1,373 research outputs found
Exploring the Atmosphere of Neoproterozoic Earth: The Effect of O on Haze Formation and Composition
Previous studies of haze formation in the atmosphere of the Early Earth have
focused on N/CO/CH atmospheres. Here, we experimentally
investigate the effect of O on the formation and composition of aerosols
to improve our understanding of haze formation on the Neoproterozoic Earth. We
obtained in situ size, particle density, and composition measurements of
aerosol particles produced from N/CO/CH/O gas mixtures
subjected to FUV radiation (115-400 nm) for a range of initial
CO/CH/O mixing ratios (O ranging from 2 ppm to 0.2\%).
At the lowest O concentration (2 ppm), the addition increased particle
production for all but one gas mixture. At higher oxygen concentrations (20 ppm
and greater) particles are still produced, but the addition of O
decreases the production rate. Both the particle size and number density
decrease with increasing O, indicating that O affects particle
nucleation and growth. The particle density increases with increasing O.
The addition of CO and O not only increases the amount of oxygen in
the aerosol, but it also increases the degree of nitrogen incorporation. In
particular, the addition of O results in the formation of nitrate bearing
molecules. The fact that the presence of oxygen bearing molecules increases the
efficiency of nitrogen fixation has implications for the role of haze as a
source of molecules required for the origin and evolution of life. The
composition changes also likely affect the absorption and scattering behavior
of these particles but optical properties measurements are required to fully
understand the implications for the effect on the planetary radiative energy
balance and climate.Comment: 15 pages, 3 tables, 8 figures, accepted in Astrophysical Journa
Gully Formation at the Haughton Impact Structure (Arctic Canada) Through the Melting of Snow and Ground Ice, with Implications for Gully Formation on Mars
The formation of gullies on Mars has been the topic of active debate and scientific study since their first discovery by Malin and Edgett in 2000. Several mechanisms have been proposed to account for gully formation on Mars, from dry mass movement processes, release of water or brine from subsurface aquifers, and the melting of near-surface ground ice or snowpacks. In their global documentation of martian gullies, report that gullies are confined to ~2783S and ~2872N latitudes and span all longitudes. Gullies on Mars have been documented on impact crater walls and central uplifts, isolated massifs, and on canyon walls, with crater walls being the most common situation. In order to better understand gully formation on Mars, we have been conducting field studies in the Canadian High Arctic over the past several summers, most recently in summer 2018 and 2019 under the auspices of the Canadian Space Agency-funded Icy Mars Analogue Program. It is notable that the majority of previous studies in the Arctic and Antarctica, including our recent work on Devon Island, have focused on gullies formed on slopes generated by regular endogenic geological processes and in regular bedrock. How-ever, as noted above, meteorite impact craters are the most dominant setting for gullies on Mars. Impact craters provide an environment with diverse lithologies including impact-generated and impact-modified rocks and slope angle, and thus greatly variable hill slope processes could occur within a localized area. Here, we investigate the formation of gullies within the Haughton impact structure and compare them to gullies formed in unimpacted target rock in the nearby Thomas Lee Inle
Coupling between downstream variations of channel width and local poolâriffle bed topography
A potential control of downstream channel width variations on the structure and planform of poolâriffle sequence local bed topography is a key to the dynamics of gravel bed rivers. How established poolâriffle sequences respond to time-varying changes in channel width at specific locations, however, is largely unexplored and challenging to address with field-based study. Here, we report results of a flume experiment aimed at building understanding of how statistically steady poolâriffle sequence profiles adjust to spatially prescribed channel width changes. We find that local bed slopes near steady-state conditions inversely correlate with local downstream width gradients when the upstream sediment supply approximates the estimated transport capacity. This result constrains conditions prior to and following the imposed local width changes. Furthermore, this relationship between local channel bed slope and downstream width gradient is consistent with expectations from scaling theory and a broad set of field-based, numerical, and experimental studies (n=88). However, upstream disruptions to coarse sediment supply through actions such as dam removal can result in a transient flipping of the expected inverse correlation between bed slope and width gradient, collectively highlighting that understanding local conditions is critical before typically implemented spatial averaging schemes can be reliably applied.Postprint (published version
Comparing three short questionnaires to detect psychosocial dysfunction among primary school children: a randomized method
BACKGROUND: Good questionnaires are essential to support the early identification of children with psychosocial dysfunction in community based settings. Our aim was to assess which of three short questionnaires was most suitable for this identification among school-aged children METHODS: A community-based sample of 2,066 parents of children aged 7-12 years (85% of those eligible) filled out the Child Behavior Checklist (CBCL) and - randomly determined - one of three questionnaires to be compared: the Strengths and Difficulties Questionnaire with Impact Supplement (SDQ), the Pediatric Symptom Checklist (PSC) and the PSYBOBA, a Dutch-origin questionnaire. Preventive Child Healthcare professionals assessed children's psychosocial functioning during routine health examinations. We assessed the scale structure (by means of Structural Equation Modelling), validity (correlation coefficients, sensitivity and specificity) and usability (ratings by parents and professionals) of each questionnaire and the degree to which they could improve the identification based only on clinical assessment (logistic regression). RESULTS: For the three questionnaires, Cronbach's alphas varied between 0.80 and 0.89. Sensitivities for a clinical CBCL at a cut off point with specificity = 0.90 varied between 0.78 and 0.86 for the three questionnaires. Areas under the Receiver Operating Curve, using the CBCL as criterion, varied between 0.93 and 0.96. No differences were statistically significant. All three questionnaires added information to the clinical assessment. Odds ratios (95% confidence intervals) for added information were PSC: 29.3 (14.4-59.8), SDQ: 55.0 (23.1-131.2) and PSYBOBA: 68.5 (28.3-165.6). Parents preferred the SDQ and PSYBOBA. Preventive Child Health Care professionals preferred the SDQ. CONCLUSIONS: This randomized comparison of three questionnaires shows that each of the three questionnaires can improve the detection of psychosocial dysfunction among children substantially
Structure and stability of finite gold nanowires
Finite gold nanowires containing less than 1000 atoms are studied using the
molecular dynamics simulation method and embedded atom potential. Nanowires
with the face-centered cubic structure and the (111) oriented cross-section are
prepared at T=0 K. After annealing and quenching the structure and vibrational
properties of nanowires are studied at room temperature. Several of these
nanowires form multi-walled structures of lasting stability. They consist of
concentrical cylindrical sheets and resemble multi-walled carbon nanotubes.
Vibrations are investigated by diagonalization of the dynamical matrix. It was
found that several percents of vibrational modes are unstable because of
uncompleted restructuring of initial fcc nanowires.Comment: 4 figures in gif forma
Impact of global warming on the rise of volcanic plumes and implications for future volcanic aerosol forcing
©2016. American Geophysical Union. All Rights Reserved. Volcanic eruptions have a significant impact on climate when they inject sulfur gases into the stratosphere. The dynamics of eruption plumes is also affected by climate itself, as atmospheric stratification impacts plumes' height. We use an integral plume model to assess changes in volcanic plume maximum rise heights as a consequence of global warming, with atmospheric conditions from an ensemble of global climate models, using three representative concentration pathways (RCP) scenarios. Predicted changes in atmospheric temperature profiles decrease the heights of tropospheric and lowermost stratospheric volcanic plumes and increase the tropopause height, for the RCP4.5 and RCP8.5 scenarios in the coming three centuries. Consequently, the critical mass eruption rate required to cross the tropopause increases by up to a factor of 3 for tropical regions and up to 2 for high-latitude regions. A number of recent lower stratospheric plumes, mostly in the tropics (e.g., Merapi, 2010), would be expected to not cross the tropopause starting from the late 21st century, under RCP4.5 and RCP8.5 scenarios. This effect could result in a â5â25% decrease in the average SO2 flux into the stratosphere carried by small plumes, the frequency of which is larger than the rate of decay of volcanic stratospheric aerosol, and a â2â12% decrease of the total flux. Our results suggest the existence of a positive feedback between climate and volcanic aerosol forcing. Such feedback may have minor implications for global warming rate but can prove to be important to understand the long-term evolution of volcanic atmospheric inputs
Impacts of Climate Change on Volcanic Stratospheric Injections: Comparison of 1-D and 3-D Plume Model Projections
©2019. American Geophysical Union. All Rights Reserved. Explosive volcanic eruptions are one of the most important driver of climate variability. Yet, we still lack a fundamental understanding of how climate change may affect future eruptions. Here, we use an ensemble of simulations by 1-D and 3-D volcanic plume models spanning a large range of eruption source and atmospheric conditions to assess changes in the dynamics of future eruptive columns. Our results shed new light on differences between the predictions of 1-D and 3-D plume models. Furthermore, both models suggest that as a result of ongoing climate change, for tropical eruptions, (i) higher eruption intensities will be required for plumes to reach the upper troposphere/lower stratosphere and (ii) the height of plumes currently reaching the upper troposphere/lower stratosphere or above will increase. We discuss the implications of these results for the climatic impacts of future eruptions. Our simulations can directly inform climate model experiments on climate-volcano feedback.T.J.A.acknowledges funding from the Royal Society through a Newton International Fellowship (Grant NIF⧔R1⧔-180809).M. C. acknowledges CINECA Award N. HP10BRDK2T (2017) for high-performance computing resources used for testing the ASHEEcode; the FISR 2016 âCentro di studioe monitoraggio dei rischi naturalidellItalia centraleâ project framework,managed by the Italian National Institute of Geophysics and Volcanology (INGV) and funded by the Italian Ministry of Education,University and Research; and the European Unions Horizon 2020 research and innovation program under Grant Agreement 731070. T. J.A. and A.M.J. acknowledge support from the Natural Sciences and Engineering Research Council of Canada during completion of this work
On the Temperature Dependence of the Lifetime of Thermally Isolated Metastable Clusters
The temperature dependence of the lifetime of the thermally isolated
metastable N8 cubane up to its decay into N2 molecules has been calculated by
the molecular dynamics method. It has been demonstrated that this dependence
significantly deviates from the Arrhenius law. The applicability of the finite
heat bath theory to the description of thermally isolated atomic clusters has
been proved using statistical analysis of the results obtained.Comment: 14 pages, 4 figure
Does the Boltzmann principle need a dynamical correction?
In an attempt to derive thermodynamics from classical mechanics, an
approximate expression for the equilibrium temperature of a finite system has
been derived [M. Bianucci, R. Mannella, B. J. West, and P. Grigolini, Phys.
Rev. E 51, 3002 (1995)] which differs from the one that follows from the
Boltzmann principle S = k log (Omega(E)) via the thermodynamic relation 1/T=
dS/dE by additional terms of "dynamical" character, which are argued to correct
and generalize the Boltzmann principle for small systems (here Omega(E) is the
area of the constant-energy surface). In the present work, the underlying
definition of temperature in the Fokker-Planck formalism of Bianucci et al. is
investigated and shown to coincide with an approximate form of the
equipartition temperature. Its exact form, however, is strictly related to the
"volume" entropy S = k log (Phi(E)) via the thermodynamic relation above for
systems of any number of degrees of freedom (Phi(E) is the phase space volume
enclosed by the constant-energy surface). This observation explains and
clarifies the numerical results of Bianucci et al. and shows that a dynamical
correction for either the temperature or the entropy is unnecessary, at least
within the class of systems considered by those authors. Explicit analytical
and numerical results for a particle coupled to a small chain (N~10) of quartic
oscillators are also provided to further illustrate these facts.Comment: REVTeX 4, 10 pages, 2 figures. Accepted to J. Stat. Phy
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