and is characterized by the migration of meteoric fluids, heated at depth (temperatures between 56 and 98 ºC) and interacted with crystalline basement rocks before upflowing through the thrust zone. During the Neogene extension, the Estamariu thrust was reactivated and normal faults and shear fractures with calcite cements Cc3, Cc4 and Cc5 developed. Cc3 and Cc4 precipitated 20 from hydrothermal fluids (temperatures between 127 and 208 ºC and between 102 and 167 ºC, respectively) derived from crystalline basement rocks and expelled through fault zones during deformation. Cc5 precipitated from low temperature meteoric waters percolating from the surface through small shear fractures. The comparison between our results and already published data in other structures from the Pyrenees suggests that regardless of the origin of the fluids and the tectonic context, basement rocks have a significant influence on the fluid chemistry, particularly on the 87Sr/86Sr ratio. Accordingly, the cements 25 precipitated from fluids interacted with crystalline basement rocks have significantly higher 87Sr/86Sr ratios (> 0.710) with respect to those precipitated from fluids that have interacted with the sedimentary cover (< 0.710)

Changes in fluid regime in syn-orogenic sediments during the growth of the south Pyrenean fold and thrust belt

The eastern sector of the south Pyrenean fold and thrust belt developed during the Alpine compression and affected Upper Cretaceous to lower Oligocene foreland basin deposits. In this study, we determine the changes in fluid regime and fluid composition during the growth of this fold and thrust belt, integrating petrographic and geochemical data obtained from fracture-filling cements. Hydrothermal fluids at temperatures up to 154 °C, migrated from the Axial zone to the foreland basin and mixed with connate fluids in equilibrium with Eocene sea-water during lower and middle Eocene (underfilled foreland basin). As the thrust front progressively emerged, low-temperature meteoric waters migrated downwards the foreland basin and mixed at depth with the hydrothermal fluids from middle Eocene to lower Oligocene (overfilled non-marine foreland basin). The comparison of the fluid flow models from the Southern Pyrenees with other orogens worldwide, seems to indicate that the presence or absence of thick evaporitic units highly control fluid composition during the development of fold and thrust belts. Whereas in thrusts not detached along thick evaporite units, mixed fluids are progressively more depleted in δ18O and have a lower temperature and lower Fe and Sr contents as the thrust front emerges, in thrust detachments through thick evaporite units, the mixed fluids are enriched in δ18O