pH-responsive gas–water–solid interface for multiphase catalysis

© 2015 American Chemical Society. Despite their wide utility in laboratory synthesis and industrial fabrication, gas-water-solid multiphase catalysis reactions often suffer from low reaction efficiency because of the low solubility of gases in water. Using a surface-modification protocol, interface-active silica nanoparticles were synthesized. Such nanoparticles can assemble at the gas-water interface, stabilizing micrometer-sized gas bubbles in water, and disassemble by tuning of the aqueous phase pH. The ability to stabilize gas microbubbles can be finely tuned through variation of the surface-modification protocol. As proof of this concept, Pd and Au were deposited on these silica nanoparticles, leading to interface-active catalysts for aqueous hydrogenation and oxidation, respectively. With such catalysts, conventional gas-water-solid multiphase reactions can be transformed to H 2 or O 2 microbubble reaction systems. The resultant microbubble reaction systems exhibit significant catalysis efficiency enhancement effects compared with conventional multiphase reactions. The significant improvement is attributed to the pronounced increase in reaction interface area that allows for the direct contact of gas, water, and solid phases. At the end of reaction, the microbubbles can be removed from the reaction systems through changing the pH, allowing product separation and catalyst recycling. Interestingly, the alcohol oxidation activation energy for the microbubble systems is much lower than that for the conventional multiphase reaction, also indicating that the developed microbubble system may be a valuable platform to design innovative multiphase catalysis reactions

OVSNet : Towards One-Pass Real-Time Video Object Segmentation

Video object segmentation aims at accurately segmenting the target object regions across consecutive frames. It is technically challenging for coping with complicated factors (e.g., shape deformations, occlusion and out of the lens). Recent approaches have largely solved them by using backforth re-identification and bi-directional mask propagation. However, their methods are extremely slow and only support offline inference, which in principle cannot be applied in real time. Motivated by this observation, we propose a efficient detection-based paradigm for video object segmentation. We propose an unified One-Pass Video Segmentation framework (OVS-Net) for modeling spatial-temporal representation in a unified pipeline, which seamlessly integrates object detection, object segmentation, and object re-identification. The proposed framework lends itself to one-pass inference that effectively and efficiently performs video object segmentation. Moreover, we propose a maskguided attention module for modeling the multi-scale object boundary and multi-level feature fusion. Experiments on the challenging DAVIS 2017 demonstrate the effectiveness of the proposed framework with comparable performance to the state-of-the-art, and the great efficiency about 11.5 FPS towards pioneering real-time work to our knowledge, more than 5 times faster than other state-of-the-art methods.Comment: 10 pages, 6 figure

An Active Margin System and its Application in Chinese Margin Lending Market

In order to protect brokers from customer defaults in a volatile market, an active margin system is proposed for the transactions of margin lending in China. The probability of negative return under the condition that collaterals are liquidated in a falling market is used to measure the risk associated with margin loans, and a recursive algorithm is proposed to calculate this probability under a Markov chain model. The optimal maintenance margin ratio can be given under the constraint of the proposed risk measurement for a specified amount of initial margin. An example of such a margin system is constructed and applied to $26,800$ margin loans of 134 stocks traded on the Shanghai Stock Exchange. The empirical results indicate that the proposed method is an operational method for brokers to set margin system with a clearly specified target of risk control.Comment: 27 pages, 2 figures, 5 table

Study of the transfer between libration point orbits and lunar orbits in Earth–Moon system

This paper is devoted to the study of the transfer problem from a libration point orbit of the Earth–Moon system to an orbit around the Moon. The transfer procedure analysed has two legs: the first one is an orbit of the unstable manifold of the libration orbit and the second one is a transfer orbit between a certain point on the manifold and the final lunar orbit. There are only two manoeuvres involved in the method and they are applied at the beginning and at the end of the second leg. Although the numerical results given in this paper correspond to transfers between halo orbits around the L1 point (of several amplitudes) and lunar polar orbits with altitudes varying between 100 and 500 km, the procedure we develop can be applied to any kind of lunar orbits, libration orbits around the L1 or L2 points of the Earth–Moon system, or to other similar cases with different values of the mass ratio.Peer ReviewedPostprint (author's final draft

Amphibian Species Contribute Similarly to Taxonomic, but not Functional and Phylogenetic Diversity: Inferences from Amphibian Biodiversity on Emei Mountain

Understanding the relationships between species, communities, and biodiversity are important challenges in conservation ecology. Current biodiversity conservation activities usually focus on species that are rare, endemic, distinctive, or at risk of extinction. However, empirical studies of whether such species contribute more to aspects of biodiversity than common species are still relatively rare. The aim of the present study was to assess the contribution of individual amphibian species to different facets of biodiversity, and to test whether species of conservation interest contribute more to taxonomic, functional, and phylogenetic diversity than do species without special conservation status. To answer these questions, 19 000 simulated random communities with a gradient of species richness were created by shuffling the regional pool of species inhabiting Emei Mountain. Differences of diversity values were then computed before and after removing individual species in these random communities. Our results indicated that although individual species contributed similarly to taxonomic diversity, their contribution to functional and phylogenetic diversity was more idiosyncratic. This was primarily driven by the diverse functional attributes of species and the differences in phylogenetic relationships among species. Additionally, species of conservation interest did not show a significantly higher contribution to any facet of biodiversity. Our results support the claims that the usefulness of metrics based only on species richness is limited. Instead, assemblages that include species with functional and phylogenetic diversity should be protected to maintain biodiversity