Tax Arrangement and Regional Industrial Restructuring: Evidence from Panel Data in China

Regional industrial restructuring has been one of the major items in the transformation of economic development mode. An exploration was made into the influence of tax arrangement on the regional industrial structure by setting up a panel data econometric model based on the evaluation and analysis of the regional industrial structure in China. It was shown that tax arrangement influenced the regional industrial restructuring in terms of three aspects. Microlevel: the turnover tax and income tax appeared with a U-path of influence on upgrading of the industrial structure while appearing with an inverted U-path of influence on rationalization of the industrial structure. In addition, the levy of resource tax had a negative impact on both upgrading and rationalization of the industrial structure. Mesolevel: taxation in the secondary and tertiary industries appeared with a U-path of influence on upgrading of the industrial structure. An increase of taxation in the secondary industry had a negative impact on rationalization of the industrial structure. The taxation in the tertiary industry appeared with an inverted U-path of influence on rationalization of the industrial structure. Macrolevel: the macrotax burden had a U-path of influence on both upgrading and rationalization of the industrial structure

Direct single-molecule dynamic detection of chemical reactions.

Single-molecule detection can reveal time trajectories and reaction pathways of individual intermediates/transition states in chemical reactions and biological processes, which is of fundamental importance to elucidate their intrinsic mechanisms. We present a reliable, label-free single-molecule approach that allows us to directly explore the dynamic process of basic chemical reactions at the single-event level by using stable graphene-molecule single-molecule junctions. These junctions are constructed by covalently connecting a single molecule with a 9-fluorenone center to nanogapped graphene electrodes. For the first time, real-time single-molecule electrical measurements unambiguously show reproducible large-amplitude two-level fluctuations that are highly dependent on solvent environments in a nucleophilic addition reaction of hydroxylamine to a carbonyl group. Both theoretical simulations and ensemble experiments prove that this observation originates from the reversible transition between the reactant and a new intermediate state within a time scale of a few microseconds. These investigations open up a new route that is able to be immediately applied to probe fast single-molecule physics or biophysics with high time resolution, making an important contribution to broad fields beyond reaction chemistry

The Stationary Distribution of Competitive Lotka-Volterra Population Systems with Jumps

Dynamics of Lotka-Volterra population with jumps (LVWJ) have recently been established (see Bao et al., 2011, and Bao and Yuan, 2012). They provided some useful criteria on the existence of stationary distribution and some asymptotic properties for LVWJ. However, the uniqueness of stationary distribution for n≥2 and asymptotic pathwise estimation limt→+∞⁡(1/t)∫0t‍|X(s)|pds (p>0) are still unknown for LVWJ. One of our aims in this paper is to show the uniqueness of stationary distribution and asymptotic pathwise estimation for LVWJ. Moreover, some characterizations for stationary distribution are provided

Immunogenicity and therapeutic effects of a Mycobacterium tuberculosis rv2190c DNA vaccine in mice

The Excel data file [FOLT] Figshare, [DOI: 10.6084/m9.figshare.4668148 and https://figshare.com/s/bd46c22986c673579bb6 ] includes all datasets supporting the conclusions of this article: IFN-Îł in spleen lymphocyte culture supernatants, IL-4 in spleen lymphocyte culture supernatants, CD4+ T cell subsets expressing intracellular IFN-Îł or IL-4, CFU in the lungs and spleens.. (XLS 143 kb

Direct measurement of the Raman enhancement factor of rhodamine 6G on graphene under resonant excitation

Graphene substrates have recently been found to generate Raman enhancement. Systematic studies using different Raman probes have been implemented, but one of the most commonly used Raman probes, rhodamine 6G (R6G), has yielded controversial results for the enhancement effect on graphene. Indeed, the Raman enhancement factor of R6G induced by graphene has never been measured directly under resonant excitation because of the presence of intense fluorescence backgrounds. In this study, a polarization-difference technique is used to suppress the fluorescence background by subtracting two spectra collected using different excitation laser polarizations. As a result, enhancement factors are obtained ranging between 1.7 and 5.6 for the four Raman modes of R6G at 611, 1,183, 1,361, and 1,647 cm[superscript −1] under resonant excitation by a 514.5 nm laser. By comparing these results with the results obtained under non-resonant excitation (632.8 nm) and pre-resonant excitation (593 nm), the enhancement can be attributed to static chemical enhancement (CHEM) and tuning of the molecular resonance. Density functional theory simulations reveal that the orbital energies and densities for R6G are modified by graphene dots.National Natural Science Foundation (China) (Nos. 21233001, 50972001, and 21129001)China. Ministry of Science and Technology (Nos. 2011YQ0301240201 and 2011CB932601)Beijing Natural Science Foundation (No. 2132056