1,695 research outputs found
Addressing the terawatt challenge:Scalability in the supply of chemical elements for renewable energy
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Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold.
Electrochemical CO[Formula: see text] reduction is a potential route to the sustainable production of valuable fuels and chemicals. Here, we perform CO[Formula: see text] reduction experiments on Gold at neutral to acidic pH values to elucidate the long-standing controversy surrounding the rate-limiting step. We find the CO production rate to be invariant with pH on a Standard Hydrogen Electrode scale and conclude that it is limited by the CO[Formula: see text] adsorption step. We present a new multi-scale modeling scheme that integrates ab initio reaction kinetics with mass transport simulations, explicitly considering the charged electric double layer. The model reproduces the experimental CO polarization curve and reveals the rate-limiting step to be *COOH to *CO at low overpotentials, CO[Formula: see text] adsorption at intermediate ones, and CO[Formula: see text] mass transport at high overpotentials. Finally, we show the Tafel slope to arise from the electrostatic interaction between the dipole of *CO[Formula: see text] and the interfacial field. This work highlights the importance of surface charging for electrochemical kinetics and mass transport
Preference for Risk Management Information Sources: Implications for Extension and Outreach Programming
This article examines farmersâ preferences for various risk management information sources. Our results suggest that information from risk management experts, in-depth materials studied on their own, and popular press outlets tend to be preferred and are ranked highly by producers. Using a regression model to investigate farmer/farm attributes that affect preference for a particular risk management information source, we find that younger farmers with college education, higher leverage, assets greater than $1 million, risk-loving attitudes, and who have used professional services (marketing consultants) tend to prefer information from risk management experts, the Internet, and marketing clubs/other producers. On the other hand, producers who prefer self-study of educational materials and popular press information sources tend to be younger, with lower leverage levels, and have used fewer professional services.crop insurance, extension, information sources, outreach, risk management, Risk and Uncertainty,
Gas-Diffusion Electrodes for Carbon-Dioxide Reduction: A New Paradigm
Significant advances have been made in recent years discovering new electrocatalysts and developing a fundamental understanding of electrochemical CO_2 reduction processes. This field has progressed to the point that efforts can now focus on translating this knowledge toward the development of practical CO_2 electrolyzers, which have the potential to replace conventional petrochemical processes as a sustainable route to produce fuels and chemicals. In this Perspective, we take a critical look at the progress in incorporating electrochemical CO_2 reduction catalysts into practical device architectures that operate using vapor-phase CO_2 reactants, thereby overcoming intrinsic limitations of aqueous-based systems. Performance comparison is made between state-of-the-art CO_2 electrolyzers and commercial H_2O electrolyzersâa well-established technology that provides realistic performance targets. Beyond just higher rates, vapor-fed reactors represent new paradigms for unprecedented control of local reaction conditions, and we provide a perspective on the challenges and opportunities for generating fundamental knowledge and achieving technological progress toward the development of practical CO_2 electrolyzers
Combining theory and experiment in electrocatalysis: Insights into materials design
Better living through water-splitting
Chemists have known how to use electricity to split water into hydrogen and oxygen for more than 200 years. Nonetheless, because the electrochemical route is inefficient, most of the hydrogen made nowadays comes from natural gas. Seh
et al.
review recent progress in electrocatalyst development to accelerate water-splitting, the reverse reactions that underlie fuel cells, and related oxygen, nitrogen, and carbon dioxide reductions. A unified theoretical framework highlights the need for catalyst design strategies that selectively stabilize distinct reaction intermediates relative to each other.
Science
, this issue p.
10.1126/science.aad4998
</jats:p
First-Principles Based Kinetic Analysis of the Electrochemical Discharge of Water on Pt3M Skin Alloys
Surface Engineering of 3D Gas Diffusion Electrodes for HighâPerformance H2 Production with Nonprecious Metal Catalysts
In this work, a methodology is demonstrated to engineer gas diffusion electrodes for nonprecious metal catalysts. Highly active transition metal phosphides are prepared on carbonâbased gas diffusion electrodes with low catalyst loadings by modifying the O/C ratio at the surface of the electrode. These nonprecious metal catalysts yield extraordinary performance as measured by low overpotentials (51 mV at â10 mA cmâ2), unprecedented mass activities (>800 A gâ1 at 100 mV overpotential), high turnover frequencies (6.96 H2 sâ1 at 100 mV overpotential), and high durability for a precious metalâfree catalyst in acidic media. It is found that a high O/C ratio induces a more hydrophilic surface directly impacting the morphology of the CoP catalyst. The improved hydrophilicity, stemming from introduced oxyl groups on the carbon electrode, creates an electrode surface that yields a wellâdistributed growth of cobalt electrodeposits and thus a wellâdispersed catalyst layer with high surface area upon phosphidation. This report demonstrates the highâperformance achievable by CoP at low loadings which facilitates further cost reduction, an important part of enabling the largeâscale commercialization of nonâplatinum group metal catalysts. The fabrication strategies described herein offer a pathway to lower catalyst loading while achieving high efficiency and promising stability on a 3D electrode
Effects of Gold Substrates on the Intrinsic and Extrinsic Activity of High-Loading Nickel-Based Oxyhydroxide Oxygen Evolution Catalysts
We systematically investigate the
effects of Au substrates on the
oxygen evolution activities of cathodically electrodeposited nickel
oxyhydroxide (NiOOH), nickelâiron oxyhydroxide (NiFeOOH), and
nickelâcerium oxyhydroxide (NiCeOOH) at varying loadings from
0 to 2000 nmol of metal/cm<sup>2</sup>. We determine that the geometric
current densities, especially at higher loadings, were greatly enhanced
on Au substrates: NiCeOOH/Au reached 10 mA/cm<sup>2</sup> at 259 mV
overpotential, and NiFeOOH/Au achieved 140 mA/cm<sup>2</sup> at 300
mV overpotential, which were much greater than those of the analogous
catalysts on graphitic carbon (GC) substrates. By performing a loading
quantification using both inductively coupled plasma optical emission
spectrometry and integration of the Ni<sup>2+/3+</sup> redox peak,
we show that the enhanced activity is predominantly caused by the
stronger physical adhesion of catalysts on Au. Further characterizations
using impedance spectroscopy and <i>in situ</i> X-ray absorption
spectroscopy revealed that the catalysts on Au exhibited lower film
resistances and higher number of electrochemically active metal sites.
We attribute this enhanced activity to a more homogeneous electrodeposition
on Au, yielding catalyst films with very high geometric current densities
on flat substrates. By investigating the mass and site specific activities
as a function of loading, we bridge the practical geometric activity
to the fundamental intrinsic activity
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