Grey-box Modeling of Reversible Solid Oxide Cell Stack’s Electrical Dynamics Based on Electrochemical Impedance Spectroscopy

This paper aims to design a lumped-capacity modelof a reversible solid oxide cell stack for hydrogen electrolysis.The lumped-capacity model needs to have an adequate representationof the electrical dynamics over a wide operatingrange and a model structure suitable for the design of a physicalemulator. The grey-box model is based on data obtained by electrochemicalimpedance spectroscopy conducted on a commercialsolid oxide cell stack for four different gas compositions at sixaging stages. In addition, a comparison of the experimental andsimulated voltage response of the reversible solid oxide cell stackin cyclic reversible operation mode was conducted at differentaging levels of the stack

Evidence of energy and nutrient transfer from invasive pink salmon (Oncorhynchus gorbuscha) spawners to juvenile Atlantic salmon (Salmo salar) and brown trout (Salmo trutta) in northern Norway

Recent large influxes of non-native Pacific pink salmon (Oncorhynchus gorbuscha) to North European rivers have raised concern over their potential negative impacts on native salmonids and recipient ecosystems. The eggs and carcasses of semelparous pink salmon may provide a significant nutrient and energy subsidy to native biota, but this phenomenon has not been widely documented outside the species' native distribution. We analysed the stomach contents and stable isotope values (δ15N and δ13C) in muscle and liver tissues of juvenile Atlantic salmon (Salmo salar) and brown trout (Salmo trutta) to determine whether these native salmonids utilise marine-derived nutrients and energy provided by pink salmon eggs and carcasses in the subarctic river system Vesterelva, northern Norway. Although egg foraging and assimilation of marine-derived nutrients in fish body tissues were found to be minor at the population level, a few juvenile salmon and trout had recently eaten large quantities of pink salmon eggs. Some of these individuals also had high δ15N and δ13C values, indicating a long-term diet subsidised by marine-derived nutrients and energy from pink salmon eggs. Hence, our study provides novel evidence that the eggs of invasive pink salmon may provide an energetic, profitable food resource for juvenile native fish. More research is needed to understand the broader ecological implications for fishes and other biota in river ecosystems invaded by pink salmon. egg predation, marine-derived nutrients, non-native salmonids, resource subsidy, stable isotope analysis, subarctic riverpublishedVersio

Response of a catalytic reaction to periodic variation of the CO pressure: Increased CO_2 production and dynamic phase transition

We present a kinetic Monte Carlo study of the dynamical response of a Ziff-Gulari-Barshad model for CO oxidation with CO desorption to periodic variation of the CO presure. We use a square-wave periodic pressure variation with parameters that can be tuned to enhance the catalytic activity. We produce evidence that, below a critical value of the desorption rate, the driven system undergoes a dynamic phase transition between a CO_2 productive phase and a nonproductive one at a critical value of the period of the pressure oscillation. At the dynamic phase transition the period-averged CO_2 production rate is significantly increased and can be used as a dynamic order parameter. We perform a finite-size scaling analysis that indicates the existence of power-law singularities for the order parameter and its fluctuations, yielding estimated critical exponent ratios $\beta/\nu \approx 0.12$ and $\gamma/\nu \approx 1.77$. These exponent ratios, together with theoretical symmetry arguments and numerical data for the fourth-order cumulant associated with the transition, give reasonable support for the hypothesis that the observed nonequilibrium dynamic phase transition is in the same universality class as the two-dimensional equilibrium Ising model.Comment: 18 pages, 10 figures, accepted in Physical Review

The variational quantum eigensolver self-consistent field method within a polarizable embedded framework

We formulate and implement the Variational Quantum Eigensolver Self Consistent Field (VQE-SCF) algorithm in combination with polarizable embedding (PE), thereby extending PE to the regime of quantum computing. We test the resulting algorithm, PE-VQE-SCF, on quantum simulators and demonstrate that the computational stress on the quantum device is only slightly increased in terms of gate counts compared to regular VQE-SCF. On the other hand, no increase in shot noise was observed. We illustrate how PE-VQE-SCF may lead to the modeling of real chemical systems using a simulation of the reaction barrier of the Diels-Alder reaction between furan and ethene as an example.Comment: 19 pages, 5 figures, submitted to Journal of Chemical Physic