Establishing the Leakage Rates of Mobile Air Conditioners

The purpose of the study is to - based on field measurements - determine the average annual leakage rate of HFC-134a from MACs in the European Union of a "second generation"1 air conditioner. From November 2002, to January 2003 300 measurements of HFC-134a leakage were carried out on air conditioners of cars up to seven years age. The measurements were carried out on vehicles of all EU relevant makes at 19 garages in Germany (Osnabrück), Portugal (Rio Maior) and Sweden (Helsingborg) reflecting different climatic conditions

Natural fluorinated organics in fluorite and rocks

Results of measurements of fluorinated compounds in gasses extracted from igneous and metamorphic rocks are reported. A new extraction method analogous to a pepper mill for geological samples is described. It permits extraction at low temperatures and ensures a rapid transfer of extracted gases from active surfaces to cryogenic pre-concentration loop. Values for CF4, CF3Cl, CF2Cl2, CFCl3, CHF3, SF6 and NF3 in fluorites, granites, basalts and other igneous and metamorphic rocks are reported. It is proposed that trifluoroacetic acid (TFA) that was recently discovered in various environmental archives could also origin from similar geogenic sources

Industry

This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of industrial mitigation for sustainable development is discussed in Section 7.7. Section 7.8 discusses the sector's vulnerability to climate change and options for adaptation. A number of policies have been designed either to encourage voluntary GHG emission reductions from the industrial sector or to mandate such reductions. Section 7.9 describes these policies and the experience gained to date. Co-benefits of reducing GHG emissions from the industrial sector are discussed in Section 7.10. Development of new technology is key to the cost-effective control of industrial GHG emissions. Section 7.11 discusses research, development, deployment and diffusion in the industrial sector and Section 7.12, the long-term (post-2030) technologies for GHG emissions reduction from the industrial sector. Section 7.13 summarizes gaps in knowledge

Estimating Future Emissions and Potential Reductions of HFCs, PFCs, and SF6

Atmospheric concentrations of HFCs, PFCs, and SF6 have been growing rapidly over the last 100 years, and they have the potential to continue growing rapidly, given the high growth rates of some emitting industries and the role of HFCs and PFCs as replacements for ozone-depleting substances. This analysis estimates global emissions of HFCs, PFCs, and SF6 from twelve source categories for the years 1990, 1995, 2000, 2010, and 2020, and provides guidance for projecting emissions beyond 2020. It also presents 2010 and 2020 marginal abatement cost curves (MACs) for the same source categories. To address issues unique to the fluorinated gases, the analysis accounts for the impact of international industry agreements to voluntarily reduce emission rates, and it aggregates emissions and MACs by gas lifetime as well as economic sector. Results indicate the availability of large, low-cost reductions, especially in developing countries, and the importance of better characterizing these reductions in future analysis.