153 research outputs found
Structural anomalies, spin transitions and charge disproportionation in LnCoO3
The diamagnetic-paramagnetic and insulator-metal transitions in LnCoO3
perovskites (Ln = La, Y, rare earths) are reinterpreted and modeled as a
two-level excitation process. In distinction to previous models, the present
approach can be characterized as a LS-HS-IS (low-high-intermediate spin)
scenario. The first level is the local excitation of HS Co3+ species in the LS
ground state. The second excitation is based on the interatomic electron
transfer between the LS/HS pairs, leading finally to a stabilization of the
metallic phase based on IS Co3+. The model parameters have been quantified for
Ln = La, Pr and Nd samples using the powder neutron diffraction on the thermal
expansion of Co-O bonds, that is associated with the two successive spin
transitions. The same model is applied to interpret the magnetic susceptibility
of LaCoO3 and YCoO3.Comment: 52.Conference on Magnetism and Magnetic Materials, November 2007,
Tamp
Modification of the Charge ordering in PrSrMnO Nanoparticles
Transport and magnetic properties have been studied in two sets of sol-gel
prepared PrSrMnO nanoparticles having average particle
size of 30 nm and 45 nm. Our measurements suggest that the formation of charge
ordered state is largely affected due to lowering of particle size, but the
ferromagnetic transition temperature () remains unaffected.Comment: Accepted in J. Appl. Phy
Phase transition in Pr0.5Ca0.5CoO3 and related cobaltites
We present an extensive investigation (magnetic, electric and thermal
measurements and X-ray absorption spectroscopy) of the Pr0.5Ca0.5CoO3 and
(Pr1-yYy)0.7Ca0.3CoO3 (y=0.0625-0.15) perovskites, in which a peculiar
metal-insulator (M-I) transition, accompanied with pronounced structural and
magnetic anomalies, occurs at 76 K and 40-132 K, respectively. The inspection
of the M-I transition using the XANES data of Pr L3-edge and Co K-edge proofs
the presence of Pr4+ ions at low temperatures and indicates simultaneously the
intermediate spin to low spin crossover of Co species on lowering the
temperature. The study thus definitively confirms the synchronicity of the
electron transfer between Pr3+ ions and Co^(3+/4+)O3 subsystem and the
transition to the low-spin, less electrically conducting phase. The large
extent of the transfer is evidenced by the good quantitative agreement of the
determined amount of the Pr4+ species, obtained either from the temperature
dependence of the XANES spectra or via integration of the magnetic entropy
change over the Pr4+ related Schottky peak in the low-temperature specific
heat. These results show that the average valence of Pr3+/Pr4+ ions increases
(in concomitance with the decrease of the formal Co valence) below TMI for
(Pr0.925Y0.075)0.7Ca0.3CoO3 up to 3.16+ (the doping level of the CoO3 subsystem
decreases from 3.30+ to 3.20+), for (Pr0.85Y0.15)0.7Ca0.3CoO3 up to 3.28+ (the
decrease of doping level from 3.30+ to 3.13+) and for Pr0.5Ca0.5CoO3 up to
3.46+ (the decrease of doping level from 3.50+ to 3.27+).Comment: 19 pages, 11 figure
Charge and Orbital Ordering in Pr_{0.5} Ca_{0.5} MnO_3 Studied by ^{17}O NMR
The charge and orbital ordering in Pr_{0.5} Ca_{0.5} MnO_3 is studied for the
first time by ^{17}O NMR. This local probe is sensitive to spin, charge and
orbital correlations. Two transitions exist in this system: the charge and
orbital ordering at T_{CO} = 225 K and the antiferromagnetic (AF) transition at
T_N = 170 K. Both are clearly seen in the NMR spectra measured in a magnetic
field of 7T. Above T_{CO} there exists only one NMR line with a large isotropic
shift, whose temperature dependence is in accordance with the presence of
ferromagnetic (FM) correlations. This line splits into two parts below T_{CO},
which are attributed to different types of oxygen in the charge/orbital ordered
state. The interplay of FM and AF spin correlations of Mn ions in the charge
ordered state of Pr_{0.5} Ca_{0.5} MnO_3 is considered in terms of the hole
hopping motion that is slowed down with decreasing temperature. The developing
fine structure of the spectra evidences, that there still exist
charge-disordered regions at T_{CO} > T > T_N and that the static (t >
10^{-6}s) orbital order is established only on approaching T_N. The CE-type
magnetic correlations develop gradually below T_{CO}, so that at first the AF
correlations between checkerboard ab-layers appear, and only at lower
temperature - CE correlations within the ab-planes
Microphase separation in Pr0.67Ca0.33MnO3 by small angle neutron scattering
We have evidenced by small angle neutron scattering at low temperature the
coexistence of ferromagnetism (F) and antiferromagnetism (AF) in
Pr0.67Ca0.33MnO3. The results are compared to those obtained in
Pr0.80Ca0.20MnO3 and Pr0.63Ca0.37MnO3, which are F and AF respectively.
Quantitative analysis shows that the small angle scattering is not due to a
mesoscopic mixing but to a nanoscopic electronic and magnetic ''red cabbage''
structure, in which the ferromagnetic phase exists in form of thin layers in
the AF matrix (stripes or 2D ''sheets'').Comment: 4 figure
Field dependence of the electronic phase separation in Pr0.67Ca0.33MnO3 by small angle magnetic neutron scattering
We have studied by small angle neutron scattering the evolution induced by
the application of magnetic field of the coexistence of ferromagnetism (F) and
antiferromagnetism (AF) in a crystal of PrCaMnO. The
results are compared to magnetic measurements which provide the evolution of
the ferromagnetic fraction. These results show that the growth of the
ferromagnetic phase corresponds to an increase of the thickness of the
ferromagnetic ''cabbage'' sheets
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