1,884 research outputs found
Electronic structures of B-2p and C-2p of boron-doped diamond film by soft X-ray absorption and emission spectroscopy
X-ray absorption (XAS) and emission (XES) spectroscopy near B-K and C-K edges
have been performed on metallic (~1at%B, B-diamond) and semiconducting
(~0.1at%B and N, BN-diamond) doped-diamond films. Both B-K XAS and XES spectra
shows metallic partial density of state (PDOS) with the Fermi energy of 185.3
eV, and there is no apparent boron-concentration dependence in contrast to the
different electric property. In C-K XAS spectrum of B-diamond, the impurity
state ascribed to boron is clearly observed near the Fermi level. The Fermi
energy is found to be almost same with the top of the valence band of non-doped
diamond, E_V, 283.9 eV. C-K XAS of BN-diamond shows both the B-induced shallow
level and N-induced deep-and-broad levels as the in-gap states, in which the
shallow level is in good agreement with the activation energy (E_a=0.37 eV)
estimated from the temperature dependence of the conductivity, namely the
change in C-2p PDOS of impurity-induced metallization is directly observed. The
electric property of this diamond is mainly ascribed to the electronic
structure of C-2p near the Fermi level. The observed XES spectra are compared
with the DVX-alpha cluster calculation. The DVX-alpha result supports the
strong hybridization between B-2p and C-2p observed in XAS and XES spectra, and
suggests that the small amount of borons (<1at%) in diamond occupy the
substitutional site rather than interstitial site.Comment: submitted to Phys. Rev. B, 5 pages and 5 figure
Theory of Melting and the Optical Properties of Gold/DNA Nanocomposites
We describe a simple model for the melting and optical properties of a
DNA/gold nanoparticle aggregate. The optical properties at fixed wavelength
change dramatically at the melting transition, which is found to be higher and
narrower in temperature for larger particles, and much sharper than that of an
isolated DNA link. All these features are in agreement with available
experiments. The aggregate is modeled as a cluster of gold nanoparticles on a
periodic lattice connected by DNA bonds, and the extinction coefficient is
computed using the discrete dipole approximation. Melting takes place as an
increasing number of these bonds break with increasing temperature. The melting
temperature corresponds approximately to the bond percolation threshold.Comment: 5 pages, 4 figure. To be published in Phys. Rev.
Response of Stream Ecosystems to Climate Change (III): Characterizing and Predicting Ecologically Relevant Flow Regimes
Dislocation Loops in Proton Irradiated Uranium-Nitrogen-Oxygen System
In this study, we investigated the type of dislocation loops formed in the proton-irradiated uranium-nitrogen-oxygen (U-N-O) system, which involves uranium mononitride (UN), uranium sesquinitride (α-U2N3), and uranium dioxide (UO2) phases. The dislocation loop formation is examined using specimens irradiated at 400°C and 710°C. Based on the detailed transmission-based electron microscopy characterization with i) the morphology-based on-zone and ii) the invisibility-criterion based two-beam condition imaging techniques, only a single type of dislocation loop in each phase is found: a/2⟨110⟩, a/2⟨111⟩, or a/3⟨111⟩ dislocation loops in UN, α-U2N3, and UO2 phases, respectively. Molecular statics calculations for the formation energy of perfect and faulted dislocation loops in the UN phase indicate a critical loop size of ∼6 nm, above which perfect loops are thermodynamically favorable. This could explain the absence of faulted loops in the experimental observation of the irradiated UN phase at two temperatures. This work will enhance the understanding of irradiation induced microstructural evolution for uranium mononitride as an advanced nuclear fuel for the next-generation nuclear reactors.</p
Structure Formation, Melting, and the Optical Properties of Gold/DNA Nanocomposites: Effects of Relaxation Time
We present a model for structure formation, melting, and optical properties
of gold/DNA nanocomposites. These composites consist of a collection of gold
nanoparticles (of radius 50 nm or less) which are bound together by links made
up of DNA strands. In our structural model, the nanocomposite forms from a
series of Monte Carlo steps, each involving reaction-limited cluster-cluster
aggregation (RLCA) followed by dehybridization of the DNA links. These links
form with a probability which depends on temperature and particle
radius . The final structure depends on the number of monomers (i. e. gold
nanoparticles) , , and the relaxation time. At low temperature, the
model results in an RLCA cluster. But after a long enough relaxation time, the
nanocomposite reduces to a compact, non-fractal cluster. We calculate the
optical properties of the resulting aggregates using the Discrete Dipole
Approximation. Despite the restructuring, the melting transition (as seen in
the extinction coefficient at wavelength 520 nm) remains sharp, and the melting
temperature increases with increasing as found in our previous
percolation model. However, restructuring increases the corresponding link
fraction at melting to a value well above the percolation threshold. Our
calculated extinction cross section agrees qualitatively with experiments on
gold/DNA composites. It also shows a characteristic ``rebound effect,''
resulting from incomplete relaxation, which has also been seen in some
experiments. We discuss briefly how our results relate to a possible sol-gel
transition in these aggregates.Comment: 12 pages, 10 figure
Relativistic calculation of nuclear transparency in (e,e'p) reactions
Nuclear transparency in (e,e'p) reactions is evaluated in a fully
relativistic distorted wave impulse approximation model. The relativistic mean
field theory is used for the bound state and the Pauli reduction for the
scattering state, which is calculated from a relativistic optical potential.
Results for selected nuclei are displayed in a Q^2 range between 0.3 and 1.8
(GeV/c)^2 and compared with recent electron scattering data. For Q^2 = 0.3
(GeV/c)^2 the results are lower than data; for higher Q^2 they are in
reasonable agreement with data. The sensitivity of the model to different
prescriptions for the one-body current operator is investigated. The off-shell
ambiguities are rather large for the distorted cross sections and small for the
plane wave cross sections.Comment: 8 pages, 3 figure
Meson Exchange Currents in (e,e'p) recoil polarization observables
A study of the effects of meson-exchange currents and isobar configurations
in reactions is presented. We use a distorted wave
impulse approximation (DWIA) model where final-state interactions are treated
through a phenomenological optical potential. The model includes relativistic
corrections in the kinematics and in the electromagnetic one- and two-body
currents. The full set of polarized response functions is analyzed, as well as
the transferred polarization asymmetry. Results are presented for proton
knock-out from closed-shell nuclei, for moderate to high momentum transfer.Comment: 44 pages, 18 figures. Added physical arguments explaining the
dominance of OB over MEC, and a summary of differences with previous MEC
calculations. To be published in PR
Soft x-ray spectroscopy experiments on the near K-edge of B in MB2 (M=Mg, Al, Ta, and Nb)
Soft X-ray absorption and emission measurements are performed for the K- edge
of B in MB (M=Mg, Al, Ta and Nb). Unique feature of MgB with a high
density of B 2-state below and above the Fermi edge, which
extends to 1 eV above the edge, is confirmed. In contrast, the B 2 density
of states in AlB and TaB, both of occupied and unoccupied states,
decreased linearly towards the Fermi energy and showed a dip at the Fermi
energy. Furthermore, there is a broadening of the peaks with
-character in XES and XAS of AlB, which is due to the increase of
three dimensionality in the -band in AlB. The DOS of NbB has a
dip just below the Fermi energy. The present results indicate that the large
DOS of B-2 states near the Fermi energy are crucial for the
superconductivity of MgB.Comment: 3 pages text and 4 pages figures. accepted for publication to Phys.
Rev.
Diffusion in an Expanding Plasma using AdS/CFT
We consider the diffusion of a non-relativistic heavy quark of fixed mass M,
in a one-dimensionally expanding and strongly coupled plasma using the AdS/CFT
duality. The Green's function constructed around a static string embedded in a
background with a moving horizon, is identified with the noise correlation
function in a Langevin approach. The (electric) noise decorrelation is of order
1/T(\tau) while the velocity de-correlation is of order MD(\tau)/T(\tau). For
MD>1, the diffusion regime is segregated and the energy loss is Langevin-like.
The time dependent diffusion constant D(\tau) asymptotes its adiabatic limit
2/\pi\sqrt{\lambda} T(\tau) when \tau/\tau_0=(1/3\eta_0\tau_0)^3 where \eta_0
is the drag coefficient at the initial proper time \tau_0.Comment: 19 pages, 2 figures, minor corrections, version to appear in JHE
Near-field optical power transmission of dipole nano-antennas
Nano-antennas in functional plasmonic applications require high near-field optical power transmission. In this study, a model is developed to compute the near-field optical power transmission in the vicinity of a nano-antenna.
To increase the near-field optical power transmission from a nano-antenna, a tightly focused beam of light is utilized to illuminate a metallic nano-antenna. The modeling and simulation of these structures is performed using 3-D finite element method based full-wave solutions of Maxwell’s equations. Using the optical power transmission model, the interaction of a focused beam of light with plasmonic nanoantennas is investigated. In addition, the tightly focused beam of light is passed through a band-pass filter to identify the effect of various regions of the angular spectrum to the near-field radiation of a dipole nano-antenna. An extensive parametric study is performed to quantify the effects of various parameters on the transmission efficiency of dipole nano-antennas, including length, thickness, width, and the composition of the antenna, as well as the wavelength and half-beam angle of incident light. An optimal dipole nanoantenna geometry is identified based on the parameter studies in this work. In addition, the results of this study show the interaction of the optimized dipole nano-antenna with a magnetic recording medium when it is illuminated with a focused beam of light
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